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US4588447A Expired / Lapsed US ⏱️ 0.0 years remaining

Method of eliminating p-type electrical activity and increasing channel mobility of Si-implanted and recrystallized SOS films

Assignee: Conexant Systems LLC
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Filing: 1984-06-25
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Granted: 1986-05-13
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Expires: 2004-06-25
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Abstract

Abstract A silicon on sapphire (SOS) semiconductor structure may be processed to improve the electrical characteristics of a silicon film on a sapphire substrate by silicon-regrowth (SRG) techniques using oxidation to remove silicon from the outward surface of the silicon film. An epitaxial film on a sapphire substrate is implanted with silicon to amorphize the silicon film except for a thin seed layer on the outward surface of the silicon film. The silicon is recrystallized inwards using the seed layer as a seed for crystallization. The silicon film is oxidized to produce an oxide layer on the outward surface of the silicon film, the SOS structure may be heated to densify the oxide layer, and the oxide layer is etched away. This produces a silicon film with a reduced p-type electrical activity and improved crystalline quality surface so that the channel mobility is improved for semiconductor devices fabricated in the silicon film.

Inventors

  • 👤 Ilan Golecki

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-25 18:22
CPC Classifications
H; H10; H10P; H10P30/00; H10P30/20; H10P30/202; H10P30/204; H10P14/00; H10P14/20; H10P14/29; H10P14/2901; H10P14/2921; H10P14/2926; H10P14/34; H10P14/3402; H10P14/3404; H10P14/3411; H10P14/38; H10P14/3802; H10P14/3822; H10P30/208; H10P36/00; H10P36/03; H10P95/00; H10P95/40; H10P95/402; Y; Y10; Y10S; Y10S148/00; Y10S148/061; Y10S148/077

Claims Analysis

Total Claims: 14
Claim 1
Independent Claim 98 words
A method for producing a silicon film on a sapphire substrate comprising: depositing a thin film of silicon on said sapphire substrate, said silicon film having an outward surface; implanting ions into said silicon film to substantially amorphize said silicon film, excepting for a thin seed layer adjacent said outward surface of said silicon film; recrystallizing the amorphous portion of said silicon film; oxidizing said seed layer for a time sufficient to permit a component of the oxidizing agent to diffuse through said silicon film and react with aluminum in said film to render said aluminum electrically inactive.
Claim 2
Independent Claim 98 words
A method for producing a silicon film on a sapphire substrate comprising: depositing a thin film of silicon on said sapphire substrate, said silicon film having an outward surface; implanting ions into said silicon film to substantially amorphize said silicon film, excepting for a thin seed layer adjacent said outward surface of said silicon film; recrystallizing the amorphous portion of said silicon film; oxidizing said seed layer for a time sufficient to permit a component of the oxidizing agent to diffuse through said silicon film and react with aluminum in said film to render said aluminum electrically inactive.
Claim 3
Dependent Claim 31 words
Tbe method of claim 1 wberein said oxidizing step comprises heating said sapphire substrate and said silicon film to a temperature of approximately 875 degrees Celsius in an atmosphere of steam.
Claim 4
Dependent Claim 23 words
The method of claim 1 wherein said thin film of silicon deposited in said depositing step has a thickness of approximately 0.2 micrometers.
Claim 5
Dependent Claim 17 words
The method of claim 2 additionally comprising etching away the oxide layer formed in said oxidizing step.
Claim 6
Dependent Claim 34 words
The method of claim 3 wherein said oxidizing step is conducted for a length of time substantially equal to the time necessary to form an oxide layer having a thickness of approximately 0.13 micrometers.
Claim 7
Dependent Claim 40 words
The method of claim 4, further comprising, prior to said etching step, the step of heating said substrate to a temperature of approximately 875 degrees Celsius in an atmosphere of flowing nitrogen to increase the density of said oxide layer.
Claim 8
Independent Claim 108 words
A method of producing on a sapphire substrate a silicon film of high crystalline quality and increased resistivity comprising: depositing a thin film of silicon on said sapphire substrate; transforming a portion of said silicon film adjacent said sapphire substrate into an amorphous silicon layer, leaving a seed layer of deposited crystalline silicon adjacent the outer surface of said silicon layer; epitaxially recrystallizing said amorphous silicon layer to produce a recrystallized silicon layer; and oxidizing said seed layer using an oxidizing agent for a time sufficient for a component of said oxidizing agent to react with aluminum distributed through said recrystallized silicon layer to electrically neutralize said aluminum.
Claim 9
Independent Claim 108 words
A method of producing on a sapphire substrate a silicon film of high crystalline quality and increased resistivity comprising: depositing a thin film of silicon on said sapphire substrate; transforming a portion of said silicon film adjacent said sapphire substrate into an amorphous silicon layer, leaving a seed layer of deposited crystalline silicon adjacent the outer surface of said silicon layer; epitaxially recrystallizing said amorphous silicon layer to produce a recrystallized silicon layer; and oxidizing said seed layer using an oxidizing agent for a time sufficient for a component of said oxidizing agent to react with aluminum distributed through said recrystallized silicon layer to electrically neutralize said aluminum.
Claim 10
Dependent Claim 49 words
The method of claim 7 wherein: said depositing step deposits a silicon film having a thickness of approximately 0.2 microns; and said oxidizing step is conducted for a length of time substantially equal to the time necessary to oxidize a silicon layer having a thickness of approximately 300 angstroms.
Claim 11
Dependent Claim 49 words
The method of claim 7, wherein: said depositing step deposits a silicon film having a thickness of approximately 0.2 microns; and said oxidizing step is conducted for a length of time substantially equal to the time necessary to form an oxide layer having a thickness of approximately 0.13 micrometers.
Claim 12
Dependent Claim 25 words
The method of claim 7, wherein said oxidizing agent comprises steam, and said oxidizing step is conducted at a temperature of approximately 875 degrees Celsius.
Claim 13
Dependent Claim 31 words
The method of claim 7 wherein said recrystallization step comprises heating the sapphire substrate and silicon layer to a temperature of approximately 550 degrees C. in an atmosphere of flowing nitrogen.
Claim 14
Dependent Claim 45 words
The method of claim 10 additionally comprising, following said oxdizing step: heating said sapphire substrate and silicon layer to a temperature of approximately 875 degrees Celsius to increase the density of the oxide layer formed during said oxidizing step; and etching away said oxide layer.

References Cited (Backward Citations)

US4177084A Cited
US4178191A Cited
US4385937A Cited
US4358326A Cited
US4463492A Cited
US4460417A Cited
US4509990A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1989-05-12 1989-11-11 1990-05-13 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1993-05-12 1993-11-11 1994-05-13 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1997-05-12 1997-11-11 1998-05-13 $7700.00 Window Closed / Lapsed

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