US4731393A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Process for chemically bonding stabilizers to polymers
Assignee: BASF Corp
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Filing: 1986-06-11
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Granted: 1988-03-15
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Expires: 2006-06-11
Abstract
Abstract s-Triazine compounds, the molecule of which contains at least one ethylenically unsaturated group and at least one 2,2,6,6-tetramethylpiperidine group can be grafted onto organic polymers, in particular onto polyolefines, in the presence of free-radical formers or by means of irradiation. Examples of free-radical formers are peroxy or azo compounds. If polyunsaturated piperidine-triazine compounds are used, it is also possible to achieve crosslinking of the polymer, particularly in the case of polyethylene.
Inventors
- 👤 Friedrich Karrer
- 👤 Peter Hofmann
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-28 08:23
CPC Classifications
C; C08; C08F; C08F255/00; C08F291/00
Claims Analysis
Total Claims: 17
Claim 1
Independent Claim
566 words
A process for chemically bonding polyalkylpiperidine stabilizers to polyolefins or olefin copolymers by grafting ethylenically unsaturated polyalkylpiperidine derivatives, by the action of free radicals produced by chemical or physical means, onto the polyolefin or copolymer, said derivative being a compound of the formula I ##STR28## in which R 1 is hydrogen, oxyl oxygen, C 1 -C 12 -alkyl, C 3 -C 7 -alkenyl, C 7 -C 11 -phenylalkyl, cyanomethyl, C 2 -C 18 -alkanoyl or C 3 -C 18 -alkenoyl or a group --CON(R 2 )(R 3 ) or --CH 2 --CH(R 4 )--OH in which R 2 is C 1 -C 12 -alkyl, allyl, cyclohexyl, benzyl, phenyl or C 7 -C 12 -alkylphenyl and R 3 is hydrogen, C 1 -C 12 -alkyl, allyl or benzyl or R 2 and R 3 , together with the N atom to which they are attached, form a 5-membered or 6-membered heterocyclic ring and R 4 is hydrogen, C 1 -C 12 -alkyl, phenyl, C 2 -C 13 -alkoxymethyl or phenoxymethyl, X is a divalent group of the formula --O--, --N(R 5 )--, --NH--CH 2 --CH 2 --, --NH--(CH 2 ) 2 --O--, --NH(CH 2 ) 3 --O-- or --N(R 5 )--R 7 --N(R.sup. 6)-- in which R 5 is hydrogen, C 1 -C 12 -alkyl, C 3 -C 7 -alkenyl, cyclohexyl, C 3 -C 12 -alkoxyalkyl, C 5 -C 12 -alkenoxyalkyl, C 4 -C 12 -dialkylaminoalkyl, a group --CH 2 --CH(R 4 )--OH, benzyl or a group of the formula ##STR29## or of the formula ##STR30## R 6 is hydrogen, C 1 -C 12 -alkyl, C 3 -C 7 -alkenyl, cyclohexyl, a group --CH 2 --CH(R 4 )--OH are group of the formula ##STR31## R 7 is C 2 -C 12 -alkylene which can be interrupted by 1, 2 or 3 of the groups --O-- or --N(R 6 )--, C 6 -C 14 -cycloalkylene or cycloalkylenedialkylene, Y is a divalent group of the formula --O-- or --N(R 6 )-- and A and B, independently of one another, (a) are a group of the formula R 8 O-- or (R 9 )(R 10 )N-- in which R 8 is C 1 -C 12 -alkyl, C 3 -C 7 -alkenyl, C 3 -C 12 -alkoxyalkyl, C 4 -C 12 -dialkylaminoalkyl, cyclohexyl, benzyl, phenyl or C 7 -C 12 -alkylphenyl, R 9 is C 1 -C 12 -alkyl, C 3 -C 7 -alkenyl, C 5 -C 8 -cycloalkyl, C 3 -C 12 -alkoxyalkyl, C 5 -C 12 -alkenoxyalkyl, C 4 -C 12 -dialkylaminoalkyl, a group --CH 2 --CH(R 4 )--OH, phenyl, C 7 -C 12 -alkylphenyl or C 7 -C 11 -phenylalkyl and R 10 is hydrogen, C 1 -C 12 -alkyl, C 3 -C 7 -alkenyl, C 5 -C 8 -cycloalkyl, C 3 -C 12 -alkoxyalkyl, C 5 -C 12 -alkenoxyalkyl, C 4 -C 12 -dialkylaminoalkyl, C 2 -C 12 -alkanoyl, C 3 -C 12 -alkenoyl, a group --CH 2 --CH(R 4 )--OH or C 7 -C 11 -phenylalkyl, or R 9 and R 10 , together with the N atom to which they are attached, form a 5-membered or 6-membered heterocyclic ring, or (b) are a group of the formula ##STR32## in which at least three of the groups R 1 , R 2 , R 3 , R 5 , R 6 , R 8 , R 9 or R 10 is an alkenyl or alkenoyl radical.
Claim 2
Dependent Claim
566 words
A process for chemically bonding polyalkylpiperidine stabilizers to polyolefins or olefin copolymers by grafting ethylenically unsaturated polyalkylpiperidine derivatives, by the action of free radicals produced by chemical or physical means, onto the polyolefin or copolymer, said derivative being a compound of the formula I ##STR28## in which R 1 is hydrogen, oxyl oxygen, C 1 -C 12 -alkyl, C 3 -C 7 -alkenyl, C 7 -C 11 -phenylalkyl, cyanomethyl, C 2 -C 18 -alkanoyl or C 3 -C 18 -alkenoyl or a group --CON(R 2 )(R 3 ) or --CH 2 --CH(R 4 )--OH in which R 2 is C 1 -C 12 -alkyl, allyl, cyclohexyl, benzyl, phenyl or C 7 -C 12 -alkylphenyl and R 3 is hydrogen, C 1 -C 12 -alkyl, allyl or benzyl or R 2 and R 3 , together with the N atom to which they are attached, form a 5-membered or 6-membered heterocyclic ring and R 4 is hydrogen, C 1 -C 12 -alkyl, phenyl, C 2 -C 13 -alkoxymethyl or phenoxymethyl, X is a divalent group of the formula --O--, --N(R 5 )--, --NH--CH 2 --CH 2 --, --NH--(CH 2 ) 2 --O--, --NH(CH 2 ) 3 --O-- or --N(R 5 )--R 7 --N(R.sup. 6)-- in which R 5 is hydrogen, C 1 -C 12 -alkyl, C 3 -C 7 -alkenyl, cyclohexyl, C 3 -C 12 -alkoxyalkyl, C 5 -C 12 -alkenoxyalkyl, C 4 -C 12 -dialkylaminoalkyl, a group --CH 2 --CH(R 4 )--OH, benzyl or a group of the formula ##STR29## or of the formula ##STR30## R 6 is hydrogen, C 1 -C 12 -alkyl, C 3 -C 7 -alkenyl, cyclohexyl, a group --CH 2 --CH(R 4 )--OH are group of the formula ##STR31## R 7 is C 2 -C 12 -alkylene which can be interrupted by 1, 2 or 3 of the groups --O-- or --N(R 6 )--, C 6 -C 14 -cycloalkylene or cycloalkylenedialkylene, Y is a divalent group of the formula --O-- or --N(R 6 )-- and A and B, independently of one another, (a) are a group of the formula R 8 O-- or (R 9 )(R 10 )N-- in which R 8 is C 1 -C 12 -alkyl, C 3 -C 7 -alkenyl, C 3 -C 12 -alkoxyalkyl, C 4 -C 12 -dialkylaminoalkyl, cyclohexyl, benzyl, phenyl or C 7 -C 12 -alkylphenyl, R 9 is C 1 -C 12 -alkyl, C 3 -C 7 -alkenyl, C 5 -C 8 -cycloalkyl, C 3 -C 12 -alkoxyalkyl, C 5 -C 12 -alkenoxyalkyl, C 4 -C 12 -dialkylaminoalkyl, a group --CH 2 --CH(R 4 )--OH, phenyl, C 7 -C 12 -alkylphenyl or C 7 -C 11 -phenylalkyl and R 10 is hydrogen, C 1 -C 12 -alkyl, C 3 -C 7 -alkenyl, C 5 -C 8 -cycloalkyl, C 3 -C 12 -alkoxyalkyl, C 5 -C 12 -alkenoxyalkyl, C 4 -C 12 -dialkylaminoalkyl, C 2 -C 12 -alkanoyl, C 3 -C 12 -alkenoyl, a group --CH 2 --CH(R 4 )--OH or C 7 -C 11 -phenylalkyl, or R 9 and R 10 , together with the N atom to which they are attached, form a 5-membered or 6-membered heterocyclic ring, or (b) are a group of the formula ##STR32## in which at least three of the groups R 1 , R 2 , R 3 , R 5 , R 6 , R 8 , R 9 or R 10 is an alkenyl or alkenoyl radical.
Claim 3
Dependent Claim
11 words
A process according to claim 1, wherein the polymer is polypropylene.
Claim 4
Dependent Claim
14 words
A process according to claim 1, wherein the polymer is polyethylene or chlorinated polyethylene.
Claim 5
Dependent Claim
33 words
A process according to claim 1, wherein the free radicals are produced by adding a free-radical former to the polymer and by heating the polymer above the decomposition temperature of the free-radical former.
Claim 6
Dependent Claim
16 words
A process according to claim 4, wherein the free-radical former used is an organic peroxy compound.
Claim 7
Dependent Claim
16 words
A process according to claim 4, wherein the free-radical former used is an aliphatic azo compound.
Claim 8
Dependent Claim
25 words
A process according to claim 1, wherein the free radicals are produced by irradiating the polymer with high-energy radiation, in particular electron radiation or γ-rays.
Claim 9
Dependent Claim
21 words
The process according to claim 1, wherein a phenolic antioxidant is added to the polymer in addition to the derivative stabiliser.
Claim 10
Dependent Claim
22 words
A process according to claim 8, wherein the antioxidant added is a derivative of δ-(3,5-di-t.-butyl-4-hydroxyphenyl)-propionic acid, in particular the octadecyl ester thereof.
Claim 11
Dependent Claim
47 words
A process according to claim 1, wherein the substituent A or the substituents A and B in formula I are a group of the formula R 8 O-- or (R 9 )(R 10 )N-- in which R 8 and R 9 are C 3 -C 7 -alkenyl.
Claim 12
Dependent Claim
34 words
A process according to claim 10, wherein A and B are a group of the formula R 8 O-- or (R 9 )(R 10 )N-- in which R 8 and R 9 are allyl.
Claim 13
Dependent Claim
55 words
A process according to claim 1, wherein the substituent A in formula I is a group (R 9' ) (R 10' )N-- in which R 9' is C 3 -C 7 -alkenyl and R 10' is C 1 -C 12 -alkyl, cyclohexyl, hydroxyethyl, benzyl, C 2 -C 12 -alkanoyl or C 3 -C 5 -alkenoxyl.
Claim 14
Dependent Claim
70 words
A process according to claim 11, wherein the substituents A and B in formula I are a group R 8 O-- or (R 9 )(R 10 )N-- in which R 8 and R 9 are allyl and X is a group --N(R 5 )-- in which R 5 is a group of the formula ##STR33## and R 1 , R 7 and R 10 are as defined in claim 1.
Claim 15
Dependent Claim
40 words
A process according to claim 1, wherein R 1 in formula I is C 3 -C 7 -alkenyl, C 7 -C 11 -phenylalkyl, cyanomethyl, C 2 -C 18 -alkanoyl, C 3 -C 18 -alkenoyl or --CON(R 2 )(R 3 ).
Claim 16
Dependent Claim
10 words
The process of claim 1, wherein said derivative is ##STR34##
Claim 17
Dependent Claim
10 words
The process of claim 1, wherein said derivative is ##STR35##
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1991-03-15 | 1991-09-14 | 1992-03-15 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1995-03-15 | 1995-09-14 | 1996-03-15 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1999-03-15 | 1999-09-14 | 2000-03-15 | $7700.00 | Window Closed / Lapsed |