Radiation-sensitive positive working composition and material with aqueous-alkaline soluble acryamide or methacryamide copolymer having hydroxyl or carboxyl groups

Claim 2

A radiation-sensitive composition, comprising in admixture: (A) a polymeric binder which is insoluble in water and soluble in aqueous-alkaline solutions, said binder being present in an amount sufficient to form a homogenous layer which is resistant to etching solutions and mechanical abrasion; and (B) one of a 1,2-quinonediazide and a mixture comprising (1) an amount of a compound forming a strong acid under the action of actinic radiation, said amount being sufficient to form enough of said acid upon exposure of said mixture to cleave a cleavable compound therein that has at least one acid-cleavable C--O--C bond, and (2) an amount of a cleavable compound having at least one acid-cleavable C--O--C bond, the solubility of which in a liquid developer is increased by the action of acid, said amount being sufficient to render said composition soluble in an aqueous-alkaline solution; wherein component (B) is radiation-sensitive and is present in an amount sufficient to alter the solubility of said composition in an aqueous-alkaline solution after imagewise irradiation, and wherein said binder (A) is a copolymer comprising units represented by the formula: ##STR3## in which R' denotes a hydrogen atom or an alkyl group, and R" denotes a hydrogen atom or a methyl group and wherein said copolymer includes units formed from monomers wherein the units are selected from the group consisting of hydroxyl group-containing units, and carboxyl group-containing units and combinations of the above.

Claim 3

A radiation-sensitive composition as claimed in claim 1, wherein said hydroxyl group-containing monomer units are present in an amount corresponding to an OH number of from about 100 to about 400.

Claim 4

A radiation-sensitive composition as claimed in claim 1, wherein said carboxyl group-containing momomer units are present in an amount corresponding to an acid number of from about 50 to about 300.

Claim 5

A radiation-sensitive composition as claimed in claim 1, wherein said copolymer has a mean molecular weight of from about 500 to about 200,000.

Claim 6

A radiation-sensitive composition as claimed in claim 1, wherein said copolymer contains carboxyl group-containing monomer units selected from the group consisting of units of acrylic acid, methacrylic acid, maleic acid, itaconic acid, vinylbenzoic acid, 4-(acrylamido)benzoic acid and 4-(methacrylamido)benzoic acid.

Claim 7

A radiation-sensitive composition as claimed in claim 5, wherein said carboxyl group-containing monomer units are selected from the group consisting of acrylic acid and methacrylic acid units.

Claim 8

A radiation-sensitive composition as claimed in claim 1, wherein said copolymer contains hydroxyl group-containing monomer units selected from the group consisting of units containing aliphatic OH groups and units containing aromatic OH groups.

Claim 9

A radiation-sensitive composition as claimed in claim 7, wherein said units containing aliphatic OH groups are selected from the group consisting of hydroxyalkyl acrylates, hydroxyalkyl methacrylates, hydroxyalkoxyalkyl acrylates, hydroxyalkoxyalkyl methacrylates, glycerol monoacrylate, glycerol monomethacrylate, trimethylolpropane monoacrylate, trimethylolpropane monomethacrylate, hydroxyalkyl vinyl ether, and vinyl alcohol.

Claim 10

A radiation-sensitive composition as claimed in claim 8, wherein said copolymer includes additional units selected from the group consisting of styrene, a styrene derivative, an alkyl acrylate and an alkyl methacrylate.

Claim 11

A radiation-sensitive composition as claimed in claim 9, wherein said additional units are derived from an alkyl methacrylate having from 4 to 12 carbon atoms.

Claim 12

A radiation-sensitive composition as claimed in claim 7, wherein said units containing aromatic OH groups are selected from the group consisting of ##STR4## in which R 1 is selected from the group consisting of a hydrogen atom, an alkyl group, a halogen atom and a cyano group; Y is selected from substituted and unsubstituted mono- and binuclear aromatic groups; X denotes a divalent linking member; and p=0 or 1.

Claim 13

A radiation-sensitive composition as claimed in claim 11, wherein said units containing aromatic OH groups are selected from the group consisting of hydroxystyrene, an N-(hydroxyphenyl)acrylamide, an N-(hydroxyphenyl)methacrylamide, a hydroxyphenyl acrylate and a hydroxyphenyl methacrylate.

Claim 14

A radiation-sensitive composition as claimed in claim 11, wherein said copolymer includes additional units selected from the group consisting of styrene, a styrene derivative, and alkyl acrylate and an alkyl methacrylate.

Claim 15

A radiation-sensitive composition as claimed in claim 13, wherein said additional units are derived from an alkyl methacrylate having from 4 to 12 carbon atoms.

Claim 16

A radiation-sensitive composition as claimed in claim 1, wherein said composition contains a 1,2-quinonediazide in an amount of from about 3% to about 50% by weight.

Claim 17

A radiation-sensitive composition as claimed in claim 1, wherein said binder is present in an amount of from about 30% to about 90% by weight, said cleavable compound is present in an amount of from about 5% to about 70% by weight, and said acid-forming compound is present in an amount of from about 0.1% to about 10% by weight.

Claim 18

A radiation-sensitive recording material, comprising a radiation-sensitive layer, and a layer support; said radiation-sensitive layer comprising in admixture: (A) a polymeric binder which is insoluble in water and soluble in aqueous-alkaline solutions, said binder being present in an amount sufficient to form a homogenous layer which is resistant to etching solutions and mechanical abrasion; and (B) one of a 1,2-quinonediazide and a mixture of (1) an amount of a compound forming a strong acid under the action of actinic radiation, said amount being sufficient to form enough of said acid upon exposure of said layer to cleave a cleavable compound therein that has at least one acid-cleavable C--O--C bond, and (2) an amount of a cleavable compound having at least one acid-cleavable C--O--C bond, the solubility of which in a liquid developer is increased by the action of acid, said amount being sufficient to render said layer soluble in an aqueous-alkaline solution; wherein component (B) is radiation-sensitive and is present in an amount sufficient to alter the solubility of said layer in an aqueous-alkaline solution after imagewise irradiation, and wherein said binder (A) is a copolymer comprising units represented by the formula: ##STR5## in which R' denotes a hydrogen atom or an alkyl group, and R" denotes a hydrogen atom or a methyl group and wherein said copolymer includes units formed from monomers wherein the units are selected from the group consisting of hydroxyl group-containing units, and carboxyl group-containing units and combinations of the above.

Claim 19

A radiation-sensitive recording material, comprising a radiation-sensitive layer, and a layer support; said radiation-sensitive layer comprising in admixture: (A) a polymeric binder which is insoluble in water and soluble in aqueous-alkaline solutions, said binder being present in an amount sufficient to form a homogenous layer which is resistant to etching solutions and mechanical abrasion; and (B) one of a 1,2-quinonediazide and a mixture of (1) an amount of a compound forming a strong acid under the action of actinic radiation, said amount being sufficient to form enough of said acid upon exposure of said layer to cleave a cleavable compound therein that has at least one acid-cleavable C--O--C bond, and (2) an amount of a cleavable compound having at least one acid-cleavable C--O--C bond, the solubility of which in a liquid developer is increased by the action of acid, said amount being sufficient to render said layer soluble in an aqueous-alkaline solution; wherein component (B) is radiation-sensitive and is present in an amount sufficient to alter the solubility of said layer in an aqueous-alkaline solution after imagewise irradiation, and wherein said binder (A) is a copolymer comprising units represented by the formula: ##STR5## in which R' denotes a hydrogen atom or an alkyl group, and R" denotes a hydrogen atom or a methyl group and wherein said copolymer includes units formed from monomers wherein the units are selected from the group consisting of hydroxyl group-containing units, and carboxyl group-containing units and combinations of the above.