Patent US4538104A successfully refreshed from Google Patents.
Patent US4735979A successfully refreshed from Google Patents.
US4735979A
Expired / Lapsed
US
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Auto-adhering one-component RTV silicone sealant composition utilizing an adhesion promoter
Assignee: Henkel Loctite Corp
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Filing: 1985-04-04
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Granted: 1988-04-05
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Expires: 2005-04-04
Abstract
Abstract An auto-adhering one-component room temperature vulcanizable silicone sealant composition generally utilizing a di-substituted mixed oxime-alkoxysilyalkyl area adhesion promoter compound. The sealant has low odor, is non-corrosive to ferrous or aluminum substrates, has good adhesion to many types of substrates, and eliminates the need for a silicone resin primer. In addition, it exhibits surprisingly good adhesion to oil contaminated surfaces.
Inventors
- 👤 M. Dale Beers
- 👤 James E. Thompson
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-01 22:27
CPC Classifications
C; C08; C08K; C08K5/00; C08K5/54; C08K5/544; C08K5/5465; C07; C07F; C07F7/00; C07F7/02; C07F7/08; C07F7/18; C07F7/1804; C08L; C08L83/00; C08L83/04; C08G; C08G77/00; C08G77/04; C08G77/14; C08G77/16; C08G77/20; C08G77/22; C08G77/24; C08G77/70; Y; Y10; Y10S; Y10S528/00; Y10S528/901
Claims Analysis
Total Claims: 10
Claim 1
Independent Claim
305 words
A room temperature vulcanizable silicone rubber composition comprising: from about 25 to 90 percent by weight based upon the total weight of the composition of a devolatilized silanol terminated diorgano-siloxane base polymer having a viscosity from about 2,000 to about 250,000 centipoises at 25° C. wherein said organo groups are the same or different and are selected from the group consisting of an alkyl having from 1 to 8 carbon atoms, a cycloalkyl having from 4 to 7 carbon atoms, an alkenyl having from 2 to 8 carbon atoms, an aryl or an alkyl substituted aryl having from 6 to 14 carbon atoms, and a fluoroalkyl having from 1 to 8 carbon atoms; from about 0 to about 40 percent by weight based upon the total weight of said composition of a devolatilized diorganopolysiloxane fluid plasticizer terminated with triorganosiloxy groups, said organo groups selected from the group consisting of alkyl having 1 to 8 carbon atoms, cycloalkyl having 4 to 7 carbon atoms, alkenyl having 2 to 8 carbon atoms, aryl or alkyl substituted aryl having 6 to 14 carbon atoms and fluoroalkyl having 1 to 8 carbon atoms said plasticizer having a viscosity from about 50 to about 100,000 centipoises at 25° C.; and 0.5 to 3 percent by weight of an adhesion promoter of the formula: ##STR7## wherein R 1 and R 6 are independently non-aromatic hydrocarbyl or halohydrocarbyl groups or carboxyalkyl groups having 1 to 10 carbon atoms; R 2 , R 3 , R 7 and R 8 are independently H, hydrocarbyl, halohydrocarbyl or carboxyalkyl having 1 to 10 carbon atoms; R 4 and R 5 are divalent hydrocarbyl or halohydrocarbyl groups of 1 to 10 carbon atoms; a and e are 0 to 2; b and f are 1 to 3; q and h are 0 or 1 and a+b+g=f+e+h=3.
Claim 2
Dependent Claim
305 words
A room temperature vulcanizable silicone rubber composition comprising: from about 25 to 90 percent by weight based upon the total weight of the composition of a devolatilized silanol terminated diorgano-siloxane base polymer having a viscosity from about 2,000 to about 250,000 centipoises at 25° C. wherein said organo groups are the same or different and are selected from the group consisting of an alkyl having from 1 to 8 carbon atoms, a cycloalkyl having from 4 to 7 carbon atoms, an alkenyl having from 2 to 8 carbon atoms, an aryl or an alkyl substituted aryl having from 6 to 14 carbon atoms, and a fluoroalkyl having from 1 to 8 carbon atoms; from about 0 to about 40 percent by weight based upon the total weight of said composition of a devolatilized diorganopolysiloxane fluid plasticizer terminated with triorganosiloxy groups, said organo groups selected from the group consisting of alkyl having 1 to 8 carbon atoms, cycloalkyl having 4 to 7 carbon atoms, alkenyl having 2 to 8 carbon atoms, aryl or alkyl substituted aryl having 6 to 14 carbon atoms and fluoroalkyl having 1 to 8 carbon atoms said plasticizer having a viscosity from about 50 to about 100,000 centipoises at 25° C.; and 0.5 to 3 percent by weight of an adhesion promoter of the formula: ##STR7## wherein R 1 and R 6 are independently non-aromatic hydrocarbyl or halohydrocarbyl groups or carboxyalkyl groups having 1 to 10 carbon atoms; R 2 , R 3 , R 7 and R 8 are independently H, hydrocarbyl, halohydrocarbyl or carboxyalkyl having 1 to 10 carbon atoms; R 4 and R 5 are divalent hydrocarbyl or halohydrocarbyl groups of 1 to 10 carbon atoms; a and e are 0 to 2; b and f are 1 to 3; q and h are 0 or 1 and a+b+g=f+e+h=3.
Claim 3
Dependent Claim
12 words
A composition as in claim 1 where g and h are 0.
Claim 4
Dependent Claim
16 words
A composition as in claim 2 where R 1 and R 6 are methyl or ethyl.
Claim 5
Dependent Claim
18 words
A composition as in claim 1 where R 4 and R 5 are --(CH 2 ) 3 --.
Claim 6
Dependent Claim
21 words
The composition of claim 1 further comprising an effective amount of a thixotropic agent to impart non-sag properties to the composition.
Claim 7
Dependent Claim
16 words
A composition as in claim 1 further comprising an oxime crosslinking agent and an organotin catalyst.
Claim 8
Dependent Claim
26 words
A composition as in claim 6 wherein the said catalyst is present in an amount in the range of 0.01-0.5 percent based on total composition weight.
Claim 9
Dependent Claim
29 words
A composition as in claim 6 wherein the catalyst is selected from dibutyltin dilaurate; dibutyltin diacetate; tin octoate; dimethyltindibutyrate; triethyl tin tartrate; tin oleate; dibutyltin oxide and dimethyltinbis neodecanoate.
Claim 10
Dependent Claim
17 words
A composition as in claim 1 further comprising between 1% and 60% by weight of a filler.
References Cited (Backward Citations)
US3133891A
Cited
US3035016A
Cited
US3185576A
Cited
US3208971A
Cited
US3382205A
Cited
US3517001A
Cited
US3541044A
Cited
US3927042A
Cited
US3776933A
Cited
US3837878A
Cited
US3847848A
Cited
US4100129A
Cited
US3962160A
Cited
US4323489A
Cited
US4356116A
Cited
US4395526A
Cited
FR2548200A1
Cited
US4506058A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1991-04-05 | 1991-10-05 | 1992-04-05 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1995-04-05 | 1995-10-05 | 1996-04-05 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1999-04-05 | 1999-10-05 | 2000-04-05 | $7700.00 | Window Closed / Lapsed |