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US4768345A Expired / Lapsed US ⏱️ 0.0 years remaining

Continuous thermal energy delivery from a periodically active energy source

Assignee: Gas Technology Institute
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Filing: 1987-07-28
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Granted: 1988-09-06
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Expires: 2007-07-28
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Abstract

Abstract Continuous thermal energy delivery from a cyclically active thermal energy source having an ON period substantially exceeding an OFF period by passing working fluid through a central working fluid conduit passing through a containment means forming an annular chamber therewith, the annular chamber substantially filled with a liquid-solid phase change thermal energy storage material having a high specific heat in the liquid phase. During insolation, thermal energy superheats the thermal energy storage material and is conducted therethrough to heat the working fluid. During eclipse the superheated thermal energy storage material transmits heat to the working fluid and formation of solid phase of the thermal energy storage material releases heat of fusion adjacent the working fluid conduit for additional supply of heat to the working fluid. A thermal gradient is maintained across the thickness of the thermal energy storage material.

Inventors

  • 👤 Alan Kardas

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-30 11:20
CPC Classifications
F; F03; F03G; F03G6/00; F03G6/06; F03G6/065; F03G6/067; F03G6/071; F03G6/098; F03G6/108; F03G6/111; F24; F24S; F24S20/00; F24S20/20; F24S60/00; F24S60/10; Y; Y02; Y02E; Y02E10/00; Y02E10/40; Y02E10/46

Claims Analysis

Total Claims: 22
Claim 1
Independent Claim 216 words
An apparatus for continuous delivery of relatively uniform predetermined thermal energy from a cyclically active thermal energy source having an ON period substantially exceeding an OFF period in duration to an energy utilization sector of a closed working fluid conduit loop additionally comprising an energy supply sector, said energy supply sector comprising: working fluid conduit means for containment and transport of said working fluid from a lower temperature outlet of a thermal utilization means to a higher temperature inlet of said thermal energy utilization means; tubular outer containment means spaced from and surrounding at least a portion of said energy supply sector of said working fluid conduit means forming an annular chamber between said working fluid conduit means and said tubular outer containment means; liquid-solid phase change thermal energy transmission and storage material having a high specific heat in the liquid phase substantially filling said annular chamber; said annular chamber having a width between said working fluid conduit means and said outer containment means and a length consistent with said continuous delivery of relatively uniform predetermined thermal energy based upon density, heat of fusion, specific heat, and thermal conductivity of said thermal transmission and storage material; and means for protection of said outer containment means from thermal losses during inactivity of said periodically active energy source.
Claim 2
Independent Claim 216 words
An apparatus for continuous delivery of relatively uniform predetermined thermal energy from a cyclically active thermal energy source having an ON period substantially exceeding an OFF period in duration to an energy utilization sector of a closed working fluid conduit loop additionally comprising an energy supply sector, said energy supply sector comprising: working fluid conduit means for containment and transport of said working fluid from a lower temperature outlet of a thermal utilization means to a higher temperature inlet of said thermal energy utilization means; tubular outer containment means spaced from and surrounding at least a portion of said energy supply sector of said working fluid conduit means forming an annular chamber between said working fluid conduit means and said tubular outer containment means; liquid-solid phase change thermal energy transmission and storage material having a high specific heat in the liquid phase substantially filling said annular chamber; said annular chamber having a width between said working fluid conduit means and said outer containment means and a length consistent with said continuous delivery of relatively uniform predetermined thermal energy based upon density, heat of fusion, specific heat, and thermal conductivity of said thermal transmission and storage material; and means for protection of said outer containment means from thermal losses during inactivity of said periodically active energy source.
Claim 3
Dependent Claim 89 words
An apparatus of claim 1 wherein said width of said annular chamber is determined by the relation: ##EQU3## wherein the damping factor F is a ratio of the maximum admissible cyclic temperature amplitude of said working fluid entering said energy utilization sector, total cycle duration τ o in hours, said thermal energy transmission and storage material thermal conductivity k s (Btu/h ft deg F.), effective specific heat including the heat of fusion c ps (Btu/lb deg F.), density ρ s (lb/ft 3 ), and said annular width Δr (ft).
Claim 4
Dependent Claim 20 words
An apparatus of claim 2 wherein the radius of said working fluid conduit is fixed by said energy utilization sector.
Claim 5
Dependent Claim 98 words
An apparatus of claim 3 wherein said length of said annular chamber is obtained by dtermination of the required mass of said energy transmission and storage material by the relation: ##EQU4## wherein m is the total mass of said energy transmission and storage material, lbs, Q.is the rated energy delivery rate to said energy utilization sector by said working fluid, Btu/h, P e is the duration of the eclipse period, hr., C ps is the effective specific heat as defined in claim 2, Δt is the bulk of said material temperature drop during an eclipse period, deg F.
Claim 6
Dependent Claim 20 words
An apparatus of claim 1 wherein said working fluid conduit means and said containment means have substantially circular cross sections.
Claim 7
Dependent Claim 27 words
An apparatus of claim 1 wherein said liquid-solid phase change thermal energy storage material forms a thin layer of solid phase adjacent said working fluid conduit means.
Claim 8
Dependent Claim 24 words
An apparatus of claim 1 wherein said thermal energy storage material has a specific heat in the liquid phase of above about 0.6 Btu/lb°F.
Claim 9
Dependent Claim 20 words
An apparatus of claim 1 wherein said thermal energy storage material has a thermal conductivity of above about 1 Btu/hft°F.
Claim 10
Dependent Claim 21 words
An apparatus of claim 1 wherein said thermal energy storage material has a heat of fusion of above about 300 Btu/lb.
Claim 11
Dependent Claim 54 words
An apparatus of claim 1 wherein said thermal energy storage material has a specific heat in the liquid phase of about 0.6 to about 0.8 Btu/lb°F.; said thermal energy storage material has a thermal conductivity of about 1 to about 5 Btu/hft°F.; and a heat of fusion of about 350 to about 450 Btu/lb.
Claim 12
Dependent Claim 14 words
An apparatus of claim 1 wherein said thermal energy storage material is lithium hydroxide.
Claim 13
Dependent Claim 17 words
An apparatus of claim 1 wherein said thermal energy utilization means is a turbine power generation means.
Claim 14
Dependent Claim 15 words
An apparatus of claim 1 additionally comprising a solar concentrator focused on said containment means.
Claim 15
Dependent Claim 284 words
A process for continuous delivery of relatively uniform predetermined thermal energy from a cyclically active thermal energy source having an ON period substantially exceeding an OFF period in duration, said process comprising: passing working fluid from a lower temperature outlet of a thermal utilization sector of a continuous working fluid conduit loop to a higher temperature inlet to said thermal utilization sector, said working fluid conduit passing through an energy supply sector in the central portion of an outer containment means forming an annular chamber therewith, said annular chamber substantially filled with a liquid-solid phase change thermal energy transmission and storage material having a high specific heat in the liquid phase and having a width and length consistent with said continuous delivery of relatively uniform predetermined thermal energy based upon density, heat of fusion, specific heat, and thermal conductivity of said thermal transmission storage material; exposing said outer containment means during cyclic insolation to said thermal energy source superheating said thermal energy storage material in the liquid phase to a temperature above said higher temperature inlet to said thermal utilization sector; passing a portion of thermal energy from said thermal energy transmission and storage material inwardly to heat said working fluid and to reduce solid phase of said thermal energy storage material adjacent said working fluid conduit during cyclic insolation; optionally but not necessarily covering said containment means during periodic eclipse to reduce loss of thermal energy; and passing a portion of said thermal energy from said thermal energy storage material inwardly to heat said working fluid and further heating said working fluid by release of heat of fusion upon solidification of said thermal energy storage material adjacent said working fluid condiut during eclipse.
Claim 16
Dependent Claim 284 words
A process for continuous delivery of relatively uniform predetermined thermal energy from a cyclically active thermal energy source having an ON period substantially exceeding an OFF period in duration, said process comprising: passing working fluid from a lower temperature outlet of a thermal utilization sector of a continuous working fluid conduit loop to a higher temperature inlet to said thermal utilization sector, said working fluid conduit passing through an energy supply sector in the central portion of an outer containment means forming an annular chamber therewith, said annular chamber substantially filled with a liquid-solid phase change thermal energy transmission and storage material having a high specific heat in the liquid phase and having a width and length consistent with said continuous delivery of relatively uniform predetermined thermal energy based upon density, heat of fusion, specific heat, and thermal conductivity of said thermal transmission storage material; exposing said outer containment means during cyclic insolation to said thermal energy source superheating said thermal energy storage material in the liquid phase to a temperature above said higher temperature inlet to said thermal utilization sector; passing a portion of thermal energy from said thermal energy transmission and storage material inwardly to heat said working fluid and to reduce solid phase of said thermal energy storage material adjacent said working fluid conduit during cyclic insolation; optionally but not necessarily covering said containment means during periodic eclipse to reduce loss of thermal energy; and passing a portion of said thermal energy from said thermal energy storage material inwardly to heat said working fluid and further heating said working fluid by release of heat of fusion upon solidification of said thermal energy storage material adjacent said working fluid condiut during eclipse.
Claim 17
Dependent Claim 31 words
The process of claim 14 wherein the time of said insolation is about 50 to about 70 minutes and the time of said eclipse is about 25 to about 45 minutes.
Claim 18
Dependent Claim 20 words
The process of claim 15 wherein a thermal gradient is maintained across the thickness of said thermal energy storage material.
Claim 19
Dependent Claim 20 words
The process of claim 14 wherein a thin layer of said solid phase is formed on said working fluid conduit.
Claim 20
Dependent Claim 21 words
The process of claim 14 wherein a solar concentrator focuses thermal energy from said thermal energy source on said containment means.
Claim 21
Dependent Claim 54 words
The process of claim 14 wherein said thermal energy storage material has a specific heat in the liquid phase of about 0.6 to about 0.8 Btu/lb°F.; said thermal energy storage material has a thermal conductivity of about 1 to about 5 Btu/hft°F.; and a heat of fusion of about 350 to about 450 Btu/lb.
Claim 22
Dependent Claim 14 words
The process of claim 14 wherein said thermal energy storage material is lithium hydroxide.

References Cited (Backward Citations)

US3548930A Cited
US3903699A Cited
US4091622A Cited
US4172491A Cited
US4304218A Cited
US4469088A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1991-09-06 1992-03-07 1992-09-06 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1995-09-06 1996-03-07 1996-09-06 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1999-09-06 2000-03-07 2000-09-06 $7700.00 Window Closed / Lapsed

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