Photoreceptor containing squaric acid methine dyes

Claim 2

A photoreceptor for use in an electrophotographic imaging process having a double charging sequence, comprising: (a) a substrate; (b) a photosensitive layer consisting essentially of a noncharge-transporting binder material and a charge-generating, charge-transporting squaric acid methine dye selected from the group consisting of compounds of formula I: ##STR8## wherein A and B are independently, ##STR9## wherein R 1 , R 2 , and R 3 are independently H, OH, alkyl of 1 to 6 carbon atoms, or NR 4 R 5 , wherein R 4 and R 5 are independently alkyl of 1 to 6 carbon atoms; ##STR10## wherein R 6 and R 7 are independently alkyl of 1 to 6 carbon atoms, and R 8 is independently H, OR 9 or halogen, wherein R 9 is alkyl of 1 to 6 carbon atoms; ##STR11## wherein R 10 , R 11 , R 12 and R 13 are independently H, OH or alkyl of 1 to 6 carbon atoms; ##STR12## wherein R 14 , R 15 , and R 16 are independently alkyl of 1 to 6 carbon atoms, and R 17 is independently H, OR 18 , or halogen, wherein R 18 is alkyl of 1 to 6 carbon atoms; or ##STR13## wherein said binder material is capable of supporting and storing charge throughout said photosensitive layer and wherein the ratio of said dye to said binder material is in the range from about 1:1 to about 1:40; and (c) an insulating layer.

Claim 3

A photoreceptor according to claim 1 wherein A and B are independently ##STR14##

Claim 4

A photoreceptor according to claim 2 wherein R 1 is methyl, R 2 is hydrogen, and R 3 is dimethylamino, and A and B are the same.

Claim 5

A photoreceptor according to claim 1 wherein said insulating layer comprises a material selected from the group consisting of polyester, polycarbonate, polyacetate, polystyrene, polyfluoroethylene, polyethylene, polypropylene, polyvinyl chloride, polyvinylidene chloride, polyurethane, epoxy resin and melamine resin.

Claim 6

A photoreceptor according to claim 1 wherein said insulating layer comprises a polyester.

Claim 7

An electrophotographic imaging process having a double charging sequence, comprising the steps of: (a) subjecting a photoreceptor to first electrostatic charges of one polarity, said photoreceptor comprising: a substrate; a photosensitive layer consisting essentially of a noncharge-transporting binder material and a charge-generating, charge-transporting squaric acid methine dye selected from the group consisting of compounds of formula I: ##STR15## wherein A and B are independently, ##STR16## wherein R 1 , R 2 , and R 3 are independently H, OH, alkyl of 1 to 6 carbon atoms, or NR 4 R 5 , wherein R 4 and R 5 are independently alkyl of 1 to 6 carbon atoms; ##STR17## wherein R 6 and R 7 are independently alkyl of 1 to 6 carbon atoms, and R 8 is independently H, OR 9 or halogen, wherein R 9 is alkyl of 1 to 6 carbon atoms; ##STR18## wherein R 10 , R 11 , R 12 and R 13 are independently H, OH or alkyl of 1 to 6 carbon atoms; ##STR19## wherein R 14 , R 15 , and R 16 are independently alkyl of 1 to 6 carbon atoms, and R 17 is independently H, OR 18 , or halogen, wherein R 18 is alkyl of 1 to 6 carbon atoms; or ##STR20## wherein said binder material is capable of supporting and storing charge throughout said photosensitive layer and wherein the ratio of said dye to said binder material is in the range from about 1:1 to about 1:40; and an insulating layer; (b) subjecting said photoreceptor to second electrostatic charges of polarity opposite the polarity of said first electrostatic charges; (c) simultaneously exposing said photoreceptor to an image-wise pattern of activating electromagnetic radiation; and (d) exposing said photoreceptor to a uniform amount of activating electromagnetic radiation to form an electrostatic latent image on the surface of said insulating layer.

Claim 8

An electrophotographic imaging process having a double charging sequence, comprising the steps of: (a) subjecting a photoreceptor to first electrostatic charges of one polarity, said photoreceptor comprising: a substrate; a photosensitive layer consisting essentially of a noncharge-transporting binder material and a charge-generating, charge-transporting squaric acid methine dye selected from the group consisting of compounds of formula I: ##STR15## wherein A and B are independently, ##STR16## wherein R 1 , R 2 , and R 3 are independently H, OH, alkyl of 1 to 6 carbon atoms, or NR 4 R 5 , wherein R 4 and R 5 are independently alkyl of 1 to 6 carbon atoms; ##STR17## wherein R 6 and R 7 are independently alkyl of 1 to 6 carbon atoms, and R 8 is independently H, OR 9 or halogen, wherein R 9 is alkyl of 1 to 6 carbon atoms; ##STR18## wherein R 10 , R 11 , R 12 and R 13 are independently H, OH or alkyl of 1 to 6 carbon atoms; ##STR19## wherein R 14 , R 15 , and R 16 are independently alkyl of 1 to 6 carbon atoms, and R 17 is independently H, OR 18 , or halogen, wherein R 18 is alkyl of 1 to 6 carbon atoms; or ##STR20## wherein said binder material is capable of supporting and storing charge throughout said photosensitive layer and wherein the ratio of said dye to said binder material is in the range from about 1:1 to about 1:40; and an insulating layer; (b) subjecting said photoreceptor to second electrostatic charges of polarity opposite the polarity of said first electrostatic charges; (c) simultaneously exposing said photoreceptor to an image-wise pattern of activating electromagnetic radiation; and (d) exposing said photoreceptor to a uniform amount of activating electromagnetic radiation to form an electrostatic latent image on the surface of said insulating layer.

Claim 9

An electrophotographic imaging process having a double charging sequence, comprising the steps of: (a) subjecting a photoreceptor to first electrostatic charges of one polarity, said photoreceptor comprising: a substrate; a photosensitive layer consisting essentially of a noncharge-transporting binder material and a charge-generating, charge-transporting squaric acid methine dye selected from the group consisting of compounds of formula I: ##STR21## wherein A and B are independently, ##STR22## wherein R 1 , R 2 , and R 3 , are independently H, OH, alkyl of 1 to 6 carbon atoms, or NR 4 R 5 , wherein R 4 and R 5 are independently alkyl of 1 to 6 carbon atoms; ##STR23## wherein R 6 and R 7 are independently alkyl of 1 to 6 carbon atoms, and R 8 is independently H, OR 9 or halogen, wherein R 9 is alkyl of 1 to 6 carbon atoms; ##STR24## wherein R 10 , R 11 , R 12 and R 13 are independently H, OH or alkyl of 1 to 6 carbon atoms; ##STR25## wherein R 14 , R 15 , and R 16 are independently alkyl of 1 to 6 carbon atoms, and R 17 is independently H, OR 18 , or halogen, wherein R 18 is alkyl of 1 to 6 carbon atoms; or ##STR26## wherein said binder material is capable of supporting and storing charge throughout said photosensitive layer and wherein the ratio of said dye to said binder material is in the range from about 1:1 to about 1:40; and an insulating layer; (b) subjecting said photoreceptor to A.C. electrostatic charges; (c) simultaneously exposing said photoreceptor to an image-wise pattern of activating electromagnetic radiation; and (d) exposing said photoreceptor to a uniform amount of activating electromagnetic radiation to form an electrostatic latent image on the surface of said insulating layer.

Claim 10

An electrophotographic imaging process having a double charging sequence, comprising the steps of: (a) subjecting a photoreceptor to first electrostatic charges of one polarity, said photoreceptor comprising: a substrate; a photosensitive layer consisting essentially of a noncharge-transporting binder material and a charge-generating, charge-transporting squaric acid methine dye selected from the group consisting of compounds of formula I: ##STR21## wherein A and B are independently, ##STR22## wherein R 1 , R 2 , and R 3 , are independently H, OH, alkyl of 1 to 6 carbon atoms, or NR 4 R 5 , wherein R 4 and R 5 are independently alkyl of 1 to 6 carbon atoms; ##STR23## wherein R 6 and R 7 are independently alkyl of 1 to 6 carbon atoms, and R 8 is independently H, OR 9 or halogen, wherein R 9 is alkyl of 1 to 6 carbon atoms; ##STR24## wherein R 10 , R 11 , R 12 and R 13 are independently H, OH or alkyl of 1 to 6 carbon atoms; ##STR25## wherein R 14 , R 15 , and R 16 are independently alkyl of 1 to 6 carbon atoms, and R 17 is independently H, OR 18 , or halogen, wherein R 18 is alkyl of 1 to 6 carbon atoms; or ##STR26## wherein said binder material is capable of supporting and storing charge throughout said photosensitive layer and wherein the ratio of said dye to said binder material is in the range from about 1:1 to about 1:40; and an insulating layer; (b) subjecting said photoreceptor to A.C. electrostatic charges; (c) simultaneously exposing said photoreceptor to an image-wise pattern of activating electromagnetic radiation; and (d) exposing said photoreceptor to a uniform amount of activating electromagnetic radiation to form an electrostatic latent image on the surface of said insulating layer.

Claim 11

An electrophotographic imaging process according to claim 6 or 7 wherein A and B are independently ##STR27##

Claim 12

An electrophotographic imaging process according to claim 8 wherein R 1 is methyl, R 2 is hydrogen and R 3 dimethylamino, and A and B are the same.

Claim 13

An electrophotographic imaging process according to claim 6 or 7 wherein said insulating layer comprises a material selected from the group consisting of polyester, polycarbonate, polyacetate, polystyrene, polyfluoroethylene, polyethylene, polypropylene, polyvinyl chloride, polyvinylidene chloride, polyurethane, epoxy resin and melamine resin.

Claim 14

An electrophotographic imaging process according to claim 6 or 7 wherein said insulating layer comprises polyester.