Color developers for pressure-sensitive or heat-sensitive recording papers

Claim 2

In a color developer composition for coating onto sheet material to make pressure-sensitive or heat-sensitive recording material, containing a color developer compound, a solvent, and other additives to permit coating, the improvement wherein said color developer compound is a compound including a sulfonylamide (--SO 2 NH--) group and also including an electron-withdrawing atom or moiety within five atoms of the nitrogen atom of said sulfonylamide group, said compound being free of any basic group, with any additional NH groups being no more than one carbon atom away from an SO 2 , C═O, C.tbd.N or NO 2 group, with the proviso that the electron withdrawing group is not a carboxyphenyl group connected through the nitrogen atom of the sulfonylamide group, with the further proviso that the sole electron-withdrawing group is not a carboxyphenyl group and with the further proviso that said compound does not include a --CHOH-- group directly connected to a nitrogen atom.

Claim 3

A color developer composition in accordance with claim 1, wherein, subject to the provisos thereof said electron-withdrawing group is selected from the group consisting --NO 2 , --SO 2 R, --CN, --SO 2 Ar, --COOH, --SO 2 NH 2 , --SO 2 NHR, --SO 2 NR 2 , --F, --Cl, --Br, --I, --OAr, --COOR, --COOAr, --OR, --OH, --SR, --SH, --COR, --COAr, --C.tbd.CR, --Ar, --CH═CR 2 , wherein R is an optionally substituted group and Ar is an optionally substituted aryl group.

Claim 4

A color developer composition in accordance with claim 1, wherein said compound has electron-withdrawing groups on both sides of the sulfonylamide grouping.

Claim 5

A color developer composition in accordance with claim 1, wherein, subject to the provisos thereof, said compound is: an N-monosubstituted sulfonamide of the formula ##STR41## in which R 1 and R 2 are alkyl, aryl or a combination of alkyl and aryl, each being substituted or unsubstituted, said substituents, if any, being any group other than a basic group and, if --NH--; no more than one carbon atom away from a SO 2 , C═O, C.tbd.N or NO 2 group, G is an electron-withdrawing group selected from the group consisting of --NO 2 , --SO 2 R, --CN, --SO 2 Ar, --COOH, --SO 2 NH 2 , --SO 2 NHR, --SO 2 NR 2 , --F, --Cl, --Br, --I, --OAr, --COOR, --COOAr, --OR, --OH, --SR, --SH, --COR, --COAr, --C.tbd.CR, --Ar, --CH═CR 2 , wherein R is an optionally substituted alkyl group and Ar is an optionally substituted aryl group, G being not more than five atoms away from the amide group of the sulfonylamide grouping, with the proviso that G is not --OH or --SH when n is 1 and with the further proviso that --(R 2 ) n --G is not ##STR42## and n is 0 or 1; a sulfonamide of the formula ##STR43## in which, R 1 , R 2 and G are as defined above, with the proviso that R 1 is not ##STR44## and with the further proviso that G is not COOH when all of the following three conditions apply; R 2 is aryl; n is 1, and R 1 does not comprehend or include an electron-withdrawing group within five atoms of the amide group of the sulfonylamide grouping; an N-mono-substituted, N'-mono or di-substituted sulfamide of the formula ##STR45## in which R 2 , G and n are as defined above, and R 3 and R 4 are as defined for R 1 and R 2 or one of R 3 and R 4 is H, and further in which, when one of R 3 and R 4 is H, the other may be an electron-withdrawing group as defined above for G; an N-monosubstituted sulfonamide having electron withdrawing groups on both sides of the sulfamoyl group, of the formula ##STR46## in which n, R 2 and G are as defined above and G 1 is an electron-withdrawing group as defined above with respect to G; or a polyfunctional molecule in which each functional group or the repeating unit is an N-monosubstituted sulfonamide or sulfamide depicted in formulas (I) through (IV).

Claim 6

A color developer composition in accordance with claim 1, wherein said compound is selected from the group consisting of: N-(phenylsulfonyl)-p-toluenesulfonamide N-phenyl-benzene sulfonamide C 3-8 alkyl-N-(phenylsulfonyl)-p-aminobenzoate N-α-(p-toluenesulfonyl)-DL-phenylalanine N-(carboxymethyl)-p-toluenesulfonamide N-[o-(p-toluenesulfonamido)phenyl]-p-toluenesulfonamide C 3-8 alkyl-N-(o-carboxyphenylsulfonyl)-p-amino-benzoate N-(o-carboxyphenylsulfonyl)-4-aminobenzophenone N-(o-carboxyphenylsulfonyl)4-aminobenzenesulfonamide N-(4-C 1-18 alkylphenyl)-o-carboxybenzenesulfonamide N-2(2,4-diC 3-8 alkylphenyl)-o-carboxybenzenesulfonamide N-(diC 1-8 alkylsulfamoyl)-p-toluenesulfonamide N-phenyl-N'-C 1-8 alkylsulfamide N-benzoyl-N'-C 1-8 alkylsulfamide N-phenyl-N',N'-diC 1-8 alkylsulfamide N-diC 1-8 alkylsulfamoyl)-α-aminophenylacetic acid N-o-(N',N'-diC 1-3 alkylsulfamoylamido)-phenyl-diC 1-8 alkylsulfamide trimethylene bis(N-o-carboxylphenylsulfonyl)-p-aminobenzoate N-toluenesulfonyl-α-aminophenylacetic acid N-phenylsulfonyl-α-aminophenylacetic acid N-(m-carboxybenzoyl)-p-toluenesulfonamide N-(m-carboxybenzoyl)-benzenesulfonamide N-(m-carboxybenzoyl)-N',N'-dimethylsulfamide N-(o-carboxybenzoyl)-p-toluenesulfonamide N-(o-carboxybenzoyl)-benzenesulfonamide N-(o-carboxybenzoyl)-N',N'-dimethylsulfamide N-(m-nitrobenzoyl)-p-toluene sulfonamide.