Patent US4797235A successfully refreshed from Google Patents.
US4797235A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Process for enhanced orientation of polymeric films
Assignee: WR Grace and Co Conn
•
Filing: 1987-04-16
•
Granted: 1989-01-10
•
Expires: 2007-04-16
Abstract
Abstract Described is the presence of both a chemical cross-linking agent and irradiation such as electron beam irradiation, in the manufacturing process for making an oriented, i.e. heat-shrinkable, polymeric film. The presence of both results in an amount of cross-linking that is effective to accomplish an increased orientation rate during manufacturing.
Inventors
- 👤 Steven B. Garland
- 👤 Thomas C. Warren
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-29 07:23
CPC Classifications
B; B32; B32B; B32B27/00; B32B27/06; B32B27/08; B29; B29C; B29C61/00; B29C61/06; B32B27/16; B32B27/32; C; C08; C08J; C08J3/00; C08J3/24; C08J3/243; C08J5/00; C08J5/18; C08K; C08K5/00; C08K5/04; C08K5/14; B32B2307/00; B32B2307/50; B32B2307/514; B32B2307/70; B32B2307/732; B32B2307/734; B32B2307/736; B32B2323/00; B32B2323/04; B32B2439/00
Claims Analysis
Total Claims: 9
Claim 1
Independent Claim
138 words
A process for manufacturing a heat-shrinkable oriented polymeric film comprising: (a) introducing a chemical cross-linking agent to a cross-linkable polymer by blending the chemical cross-linking agent with the cross-linkable polymer, (b) extruding a film of the blended cross-linkable polymer, said chemical cross-linking agent is originally present in an amount from about 0.001 to about 0.025% by weight, (c) subjecting the extruded polymer film to electron beam irradiation, (d) heating and stretching to orient the irradiated extruded polymer film in at least one direction, followed by cooling the film while it is in its stretched condition and (e) recovering an oriented, heat-shrinkable polymeric film, wherein (f) both the original amount of chemical cross-linking agent and the dosage of electron beam irradiation are to an extent sufficient to provide an amount of cross-linking effective to accomplish an increased orientation rate.
Claim 2
Dependent Claim
138 words
A process for manufacturing a heat-shrinkable oriented polymeric film comprising: (a) introducing a chemical cross-linking agent to a cross-linkable polymer by blending the chemical cross-linking agent with the cross-linkable polymer, (b) extruding a film of the blended cross-linkable polymer, said chemical cross-linking agent is originally present in an amount from about 0.001 to about 0.025% by weight, (c) subjecting the extruded polymer film to electron beam irradiation, (d) heating and stretching to orient the irradiated extruded polymer film in at least one direction, followed by cooling the film while it is in its stretched condition and (e) recovering an oriented, heat-shrinkable polymeric film, wherein (f) both the original amount of chemical cross-linking agent and the dosage of electron beam irradiation are to an extent sufficient to provide an amount of cross-linking effective to accomplish an increased orientation rate.
Claim 3
Dependent Claim
14 words
The process of claim 1 wherein said chemical cross-linking agent is an organic peroxide.
Claim 4
Dependent Claim
32 words
The process of claim 2 wherein said organic peroxide is dichlorobenzoyl peroxide, benzoyl peroxide, dicumyl peroxide, di-tert-butyl peroxide, 4,5-dimethyl-2,5-di(peroxy benzoate)hexyne-3, 1,3-bis(tert-butyl peroxy isopropyl)benzene, lauroyl peroxide, tert-butyl peracetate, 2,5-dimethyl-2,5-di(tert-butyl-peroxy)hexyne-3, 2,5-dimethyl-2,5-di(tert-butylperoxy)hexane or tertbutyl perbenzoate.
Claim 5
Dependent Claim
20 words
The process of claim 1 wherein the irradiation is in a dosage from about 1 MR to about 20 MR.
Claim 6
Dependent Claim
12 words
The process of claim 1 wherein the cross-linkable polymer is a polyolefin.
Claim 7
Dependent Claim
11 words
The process of claim 5 wherein the polyolefin is a polyethylene.
Claim 8
Dependent Claim
22 words
The process of claim 6 wherein the polyethylene is HDPE, MDPE, LDPE, LLDPE, VLDPE, EVA, EAA, EMA, EBA, EEA, or mixtures thereof.
Claim 9
Dependent Claim
13 words
The process of claim 1 wherein the extruding includes extruding a barrier layer.
References Cited (Backward Citations)
US3022543A
Cited
US3821182A
Cited
US4048428A
Cited
US3456044A
Cited
US3555604A
Cited
US3448182A
Cited
US3741253A
Cited
JPS5356241A
Cited
US4178401A
Cited
US4194039A
Cited
DE2836798B1
Cited
US4188443A
Cited
US4274900A
Cited
US4229241A
Cited
WO1981003461A1
Cited
JPS5818228A
Cited
US4465812A
Cited
JPS59100141A
Cited
US4525257A
Cited
JPS59184629A
Cited
US4515745A
Cited
US4675364A
Cited
US4614764A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1992-01-10 | 1992-07-11 | 1993-01-10 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1996-01-10 | 1996-07-11 | 1997-01-10 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2000-01-10 | 2000-07-11 | 2001-01-10 | $7700.00 | Window Closed / Lapsed |