Heat sensitive record material

Claim 2

A heat sensitive record material comprising a support sheet and a record layer formed on the support sheet, the record layer being composed essentially of a colorless or light-colored fluoran compound, an acidic substance which is thermally reactive with the fluoran compound to develop a color and a binder, characterized in that said record layer contains an effective amount of at least one benzenesulfonamide compound represented by the general formula: ##STR39## where R 1 is a hydrogen atom, a C 1 -C 5 alkyl group, an acetylamino group or a halogen atom, R 2 is a hydrogen atom, a C 1 -C 5 alkyl group, a cyclohexyl group or a phenyl group which may be substituted and R 3 is a C 1 -C 5 alkyl group, a cyclohexyl group or a phenyl group which may be substituted, provided R 2 and R 3 may form together with N a saturated ring.

Claim 3

The heat sensitive record material according to claim 1, wherein the record layer contains at least one benzenesulfonamide compound of the general formula I in an amount of from 0.1 to 10 parts by weight relative to 1 part by weight of the chromogenic material.

Claim 4

The heat sensitive record material according to claim 1, wherein the record layer comprises 1 part by weight of the chromogenic material, from 0.1 to 10 parts by weight of at least one benzenesulfonamide compound of the general formula I, from 2 to 10 parts by weight of the acidic substance and from 2 to 10 parts by weight of the binder.

Claim 5

The heat sensitive record material according to claim 1, wherein the fluoran compound is selected from the group consisting of compounds represented by the general formula: ##STR40## where R 4 is a C 1 -C 5 alkyl group, R 5 is a C 1 -C 5 alkyl group, a cyclohexyl group or a phenyl group which may be substituted, provided R 4 and R 5 may form together with the nitrogen atom a heterocyclic ring, R 6 is a hydrogen atom, a halogen atom, a C 1 -C 3 alkoxy group or a C 1 -C 3 alkyl group, R 7 is a hydrogen atom, a C 1 -C 3 alkyl group, a halogen atom or a trifluoromethyl group, and R 8 is a hydrogen atom or a C 1 -C 3 alkyl group.

Claim 6

The heat sensitive record material according to claim 1, wherein the fluoran compound is selected from the group consisting of 2-(2-chlorophenylamino)-6-diethylaminofluoran, 2-(2-chlorophenylamino)-6-di-n-butylaminofluoran, 2-anilino-3-methyl-6-diethylaminofluoran, 2-anilino-3-methyl-6-pyrrolidinylfluoran, 2-anilino-3-methyl-6-piperidinofluoran, 2-(3-trifluoromethylanilino)-6-diethylaminofluoran, 2-anilino-6-diethylaminofluoran, 2-anilino-3-methyl-6-(N-ethyl-N-p-tolyl)aminofluoran, 2-(p-ethoxyanilino)-3-methyl-6-diethylaminofluoran, 2-xylidino-3-methyl-6-diethylaminofluoran, 2-anilino-3-methyl-6-(N-methyl-N-cyclohexylamino)fluoran, 2-anilino-3-chloro-6-diethylaminofluoran, 2-anilino-3,4-dimethyl-6-diethylaminofluoran and 2-anilino-3-methoxy-6-dibutylaminofluoran.

Claim 7

The heat sensitive record material according to claim 1, wherein the acidic substance is a colorless solid phenolic compound or a colorless solid organic acid or its metal salt which is liquefied or vaporized at a temperature of 50° C. or higher.

Claim 8

The heat sensitive record material according to claim 1, wherein the acidic substance is 4,4'-isopropylidene-diphenol.

Claim 9

The heat sensitive record material according to claim 1, wherein the benzenesulfonamide compound of the general formula I is selected from the group consisting of N-(2-chlorophenyl)-4-methylbenzenesulfonamide, N-(4-chlorophenyl)-4-methylbenzenesulfonamide, N-(4-methylphenyl)-4-methylbenzenesulfonamide, N-(3-hydroxyphenyl)-4-methylbenzenesulfonamide, N-(4-hydroxyphenyl)-4-methylbenzenesulfonamide, N-(4-sulfamoylphenyl)-4-methylbenzenesulfonamide, N-(4-methoxyphenyl)-4-methylbenzenesulfonamide, 4-(piperidinosulfonyl)-acetanilide, N,N-dimethyl-4-(acethylamino)-benzenesulfonamide, 4-(morpholinosulfonyl)-acetanilide, N,N-dimethyl-4-methylbenzenesulfonamide, 4-(morpholinosulfonyl)-toluene, N-methyl-4-methylbenzenesulfonamide, 4-(4-N-methylpiperazinosulfonyl)-toluene, 4-(4-N-methylpiperazinosulfonyl)-acetanilide, N-(2-chlorophenyl)-benzenesulfonamide, N-(4-chlorophenyl)-benzenesulfonamide, N-(3-chlorophenyl)-benzenesulfonamide, N-(2-methylphenyl)-benzenesulfonamide, N-(2-methoxyphenyl)-benzenesulfonamide, N-(2,3-dichlorophenyl)-benzenesulfonamide, N-(3,4-dichlorophenyl)-benzenesulfonamide, N-(2-nitrophenyl)-benzenesulfonamide, morpholinosulfonylbenzene, N-phenylbenzenesulfonamide, N-cyclohexyl-benzenesulfonamide, N-(2-chlorophenyl)-4-chlorobenzenesulfonamide, N-(4-chlorophenyl)-4-chlorobenzenesulfonamide, N-(2-methylphenyl)-4-chlorobenzenesulfonamide, N-(4-methylphenyl)-4-chlorobenzenesulfonamide, N-(2-methoxyphenyl)-4-chlorobenzenesulfonamide, N-(2,3-dichlorophenyl)-4-chlorobenzenesulfonamide, N-(3,4-dichlorophenyl)-4-chlorobenzenesulfonamide, 4-(morphoninosulfonyl)-chlorobenzene, N-phenyl-4-chlorobenzenesulfonamide, N-cyclohexyl-4-chlorobenzenesulfonamide, N,N-dimethyl-4-chlorobenzenesulfonamide and N-(4-hydroxyphenyl)-2-methylbenzenesulfonamide.

Claim 10

The heat sensitive record material according to claim 1, wherein the binder is selected from polyvinyl alcohol, methyl cellulose, hydroxyethyl cellulose, carboxymethyl cellulose, gum arabic, starch, gelatin, casein, polyvinyl pyrrolidone, a styrene-maleic acid anhydride copolymer, a polyacrylic acid amide, a polyacrylic acid salt, a terpene resin and a petroleum resin.

Claim 11

The heat sensitive record material according to claim 1, wherein the chromogenic material, the acidic substance and the benzenesulfonamide compound of the general formula I are uniformly distributed in the record layer in particle form having a particle size of from 1 to 6 μm.