US4515746A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Microcomposite of metal carbide and ceramic particles
Assignee: General Electric Co
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Filing: 1983-09-06
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Granted: 1985-05-07
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Expires: 2003-09-06
Abstract
Abstract A particulate mixture of ceramic powder, free carbon and a hydride of a metal selected from the group consisting of hafnium, niobium, tantalum, titanium, vanadium, zirconium and mixtures thereof is hot pressed decomposing the hydride and reacting the resulting metal with carbon producing a polycrystalline microcomposite comprised of a continuous phase of the carbide of the metal which encapsulates at least about 20% by volume of the ceramic particles and which either encapsulates or is intermixed with the balance of said ceramic particles.
Inventors
- 👤 Milivoj K. Brun
- 👤 Minyoung Lee
- 👤 Lawrence E. Szala
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-28 16:29
CPC Classifications
C; C04; C04B; C04B35/00; C04B35/622; C04B35/64; C04B35/645; C04B35/01; C04B35/10; C04B35/111; C04B35/48; C04B35/486; C04B35/488; C04B35/515; C04B35/56; C04B35/5607; C04B35/5611; C04B35/5622; C04B35/563; C04B35/65
Claims Analysis
Total Claims: 16
Claim 1
Independent Claim
235 words
A process for producing a polycrystalline microcomposite consisting essentially of a continuous interconnecting phase of a carbide of a metal selected from the group consisting of hafnium, niobium, tantalum, titanium, vanadium, zirconium and mixtures thereof and a phase of ceramic particles, said phases being distributed at least significantly uniformly in said microcomposite, said microcomposite having a density greater than 95% of the theoretical density for said composite, which consists essentially of forming a particulate mixture of elemental or free carbon, a hydride of a metal selected from the group consisting of hafnium, niobium, tantalum, titanium, vanadium, zirconium and mixtures thereof, and a ceramic powder, hot pressing the particulate mixture under a pressure of at least about 200 psi at a temperature ranging from about 1200° C. to about 2000° C. decomposing said hydride of said metal producing said metal and by-product gas which vaporizes away and reacting said metal with said carbon producing the carbide of said metal as a continuous interconnecting phase, said continuous metal carbide phase encapsulating at least about 20% by volume of said ceramic particles and either encapsulating or being intermixed with the balance of said ceramic particles, said process having no significant effect on said ceramic particles, said continuous interconnecting metal carbide phase ranging from about 20% by volume to about 80% by volume of said microcomposite and the balance of said microcomposite consisting essentially of particles of said ceramic.
Claim 2
Dependent Claim
235 words
A process for producing a polycrystalline microcomposite consisting essentially of a continuous interconnecting phase of a carbide of a metal selected from the group consisting of hafnium, niobium, tantalum, titanium, vanadium, zirconium and mixtures thereof and a phase of ceramic particles, said phases being distributed at least significantly uniformly in said microcomposite, said microcomposite having a density greater than 95% of the theoretical density for said composite, which consists essentially of forming a particulate mixture of elemental or free carbon, a hydride of a metal selected from the group consisting of hafnium, niobium, tantalum, titanium, vanadium, zirconium and mixtures thereof, and a ceramic powder, hot pressing the particulate mixture under a pressure of at least about 200 psi at a temperature ranging from about 1200° C. to about 2000° C. decomposing said hydride of said metal producing said metal and by-product gas which vaporizes away and reacting said metal with said carbon producing the carbide of said metal as a continuous interconnecting phase, said continuous metal carbide phase encapsulating at least about 20% by volume of said ceramic particles and either encapsulating or being intermixed with the balance of said ceramic particles, said process having no significant effect on said ceramic particles, said continuous interconnecting metal carbide phase ranging from about 20% by volume to about 80% by volume of said microcomposite and the balance of said microcomposite consisting essentially of particles of said ceramic.
Claim 3
Dependent Claim
11 words
The process according to claim 1 wherein said metal is hafnium.
Claim 4
Dependent Claim
11 words
The process according to claim 1 wherein said metal is niobium.
Claim 5
Dependent Claim
11 words
The process according to claim 1 wherein said metal is tantalum.
Claim 6
Dependent Claim
11 words
The process according to claim 1 wherein said metal is titanium.
Claim 7
Dependent Claim
11 words
The process according to claim 1 wherein said metal is vanadium.
Claim 8
Dependent Claim
11 words
The process according to claim 1 wherein said metal is zirconium.
Claim 9
Dependent Claim
16 words
The process according to claim 1 wherein said ceramic powder is Al 2 O 3 .
Claim 10
Dependent Claim
22 words
The process according to claim 1 wherein said continuous metal carbide phase encapsulates more than 95% by volume of said ceramic particles.
Claim 11
Dependent Claim
189 words
A process for producing a microcomposite consisting essentially of a continuous interconnecting phase of titanium carbide and a phase of ceramic particles, said phases being distributed at least significantly uniformly in said microcomposite, said microcomposite having a density greater than 95% of the theoretical density for said microcomposite, which consists essentially of forming a particulate mixture of free carbon, titanium hydride and a ceramic powder, hot pressing the particulate mixture under a pressure of at least about 200 psi at a temperature ranging from about 1200° C. to about 2000° C. decomposing said titanium hydride producing titanium and by-product gas which vaporizes away and reacting said titanium with said carbon producing titanium carbide as a continuous interconnecting phase, said continuous titanium carbide phase encapsulating at least about 20% by volume of said ceramic particles and either encapsulating or being intermixed with the balance of said ceramic particles, said process having no significant effect on said ceramic particles, said continuous titanium carbide phase ranging from about 20% by volume to about 30% by volume of said microcomposite and the balance of said microcomposite consisting essentially of particles of said ceramic.
Claim 12
Dependent Claim
189 words
A process for producing a microcomposite consisting essentially of a continuous interconnecting phase of titanium carbide and a phase of ceramic particles, said phases being distributed at least significantly uniformly in said microcomposite, said microcomposite having a density greater than 95% of the theoretical density for said microcomposite, which consists essentially of forming a particulate mixture of free carbon, titanium hydride and a ceramic powder, hot pressing the particulate mixture under a pressure of at least about 200 psi at a temperature ranging from about 1200° C. to about 2000° C. decomposing said titanium hydride producing titanium and by-product gas which vaporizes away and reacting said titanium with said carbon producing titanium carbide as a continuous interconnecting phase, said continuous titanium carbide phase encapsulating at least about 20% by volume of said ceramic particles and either encapsulating or being intermixed with the balance of said ceramic particles, said process having no significant effect on said ceramic particles, said continuous titanium carbide phase ranging from about 20% by volume to about 30% by volume of said microcomposite and the balance of said microcomposite consisting essentially of particles of said ceramic.
Claim 13
Dependent Claim
21 words
The process according to claim 10 wherein said titanium carbide phase encapsulates more than 90% by volume of said ceramic particles.
Claim 14
Dependent Claim
16 words
The process according to claim 10 wherein said ceramic particles are Al 2 O 3 .
Claim 15
Dependent Claim
22 words
The process according to claim 1 wherein said microcomposite has a density greater than 98% of the theoretical density for said microcomposite.
Claim 16
Dependent Claim
22 words
The process according to claim 10 wherein said microcomposite has a density greater than 98% of the theoretical density for said microcomposite.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1988-05-06 | 1988-11-05 | 1989-05-07 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1992-05-06 | 1992-11-05 | 1993-05-07 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1996-05-06 | 1996-11-05 | 1997-05-07 | $7700.00 | Window Closed / Lapsed |