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Mixed squaraine photoconductive compositions

Assignee: Xerox Corp
•
Filing: 1984-09-13
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Granted: 1985-12-17
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Expires: 2004-09-13
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Abstract

Abstract An improved process for the preparation of mixed squaraine compositions which comprises reacting squaric acid, an aromatic amine, and a fluoroaniline, in the presence of an aliphatic alcohol, and an optional azeotropic substance. Also disclosed are mixed squaraine composition products of the following formulas: <IMAGE> I <IMAGE> II <IMAGE> III

Inventors

  • 👤 Peter M. Kazmaier
  • 👤 Giuseppa Baranyi
  • 👤 Cheng-Kuo Hsiao
  • 👤 Richard A. Burt

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-07 05:21
CPC Classifications
G; G03; G03G; G03G5/00; G03G5/02; G03G5/04; G03G5/06; G03G5/0698; C; C09; C09B; C09B67/00; C09B67/0033; C09B67/0034; G03G5/0601; G03G5/0609; G03G5/0611

Claims Analysis

Total Claims: 13
Claim 1
Independent Claim 50 words
An imaging member comprised of a supporting substrate; the mixed squaraine composition comprised of components I, II, and III ##STR7## as a photogenerating pigment wherein fluorine is present in an amount of from about 0.050 to about 5 percent by weight; and in contact therewith an arylamine hole transport layer.
Claim 2
Dependent Claim 50 words
An imaging member comprised of a supporting substrate; the mixed squaraine composition comprised of components I, II, and III ##STR7## as a photogenerating pigment wherein fluorine is present in an amount of from about 0.050 to about 5 percent by weight; and in contact therewith an arylamine hole transport layer.
Claim 3
Dependent Claim 35 words
An imaging member in accordance with claim 1, wherein the components are present in the proportions I 98.50, to II 1.43, to III 0.07; to about I 41.36, to II 52.20, and III to 6.44.
Claim 4
Dependent Claim 13 words
An imaging member in accordance with claim 1 wherein the arylamine is N,N'-diphenyl-N,N'-bis(3-methylphenyl)1,1'-biphenyl-4,4'-diamine.
Claim 5
Dependent Claim 23 words
An imaging member in accordance with claim 1 wherein the hole transport layer is situated between the supporting substrate and the photogenerating pigment.
Claim 6
Dependent Claim 20 words
An imaging member in accordance with claim 1 further including therein an adhesive layer and a silane hole blocking layer.
Claim 7
Dependent Claim 43 words
An imaging member in accordance with claim 1 wherein the arylamine hole transport layer comprises molecules of the formula ##STR8## wherein X is selected from the group consisting of alkyl and halogen, and wherein the molecules are dispersed in an inactive resinous binder.
Claim 8
Dependent Claim 50 words
An improved photoresponsive imaging member comprised of a supporting substrate; an inorganic photogenerating layer; a photoconductive layer comprised of the squaraine components I, II and III, ##STR9## wherein fluorine is present in an amount of from about 0.050 to about 6 percent by weight; and an arylamine hole transport layer.
Claim 9
Dependent Claim 50 words
An improved photoresponsive imaging member comprised of a supporting substrate; an inorganic photogenerating layer; a photoconductive layer comprised of the squaraine components I, II and III, ##STR9## wherein fluorine is present in an amount of from about 0.050 to about 6 percent by weight; and an arylamine hole transport layer.
Claim 10
Dependent Claim 20 words
An imaging member in accordance with claim 7 further including a hole blocking layer and an optional adhesive interface layer.
Claim 11
Dependent Claim 30 words
An imaging member in accordance with claim 7 wherein the inorganic photogenerating layer contains therein substances selected from the group consisting of amorphous selenium, amorphous selenium alloys, and trigonal selenium.
Claim 12
Dependent Claim 16 words
An imaging member in accordance with claim 7 wherein the photogenerating layer contains therein vanadyl phthalocyanine.
Claim 13
Dependent Claim 16 words
An imaging member in accordance with claim 7 wherein the arylamine hole transport molecule is N,N'-diphenyl-N,N'-bis(3-methylphenyl)1,1'-biphenyl-4,4'-diamine.

References Cited (Backward Citations)

US3121006A Cited
BE763540A Cited
US3838059A Cited
US3824099A Cited
US4123270A Cited
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US4251612A Cited
US4353971A Cited
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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1988-12-16 1989-06-17 1989-12-17 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1992-12-16 1993-06-17 1993-12-17 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1996-12-16 1997-06-17 1997-12-17 $7700.00 Window Closed / Lapsed

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