Radiation curable coating for photographic laminate

Claim 1

Unexposed photographic color print material comprising a laminate of a photoemulsion layer having front and back sides and an optically clear coating layer having front and back sides, wherein: A. said photoemulsion layer is adapted to be exposed to the image of a color print negative projected through said coating layer, developed by an immersion development process, and viewed through said coating layer following said development process; B. the front side of said coating layer is the front outside surface of said color print material, and is adapted to be in contact with immersion development process chemicals during develpment of said print material; C. the back side of said coating layer faces the front side of said photoemulsion layer; D. said coating layer has the property of being essentially non-yellowing during and after immersion of said color print material in immersion development process chemicals with said coating layer in direct contact with said chemicals; and E. said coating layer consists essentially of the cured reaction product of: (i) from 45 to 80 percent, based upon total weight of the composition, of an oligomer of the formula: ##STR5## where R 1 is a linear or branched hydrocarbon polymer of from 1,000 to 4,000 molecular weight selected from the group consisting of fully hydrogenated 1,2-polybutadiene; 1,2-polybutadiene hydrogenated to an iodine number of from 9 to 21; and fully hydrogenated polyisobutylene; R 2 is a linear, branched or cyclic alkylene of from six to twenty carbon atoms; and X and Q are independently either (a) a radical of the formula: ##STR6## wherein R 3 , R 4 , and R 5 are independently hydrogen or methyl, m is an integer from 1 to 10, and p is either zero or one, or (b) a saturated alkyl radical of from nine to twenty carbon atoms, with the proviso that said oligomer must possess at least one acrylate or methacrylate terminal group; (ii) from 20 to 50 percent, based on total weight of the composition, of an acrylate or methacrylate terminated reactive diluent of from 11 to 22 carbon atoms; and (iii) from 0.5 to 5 percent, based upon the total weight of the composition, of a photoinitiator selected from the goup consisting of alpha-hydroxycyclohexylphenyl ketone, diethoxyacetophenone, 1-(4-dodecylphenyl)-2-hydroxy-2-methyl-propan-1-one, 2-hydroxy-2-methyl-1-phenyl-propan-1-one, and mixtures thereof; wherein R 1 and R 2 are free of aromatic, ether, or ester functional groups.