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US4731349A Expired / Lapsed US ⏱️ 0.0 years remaining

Process of producing alumina-titanium carbide ceramic body

Assignee: General Electric Co
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Filing: 1985-08-26
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Granted: 1988-03-15
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Expires: 2005-08-26
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Abstract

Abstract High-strength, fine-grain, multi-phase substantially crystalline sintered ceramic bodies are produced by a process comprising the steps of cold pressing, followed by sintering at a high temperature, of a mixture of different powdered ceramic materials containing non-inhibitory components and a source of inhibitory components that can chemically interact at elevated temperatures generate gases which hinder densification or form phases undesirable for sintering provided that there is also included in the mixture an amount of a source of a component co-reactive with the gases produced by the inhibitory components at elevated temperature to achieve efficient densification and retention of properties in the sintered body.

Inventors

  • 👤 Minyoung Lee
  • 👤 Lawrence E. Szala
  • 👤 Marcus P. Borom

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-06 11:27
CPC Classifications
C; C04; C04B; C04B35/00; C04B35/01; C04B35/10; C04B35/111; C04B35/117

Claims Analysis

Total Claims: 18
Claim 1
Independent Claim 199 words
In a process of making a multi-phase, substantially crystalline, sintered ceramic body, consisting essentially of (i) preparing a mixture consisting essentially of 40% to 80% by weight aluminum oxide powder and from about 20% by weight to about 60% by weight titanium carbide powder, (ii) consolidating said mixture under pressure to produce a pressed powder body; (iii) heating said body in an unconfined state to at least a sintering temperature; (iv) holding said body at sintering temperature for a period at least sufficiently long enough to achieve uniform temperature distribution throughout the body; and (v) recovering said sintered body, the improvement which consists essentially of including in said mixture a member selected from the group consisting of zirconium hydride, hafnium hydride, niobium hydride, tantalum hydride, titanium hydride, vanadium hydride and a mixture thereof, said member ranging from about 0.5% by weight to about 5% by weight of said mixture and being present in an amount sufficient to produce a sintered body having a minimum Rockwell A hardness of 91, said sintering temperature ranging from about 1650° C. to about 1950° C., said sintering being carrried out in a partial vacuum or atmosphere which has no significantly deleterious effect thereon.
Claim 2
Dependent Claim 199 words
In a process of making a multi-phase, substantially crystalline, sintered ceramic body, consisting essentially of (i) preparing a mixture consisting essentially of 40% to 80% by weight aluminum oxide powder and from about 20% by weight to about 60% by weight titanium carbide powder, (ii) consolidating said mixture under pressure to produce a pressed powder body; (iii) heating said body in an unconfined state to at least a sintering temperature; (iv) holding said body at sintering temperature for a period at least sufficiently long enough to achieve uniform temperature distribution throughout the body; and (v) recovering said sintered body, the improvement which consists essentially of including in said mixture a member selected from the group consisting of zirconium hydride, hafnium hydride, niobium hydride, tantalum hydride, titanium hydride, vanadium hydride and a mixture thereof, said member ranging from about 0.5% by weight to about 5% by weight of said mixture and being present in an amount sufficient to produce a sintered body having a minimum Rockwell A hardness of 91, said sintering temperature ranging from about 1650° C. to about 1950° C., said sintering being carrried out in a partial vacuum or atmosphere which has no significantly deleterious effect thereon.
Claim 3
Dependent Claim 13 words
A process as defined in claim 1 wherein said member is zirconium hydride.
Claim 4
Dependent Claim 13 words
A process as defined in claim 1 wherein said member is hafnium hydride.
Claim 5
Dependent Claim 33 words
A process as defined in claim 1 wherein step (iii) is carried out in helium at a heating rate of 50° C./min. up to 1500° C. followed by 400° C./min. to 1950° C.
Claim 6
Dependent Claim 19 words
The process according to claim 1 wherein said sintering temperature ranges from about 1850° C. to about 1920° C.
Claim 7
Dependent Claim 159 words
A process for producing a sintered body having a minimum Rockwell A hardness of 91 which consists essentially of forming a mixture of aluminum oxide, titanium carbide and a metal hydride into a compact, said metal hydride being selected from the group consisting of zirconium hydride, hafnium hydride, niobium hydride, tantalum hydride, titanium hydride, vanadium hydride and mixture thereof, said metal hydride ranging from about 0.5% by weight to about 5% by weight of the total amount of said aluminum oxide and titanium carbide and being present in an amount sufficient to produce said sintered body, said titanium carbide ranging from about 20% by weight to about 60% by weight of the total amount of said aluminum oxide and titanium carbide, and sintering said compact in an unconfined state at a temperature ranging from about 1650° C. to about 1950° C., said sintering being carried out in a partial vacuum or atmosphere which has no significantly deleterious effect thereon.
Claim 8
Dependent Claim 159 words
A process for producing a sintered body having a minimum Rockwell A hardness of 91 which consists essentially of forming a mixture of aluminum oxide, titanium carbide and a metal hydride into a compact, said metal hydride being selected from the group consisting of zirconium hydride, hafnium hydride, niobium hydride, tantalum hydride, titanium hydride, vanadium hydride and mixture thereof, said metal hydride ranging from about 0.5% by weight to about 5% by weight of the total amount of said aluminum oxide and titanium carbide and being present in an amount sufficient to produce said sintered body, said titanium carbide ranging from about 20% by weight to about 60% by weight of the total amount of said aluminum oxide and titanium carbide, and sintering said compact in an unconfined state at a temperature ranging from about 1650° C. to about 1950° C., said sintering being carried out in a partial vacuum or atmosphere which has no significantly deleterious effect thereon.
Claim 9
Dependent Claim 19 words
The process according to claim 6 wherein said sintering temperature ranges from about 1850° C. to about 1920° C.
Claim 10
Dependent Claim 21 words
The process according to claim 6 wherein said metal hydride ranges from about 1% by weight to about 2% by weight.
Claim 11
Dependent Claim 13 words
The process according to claim 6 wherein said metal hydride is zirconium hydride.
Claim 12
Dependent Claim 13 words
The process according to claim 6 wherein said metal hydride is hafnium hydride.
Claim 13
Dependent Claim 156 words
A process for sintering an aluminum oxide-base powder to produce a sintered body having a minimum Rockwell-A hardness of 91 which consists essentially of forming said powder into a compact, said powder containing titanium carbide in an amount sufficient to impede densification of said compact with time at elevated temperature, said powder containing a metal hydride selected from the group consisting of zirconium hydride, hafnium hydride, niobium hydride, tantalum hydride, titanium hydride, vanadium hydride and a mixture thereof, said metal hydride ranging from about 0.5% by weight to about 5% by weight of the total amount of said aluminum oxide and titanium carbide powders and being present in an amount sufficient to enable production of said sintered body, and sintering said compact in an unconfined state at a temperature ranging from about 1650° C. to about 1950° C., said sintering being carried out in a partial vacuum or atmosphere which has no significantly deleterious effect thereon.
Claim 14
Dependent Claim 156 words
A process for sintering an aluminum oxide-base powder to produce a sintered body having a minimum Rockwell-A hardness of 91 which consists essentially of forming said powder into a compact, said powder containing titanium carbide in an amount sufficient to impede densification of said compact with time at elevated temperature, said powder containing a metal hydride selected from the group consisting of zirconium hydride, hafnium hydride, niobium hydride, tantalum hydride, titanium hydride, vanadium hydride and a mixture thereof, said metal hydride ranging from about 0.5% by weight to about 5% by weight of the total amount of said aluminum oxide and titanium carbide powders and being present in an amount sufficient to enable production of said sintered body, and sintering said compact in an unconfined state at a temperature ranging from about 1650° C. to about 1950° C., said sintering being carried out in a partial vacuum or atmosphere which has no significantly deleterious effect thereon.
Claim 15
Dependent Claim 19 words
The process according to claim 11 wherein said sintering temperature ranges from about 1850° C. to about 1920° C.
Claim 16
Dependent Claim 21 words
The process according to claim 11 wherein said metal hydride ranges from about 1% by weight to about 2% by weight.
Claim 17
Dependent Claim 13 words
The process according to claim 11 wherein said metal hydride is zirconium hydride.
Claim 18
Dependent Claim 13 words
The process according to claim 11 wherein said metal hydride is hafnium hydride.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1991-03-15 1991-09-14 1992-03-15 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1995-03-15 1995-09-14 1996-03-15 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1999-03-15 1999-09-14 2000-03-15 $7700.00 Window Closed / Lapsed

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