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US4735979A Expired / Lapsed US ⏱️ 0.0 years remaining

Auto-adhering one-component RTV silicone sealant composition utilizing an adhesion promoter

Assignee: Henkel Loctite Corp
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Filing: 1985-04-04
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Granted: 1988-04-05
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Expires: 2005-04-04
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Abstract

Abstract An auto-adhering one-component room temperature vulcanizable silicone sealant composition generally utilizing a di-substituted mixed oxime-alkoxysilyalkyl area adhesion promoter compound. The sealant has low odor, is non-corrosive to ferrous or aluminum substrates, has good adhesion to many types of substrates, and eliminates the need for a silicone resin primer. In addition, it exhibits surprisingly good adhesion to oil contaminated surfaces.

Inventors

  • 👤 M. Dale Beers
  • 👤 James E. Thompson

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-01 22:27
CPC Classifications
C; C08; C08K; C08K5/00; C08K5/54; C08K5/544; C08K5/5465; C07; C07F; C07F7/00; C07F7/02; C07F7/08; C07F7/18; C07F7/1804; C08L; C08L83/00; C08L83/04; C08G; C08G77/00; C08G77/04; C08G77/14; C08G77/16; C08G77/20; C08G77/22; C08G77/24; C08G77/70; Y; Y10; Y10S; Y10S528/00; Y10S528/901

Claims Analysis

Total Claims: 10
Claim 1
Independent Claim 305 words
A room temperature vulcanizable silicone rubber composition comprising: from about 25 to 90 percent by weight based upon the total weight of the composition of a devolatilized silanol terminated diorgano-siloxane base polymer having a viscosity from about 2,000 to about 250,000 centipoises at 25° C. wherein said organo groups are the same or different and are selected from the group consisting of an alkyl having from 1 to 8 carbon atoms, a cycloalkyl having from 4 to 7 carbon atoms, an alkenyl having from 2 to 8 carbon atoms, an aryl or an alkyl substituted aryl having from 6 to 14 carbon atoms, and a fluoroalkyl having from 1 to 8 carbon atoms; from about 0 to about 40 percent by weight based upon the total weight of said composition of a devolatilized diorganopolysiloxane fluid plasticizer terminated with triorganosiloxy groups, said organo groups selected from the group consisting of alkyl having 1 to 8 carbon atoms, cycloalkyl having 4 to 7 carbon atoms, alkenyl having 2 to 8 carbon atoms, aryl or alkyl substituted aryl having 6 to 14 carbon atoms and fluoroalkyl having 1 to 8 carbon atoms said plasticizer having a viscosity from about 50 to about 100,000 centipoises at 25° C.; and 0.5 to 3 percent by weight of an adhesion promoter of the formula: ##STR7## wherein R 1 and R 6 are independently non-aromatic hydrocarbyl or halohydrocarbyl groups or carboxyalkyl groups having 1 to 10 carbon atoms; R 2 , R 3 , R 7 and R 8 are independently H, hydrocarbyl, halohydrocarbyl or carboxyalkyl having 1 to 10 carbon atoms; R 4 and R 5 are divalent hydrocarbyl or halohydrocarbyl groups of 1 to 10 carbon atoms; a and e are 0 to 2; b and f are 1 to 3; q and h are 0 or 1 and a+b+g=f+e+h=3.
Claim 2
Dependent Claim 305 words
A room temperature vulcanizable silicone rubber composition comprising: from about 25 to 90 percent by weight based upon the total weight of the composition of a devolatilized silanol terminated diorgano-siloxane base polymer having a viscosity from about 2,000 to about 250,000 centipoises at 25° C. wherein said organo groups are the same or different and are selected from the group consisting of an alkyl having from 1 to 8 carbon atoms, a cycloalkyl having from 4 to 7 carbon atoms, an alkenyl having from 2 to 8 carbon atoms, an aryl or an alkyl substituted aryl having from 6 to 14 carbon atoms, and a fluoroalkyl having from 1 to 8 carbon atoms; from about 0 to about 40 percent by weight based upon the total weight of said composition of a devolatilized diorganopolysiloxane fluid plasticizer terminated with triorganosiloxy groups, said organo groups selected from the group consisting of alkyl having 1 to 8 carbon atoms, cycloalkyl having 4 to 7 carbon atoms, alkenyl having 2 to 8 carbon atoms, aryl or alkyl substituted aryl having 6 to 14 carbon atoms and fluoroalkyl having 1 to 8 carbon atoms said plasticizer having a viscosity from about 50 to about 100,000 centipoises at 25° C.; and 0.5 to 3 percent by weight of an adhesion promoter of the formula: ##STR7## wherein R 1 and R 6 are independently non-aromatic hydrocarbyl or halohydrocarbyl groups or carboxyalkyl groups having 1 to 10 carbon atoms; R 2 , R 3 , R 7 and R 8 are independently H, hydrocarbyl, halohydrocarbyl or carboxyalkyl having 1 to 10 carbon atoms; R 4 and R 5 are divalent hydrocarbyl or halohydrocarbyl groups of 1 to 10 carbon atoms; a and e are 0 to 2; b and f are 1 to 3; q and h are 0 or 1 and a+b+g=f+e+h=3.
Claim 3
Dependent Claim 12 words
A composition as in claim 1 where g and h are 0.
Claim 4
Dependent Claim 16 words
A composition as in claim 2 where R 1 and R 6 are methyl or ethyl.
Claim 5
Dependent Claim 18 words
A composition as in claim 1 where R 4 and R 5 are --(CH 2 ) 3 --.
Claim 6
Dependent Claim 21 words
The composition of claim 1 further comprising an effective amount of a thixotropic agent to impart non-sag properties to the composition.
Claim 7
Dependent Claim 16 words
A composition as in claim 1 further comprising an oxime crosslinking agent and an organotin catalyst.
Claim 8
Dependent Claim 26 words
A composition as in claim 6 wherein the said catalyst is present in an amount in the range of 0.01-0.5 percent based on total composition weight.
Claim 9
Dependent Claim 29 words
A composition as in claim 6 wherein the catalyst is selected from dibutyltin dilaurate; dibutyltin diacetate; tin octoate; dimethyltindibutyrate; triethyl tin tartrate; tin oleate; dibutyltin oxide and dimethyltinbis neodecanoate.
Claim 10
Dependent Claim 17 words
A composition as in claim 1 further comprising between 1% and 60% by weight of a filler.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1991-04-05 1991-10-05 1992-04-05 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1995-04-05 1995-10-05 1996-04-05 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1999-04-05 1999-10-05 2000-04-05 $7700.00 Window Closed / Lapsed

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