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US4720452A Expired / Lapsed US ⏱️ 0.0 years remaining

Light-sensitive silver halide photographic material

Assignee: Konica Minolta Inc
•
Filing: 1986-08-07
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Granted: 1988-01-19
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Expires: 2006-08-07
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Abstract

Abstract A light-sensitive silver halide photographic material having silver halide emulsion layers on a support, wherein at least one layer of said silver halide emulsion layers contains surface latent image type mono-dispersed silver halide grains, and 50% or more of the silver halide grains contained in said at least one silver halide emulsion layer are regular surface latent image type mono-dispersed silver halide grains of tetradecahedral crystals whose external surfaces have crystal faces with Miller indices (100) and (111), the area ratio of said (100) face and said (111) face satisfying the relation represented by the correlation formula (I) shown below: correlation formula (I): ##EQU1## wherein K is the ratio between the intensities of respective diffraction lines attributable to the (200) face and the (222) face measured in X-ray diffraction analysis as set forth in the following formula ##EQU2##

Inventors

  • 👤 Hideki Takiguchi
  • 👤 Toshifumi Iijima
  • 👤 Toshihiko Yagi
  • 👤 Yoshihiro Haga

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-05 11:11
CPC Classifications
G; G03; G03C; G03C1/00; G03C1/005; G03C1/035; G03C2001/03558; G03C2001/0357

Claims Analysis

Total Claims: 11
Claim 1
Independent Claim 176 words
A light-sensitive silver halide photographic material having silver halide emulsion layers on a support, wherein at least one layer of said silver halide emulsion layers contains surface latent image-forming mono-dispersed silver halide grains, and 50% or more of the silver halide grains contained in said at least one silver halide emulsion layer are core-shell silver halide grains containing cores comprising a silver halide containing silver iodide and shells comprising primarily silver bromide covering said cores and are the surface latent image-forming mono-dispersed silver halide grains of tetradecahedral regular crystals whose external surfaces have crystal faces (100) and (111), the area ratio of said (100) face and said (111) face represented by: ##EQU12## and satisfying the following formula: ##EQU13## wherein K is the ratio between the intensities of respective diffraction lines attributable to the (200) face at 30.9° of the diffraction angle which corresponds to the (100) face and the (222) face at 55° of the diffraction angle which corresponds to the (111) face measured in X-ray diffraction analysis as set forth in the following formula ##EQU14##
Claim 2
Dependent Claim 176 words
A light-sensitive silver halide photographic material having silver halide emulsion layers on a support, wherein at least one layer of said silver halide emulsion layers contains surface latent image-forming mono-dispersed silver halide grains, and 50% or more of the silver halide grains contained in said at least one silver halide emulsion layer are core-shell silver halide grains containing cores comprising a silver halide containing silver iodide and shells comprising primarily silver bromide covering said cores and are the surface latent image-forming mono-dispersed silver halide grains of tetradecahedral regular crystals whose external surfaces have crystal faces (100) and (111), the area ratio of said (100) face and said (111) face represented by: ##EQU12## and satisfying the following formula: ##EQU13## wherein K is the ratio between the intensities of respective diffraction lines attributable to the (200) face at 30.9° of the diffraction angle which corresponds to the (100) face and the (222) face at 55° of the diffraction angle which corresponds to the (111) face measured in X-ray diffraction analysis as set forth in the following formula ##EQU14##
Claim 3
Dependent Claim 73 words
The light-sensitive silver halide photographic material according to claim 1, wherein the mono-dispersed silver halide grains which have uniform shapes of individual silver halide grains, have regular substantially uniformly and evenly arranged grain sizes, and have a grain size distribution as defined by the following formula: ##EQU15## wherein S is the standard deviation S, r is the mean grain size, ri represents the individual grain sizes and their numbers are represented by ni.
Claim 4
Dependent Claim 23 words
The light-sensitive silver halide photographic material according to claim 1, wherein said silver halide grains consist essentially of core-shell type silver halide grains.
Claim 5
Dependent Claim 27 words
The light-sensitive silver halide photographic material according to claim 1, wherein said silver halide grains comprise silver iodide at a level of 3 to 12 mole %.
Claim 6
Dependent Claim 27 words
The light-sensitive silver halide photographic material according to claim 4, wherein said silver halide grains comprise silver iodide at a level of 5 to 10 mole %.
Claim 7
Dependent Claim 26 words
The light-sensitive silver halide photographic material according to claim 3, wherein said core-shell type silver halide grains comprise shells having a thickness of 0.001 to 0.1μ.
Claim 8
Dependent Claim 44 words
The light-sensitive silver halide photographic material according to claim 2, wherein said silver halide grains consist essentially of core-shell type silver halide grains which consist essentially of cores comprising a silver halide containing silver iodide and shells comprising primarily silver bromide covering said cores.
Claim 9
Dependent Claim 26 words
The light-sensitive silver halide photographic material according to claim 7, wherein said core-shell type silver halide grains comprise shells having a thickness of 0.001 to 0.1μ.
Claim 10
Dependent Claim 27 words
The light-sensitive silver halide photographic material according to claim 8, wherein said silver halide grains comprise silver iodide at a level of 5 to 10 mole %.
Claim 11
Dependent Claim 27 words
The light-sensitive silver halide photographic material according to claim 7, wherein said silver halide grains comprise silver iodide at a level of 5 to 10 mole %.

References Cited (Backward Citations)

US4045228A Cited
US3885970A Cited
US4184877A Cited
US4496652A Cited
JPS55126234A Cited
US4469784A Cited
US4400463A Cited
US4414306A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1991-01-18 1991-07-20 1992-01-19 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1995-01-18 1995-07-20 1996-01-19 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1999-01-18 1999-07-20 2000-01-19 $7700.00 Window Closed / Lapsed

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