US4585493A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Grain-driven zone-melting of silicon films on insulating substrates
Assignee: Intersil Corp
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Filing: 1984-06-26
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Granted: 1986-04-29
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Expires: 2004-06-26
Abstract
Abstract A method of growing single crystal layers from polycrystal layers is taught. The method involves forming a eutectic of the polycrystal material and an alloying metal and forming a eutectic bridge between a seed single crystal and the polycrystalline material with the eutectic alloy. The alloy is kept molten and both the single crystal and polycrystal are kept solid at a temperature to induce the eutectic alloy to eat into the polycrystal and to extend the single crystal to form a single crystal layer.
Inventors
- 👤 Thomas R. Anthony
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-31 20:54
CPC Classifications
H; H10; H10P; H10P95/00; H10P95/50; H10P14/00; H10P14/20; H10P14/29; H10P14/2901; H10P14/2902; H10P14/2905; H10P14/32; H10P14/3202; H10P14/3238; H10P14/34; H10P14/3402; H10P14/3404; H10P14/3411; H10P14/38; H10P14/3802; H10P14/3806; Y; Y10; Y10S; Y10S438/00; Y10S438/929
Claims Analysis
Total Claims: 26
Claim 1
Independent Claim
208 words
The method of forming a single crystal silicon layer on a silicon oxide insulator layer which comprises; forming a silicon oxide insulator layer on a single crystal silicon wafer disc base and forming a slit window in the silicon oxide insulator layer to expose the upper surface of the single crystal silicon wafer disc; forming a polycrystalline silicon layer on the silicon oxide insulator layer; seeding the polycrystalline silicon layer from the single crystal silicon wafer disc base by forming a melt zone with a eutectic alloying agent aligned with said slit window; heating the single crystal silicon wafer disc and the silicon oxide insulator layer and the polycrystalline silicon layer to an isothermal temperature substantially below the melting point of the silicon but above the melting point of the eutectic; maintaining the isothermal temperature at a level to cause the melt zone to advance into the polycrystalline silicon layer, and to cause a single crystal silicon layer to form from the polycrystalline silicon layer at the trailing edge of the melt zone; and cooling the single crystal silicon wafer disc base and the silicon oxide insulator layer and the single crystal silicon layer after the polycrystalline silicon layer has been converted to a single crystal silicon layer.
Claim 2
Independent Claim
208 words
The method of forming a single crystal silicon layer on a silicon oxide insulator layer which comprises; forming a silicon oxide insulator layer on a single crystal silicon wafer disc base and forming a slit window in the silicon oxide insulator layer to expose the upper surface of the single crystal silicon wafer disc; forming a polycrystalline silicon layer on the silicon oxide insulator layer; seeding the polycrystalline silicon layer from the single crystal silicon wafer disc base by forming a melt zone with a eutectic alloying agent aligned with said slit window; heating the single crystal silicon wafer disc and the silicon oxide insulator layer and the polycrystalline silicon layer to an isothermal temperature substantially below the melting point of the silicon but above the melting point of the eutectic; maintaining the isothermal temperature at a level to cause the melt zone to advance into the polycrystalline silicon layer, and to cause a single crystal silicon layer to form from the polycrystalline silicon layer at the trailing edge of the melt zone; and cooling the single crystal silicon wafer disc base and the silicon oxide insulator layer and the single crystal silicon layer after the polycrystalline silicon layer has been converted to a single crystal silicon layer.
Claim 3
Dependent Claim
12 words
The method of claim 1 in which the eutectic agent is gold.
Claim 4
Dependent Claim
16 words
The method of claim 2 in which the processing temperature is less than about 800° C.
Claim 5
Dependent Claim
12 words
The method of claim 1 in which the eutectic agent is silver.
Claim 6
Dependent Claim
14 words
The method of claim 4 in which the processing temperature is below 1150° C.
Claim 7
Dependent Claim
21 words
The method of claim 1 wherein the zone width is at least three times the grain size of the polycrystalline layer.
Claim 8
Dependent Claim
20 words
The method of claim 1 in which the zone orientation for a <100> single crystal substrate is <011> or <011>.
Claim 9
Dependent Claim
17 words
The method of claim 1 wherein the zone orientation for a <111> substrate is <110> or <01/1>.
Claim 10
Dependent Claim
19 words
The method of claim 1 in which the eutectic metal is antimony and the single crystal formed is N-type.
Claim 11
Dependent Claim
31 words
The method of claim 1 in which the eutectic metal is selected from the group consisting of aluminum, indium and gallium and the single crystal layer formed is of the P-type.
Claim 12
Dependent Claim
12 words
The method of claim 1 in which the eutectic metal is tin.
Claim 13
Independent Claim
104 words
The method of forming a single crystal layer on an insulating substrate which comprises disposing a polycrystalline silicon layer on said insulating substrate, disposing an alloying metal on a portion of said polycrystalline layer and heating said polycrystalline layer and alloying metal to form a eutectic metal zone in contact with said polycrystalline layer, disposing a single crystal silicon seed at one surface of said melt to permit growth of said single crystal from material of said melt, and maintaining the wafer heated to cause the melt to advance into the polycrystalline layer and the deposit of single crystal to follow the melt advance.
Claim 14
Independent Claim
104 words
The method of forming a single crystal layer on an insulating substrate which comprises disposing a polycrystalline silicon layer on said insulating substrate, disposing an alloying metal on a portion of said polycrystalline layer and heating said polycrystalline layer and alloying metal to form a eutectic metal zone in contact with said polycrystalline layer, disposing a single crystal silicon seed at one surface of said melt to permit growth of said single crystal from material of said melt, and maintaining the wafer heated to cause the melt to advance into the polycrystalline layer and the deposit of single crystal to follow the melt advance.
Claim 15
Dependent Claim
12 words
The method of claim 12 in which the eutectic agent is gold.
Claim 16
Dependent Claim
16 words
The method of claim 13 in which the processing temperature is less than about 800° C.
Claim 17
Dependent Claim
12 words
The method of claim 12 in which the eutectic agent is silver.
Claim 18
Dependent Claim
14 words
The method of claim 15 in which the processing temperature is below 1150° C.
Claim 19
Dependent Claim
21 words
The method of claim 12 wherein the zone width is at least three times the grain size of the polycrystalline layer.
Claim 20
Dependent Claim
19 words
The method of claim 12 wherein the zone orientation for a <100> single crystal substrate is <011> or <011>.
Claim 21
Dependent Claim
17 words
The method of claim 12 wherein the zone orientation for a <111> substrate is <110> or <011>.
Claim 22
Dependent Claim
19 words
The method of claim 12 in which the eutectic metal is antimony and the single crystal formed is N-type.
Claim 23
Dependent Claim
31 words
The method of claim 12 in which the eutectic metal is selected from the group consisting of aluminum, indium and gallium and the single crystal layer formed is of the P-type.
Claim 24
Dependent Claim
12 words
The method of claim 12 in which the eutectic metal is tin.
Claim 25
Independent Claim
103 words
The method of forming single crystal layers on insulating substrates at high production rates which comprises forming an insulating layer on a single crystal silicon wafer, forming a number of slit windows through said insulating layer to expose said single crystal silicon wafer, depositing a polycrystalline silicon layer on said insulating layer and through the windows thereof, disposing a eutectic forming metal on said polycrystalline layer over said window, heating the resulting structure to melt the polycrystalline silicon occupying said windows into a eutectic composition, and continuing to heat said structure to convert the polycrystalline silicon layer to a single crystal silicon layer.
Claim 26
Independent Claim
103 words
The method of forming single crystal layers on insulating substrates at high production rates which comprises forming an insulating layer on a single crystal silicon wafer, forming a number of slit windows through said insulating layer to expose said single crystal silicon wafer, depositing a polycrystalline silicon layer on said insulating layer and through the windows thereof, disposing a eutectic forming metal on said polycrystalline layer over said window, heating the resulting structure to melt the polycrystalline silicon occupying said windows into a eutectic composition, and continuing to heat said structure to convert the polycrystalline silicon layer to a single crystal silicon layer.
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| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
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| 3.5 Years (Year 4) | 1989-04-28 | 1989-10-28 | 1990-04-29 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1993-04-28 | 1993-10-28 | 1994-04-29 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1997-04-28 | 1997-10-28 | 1998-04-29 | $7700.00 | Window Closed / Lapsed |