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US4642282A Expired / Lapsed US ⏱️ 0.0 years remaining

Light-sensitive positive copying material with alkali soluble polycondensation binder

Assignee: Hoechst AG
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Filing: 1984-06-20
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Granted: 1987-02-10
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Expires: 2004-06-20
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Abstract

Abstract A light-sensitive mixture is disclosed which contains a binder comprising a polycondensation product of a phenol corresponding to the formula ##STR1## wherein R 1 is a hydrogen atom, an alkyl group or a hydroxy group, R 2 is a hydrogen atom, an alkyl group, a hydroxy group or an acetyl group, and R 3 is a hydrogen atom or a halogen atom, an alkyl group, an alkoxy group, a carboxyl group or a carboxylic acid ester group, and a compound corresponding to the formula ROCH.sub.2 --X--CH.sub.2 OR, wherein R is a hydrogen atom, a methyl group, an ethyl group or an acetyl group and X is a phenylene group or a binuclear aromatic group. The mixture yields printing plates which have a high resistance to developing solutions and which show a low degree of soiling upon baking.

Inventors

  • 👤 Paul Stahlhofen

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-31 07:15
CPC Classifications
C; C08; C08L; C08L65/00; C08G; C08G61/00; G; G03; G03F; G03F7/00; G03F7/004; G03F7/022; G03F7/023; G03F7/0233; G03F7/0236

Claims Analysis

Total Claims: 20
Claim 1
Independent Claim 209 words
Light-sensitive copying material comprising an aluminum support having a surface that is pretreated by being electrochemically roughened and anodically oxidized and a positive-acting, light-sensitive layer provided on said surface, which light-sensitive layer is comprised of (A) an amount of a positive-acting light-sensitive compound sufficient to impart light-sensitivity to said mixture and (B) a binder which is insoluble in water and soluble in aqueous-alkaline solutions, wherein said binder comprises a polycondensation product of (i) a phenol corresponding to the formula ##STR3## wherein R 1 is a hydrogen atom, an alkyl group or a hydroxy group, R 2 is a hydrogen atom, an alkyl group, a hydroxy group or an acetyl group, and R 3 is a hydrogen atom or a halogen atom, an alkyl group, an alkoxy group, a carboxyl group or a carboxylic acid ester group, and (ii) a compound corresponding to the formula ROCH.sub.2 --X--CH.sub.2 OR, wherein R is a hydrogen atom, a methyl group, an ethyl group or an acetyl group and X is a phenylene group or a divalent aromatic group which comprises two phenylene groups linked by (a) a single bond, (b) an ether group, (c) a sulfide group, (d) a sulfone group, or (e) an alkylene group, and which may be unsubstituted or substituted.
Claim 2
Dependent Claim 209 words
Light-sensitive copying material comprising an aluminum support having a surface that is pretreated by being electrochemically roughened and anodically oxidized and a positive-acting, light-sensitive layer provided on said surface, which light-sensitive layer is comprised of (A) an amount of a positive-acting light-sensitive compound sufficient to impart light-sensitivity to said mixture and (B) a binder which is insoluble in water and soluble in aqueous-alkaline solutions, wherein said binder comprises a polycondensation product of (i) a phenol corresponding to the formula ##STR3## wherein R 1 is a hydrogen atom, an alkyl group or a hydroxy group, R 2 is a hydrogen atom, an alkyl group, a hydroxy group or an acetyl group, and R 3 is a hydrogen atom or a halogen atom, an alkyl group, an alkoxy group, a carboxyl group or a carboxylic acid ester group, and (ii) a compound corresponding to the formula ROCH.sub.2 --X--CH.sub.2 OR, wherein R is a hydrogen atom, a methyl group, an ethyl group or an acetyl group and X is a phenylene group or a divalent aromatic group which comprises two phenylene groups linked by (a) a single bond, (b) an ether group, (c) a sulfide group, (d) a sulfone group, or (e) an alkylene group, and which may be unsubstituted or substituted.
Claim 3
Dependent Claim 35 words
A light-sensitive copy material as claimed in claim 1, wherein said phenol is a monohydric phenol wherein at least one from the group consisting of an o-position and the p-position of said phenol is occupied.
Claim 4
Dependent Claim 21 words
A light-sensitive copy material as claimed in claim 1, wherein said polycondensation product comprises at least three units of said phenol.
Claim 5
Dependent Claim 19 words
A light-sensitive copy material as claimed in claim 1, wherein X is a group corresponding to the formula ##STR4##
Claim 6
Dependent Claim 18 words
A light-sensitive copy material as claimed in claim 1, or claim 3, wherein R is a methyl group.
Claim 7
Dependent Claim 39 words
A light-sensitive copy material as claimed in claim 5, wherein X is a radical of one selected from the group consisting of a diphenylether, a diphenylsulfide, a diphenyl, a diphenylmethane, and a diphenylsulfone, said radical being substituted or unsubstituted.
Claim 8
Dependent Claim 27 words
A light-sensitive copy material as claimed in claim 1, wherein X is a radical of a diphenylalkane which comprises an alkane group having 1 to 6 carbons.
Claim 9
Dependent Claim 18 words
A light-sensitive copy material as claimed in claim 1, which contains a 1,2-quinone diazide as a light-sensitive compound.
Claim 10
Dependent Claim 42 words
A light-sensitive copy material as claimed in claim 1, comprising as said light-sensitive combination of compounds (A) a compound having at least one C--O--C bond which can be split by acid and (B) a compound which eliminates a strong acid upon exposure.
Claim 11
Dependent Claim 36 words
A light-sensitive copy material as claimed in claim 1, wherein said polycondensation product is present in a quantity ranging between about 10 and 95% by weight, relative to the mixture of non-volatile constituents in said mixture.
Claim 12
Dependent Claim 20 words
A light-sensitive copy material as claimed in claim 10, wherein said quantity ranges between about 40 and 80% by weight.
Claim 13
Dependent Claim 61 words
Copying material as claimed in claim 1, wherein said polycondensation product is produced by a process comprising the steps of (a) dissolving 2-methyl-resorcinol in 4,4'-bis-(methoxymethyl)-diphenylether to form a solution, (b) adding to said solution a condensing agent such that condensation occurs with increasing temperature in said solution, and thereafter (c) obtaining said polycondensation product as a precipitate from said reaction solution.
Claim 14
Dependent Claim 25 words
Copying material as claimed in claim 12, wherein said condensing agent is selected from the group consisting of diethylsulfate, methane sulfonic acid and phosphorous oxychloride.
Claim 15
Dependent Claim 15 words
Copying material as claimed in claim 13, wherein the condensing agent is methane sulfonic acid.
Claim 16
Dependent Claim 13 words
Copying material as claimed in claim 13, wherein the condensing agent is diethylsulfate.
Claim 17
Dependent Claim 17 words
Copying material as claimed in claim 12, wherein said solution comprises a solvent in addition to 4,4'-bis-(methoxymethyl)-diphenylether.
Claim 18
Dependent Claim 21 words
Copying material as claimed in claim 16, wherein said solvent is selected from the group consisting of 1,2-dimethoxyethane, dioxane and xylene.
Claim 19
Dependent Claim 12 words
Copying material as claimed in claim 17, wherein said solvent is 1,2-dimethoxyethane.
Claim 20
Dependent Claim 17 words
Copying material as claimed in claim 1, wherein said polycondensation product is comprised of 2-methyl-resorcinol and 4,4'-bis-(methoxymethyl)diphenylether.

References Cited (Backward Citations)

US3201239A Cited
GB1150203A Cited
US3849392A Cited
US3890152A Cited
US4288520A Cited
EP0021718A1 Cited
US4510227A Cited
EP0054258A2 Cited
US4477553A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1990-02-09 1990-08-11 1991-02-10 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1994-02-09 1994-08-11 1995-02-10 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1998-02-09 1998-08-11 1999-02-10 $7700.00 Window Closed / Lapsed

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