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US4251612A Expired / Lapsed US ⏱️ 0.0 years remaining

Dielectric overcoated photoresponsive imaging member

Assignee: Xerox Corp
•
Filing: 1978-05-12
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Granted: 1981-02-17
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Expires: 1998-05-12
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Abstract

Abstract This invention relates to an electrophotographic imaging member or device and an imaging method using this imaging member, which member or device is comprised of a substrate, a layer of a charge carrier injecting material comprised of carbon or graphite dispersed in a polymer, a layer of a charge carrier transport material, a layer of a photoconductive charge carrier generating material and an electrically insulating overcoating layer. In one embodiment the imaging member is layered and comprises from the bottom up a substrate; a layer of material comprised of carbon black dispersed in a polymer, and capable of injecting holes into a layer on its surface; a hole transport layer in operative contact with the layer of hole injecting material which transport layer comprises a combination of an electrically inactive organic resin having dispersed therein an electrically active material, the combination of which is substantially nonabsorbing to visible electromagnetic radiation, but allows the injecting of photogenerated holes from a charge generator layer in contact with the hole transport layer and electrically induced holes from the layer of injecting material; a layer of charge generating material on and in operative connection with the charge transport layer and a layer of insulating organic resin overlaying the layer of charge generating material.

Inventors

  • 👤 Joseph Y. C. Chu
  • 👤 Simpei Tutihasi

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-01 12:55
CPC Classifications
G; G03; G03G; G03G5/00; G03G5/10; G03G5/02; G03G5/04; G03G5/043; G03G5/0436; G03G5/047

Claims Analysis

Total Claims: 16
Claim 1
Independent Claim 161 words
A layered photosensitive imaging member which comprises from the bottom up: (a) an electrically conductive substrate; (b) a layer of material capable of injecting holes into a layer on its surface, this layer being comprised of materials selected from the group consisting of carbon dispersed in a polymer and graphite dispersed in a polymer; (c) a hole transport layer in operative contact with the layer of hole injecting material, which transport layer comprises a combination of a highly insulating organic resin having dispersed therein small molecules of an electrically active material, the combination of which is substantially non-absorbing to visible light but allows injection of photogenerated holes from a charge generator in contact with the hole transport layer and electrically induced holes from the layer of injecting material; (d) a layer of charge generating photoconductive material on and in operative contact with the charge transport layer; and (e) a layer of insulating organic resin overlaying the layer of charge generating material.
Claim 2
Dependent Claim 161 words
A layered photosensitive imaging member which comprises from the bottom up: (a) an electrically conductive substrate; (b) a layer of material capable of injecting holes into a layer on its surface, this layer being comprised of materials selected from the group consisting of carbon dispersed in a polymer and graphite dispersed in a polymer; (c) a hole transport layer in operative contact with the layer of hole injecting material, which transport layer comprises a combination of a highly insulating organic resin having dispersed therein small molecules of an electrically active material, the combination of which is substantially non-absorbing to visible light but allows injection of photogenerated holes from a charge generator in contact with the hole transport layer and electrically induced holes from the layer of injecting material; (d) a layer of charge generating photoconductive material on and in operative contact with the charge transport layer; and (e) a layer of insulating organic resin overlaying the layer of charge generating material.
Claim 3
Dependent Claim 20 words
An imaging member in accordance with claim 1 wherein the hole injecting material is carbon black dispersed in a polyester.
Claim 4
Dependent Claim 19 words
An imaging member in accordance with claim 1 wherein the hole injecting material is graphite dispersed in a polyester.
Claim 5
Dependent Claim 16 words
An imaging member in accordance with claim 1 wherein the substrate is a polyethylene terphthalate film.
Claim 6
Dependent Claim 24 words
An imaging member in accordance with claim 1 wherein the ratio of polymer to carbon black or graphite ranges from about 0.5:1 to 2:1.
Claim 7
Dependent Claim 27 words
An imaging member in accordance with claim 1 wherein the hole injecting electrode has a thickness in the range of from about 1 to about 20 microns.
Claim 8
Dependent Claim 27 words
An imaging member in accordance with claim 1 wherein the hole injecting electrode has a thickness in the range of from about 4 to about 10 microns.
Claim 9
Dependent Claim 55 words
An imaging member in accordance with claim 1 wherein the electrically active material dispersed in the insulating organic resin is a nitrogen containing compound of the formula: ##STR2## wherein X is selected from the group consisting of (ortho) CH 3 , (meta) CH 3 , (para) CH 3 , (ortho) Cl, (meta) Cl, (para) Cl.
Claim 10
Dependent Claim 24 words
An imaging member in accordance with claim 8 wherein the hole transport layer contains from about 10 to 75% of the nitrogen containing composition.
Claim 11
Dependent Claim 15 words
An imaging member in accordance with claim 1 wherein the transport layer is N,N'-diphenyl-N,N'-bis(3-methyl phenyl)-[1,1'-biphenyl]-4,4'-diamine.
Claim 12
Dependent Claim 33 words
An imaging member in accordance with claim 1 wherein the charge generating photoconductive layer is selected from the group consisting of amorphous selenium, trigonal selenium, arsenic triselenide, metal free phthalocyanines and metal phthalocyanines.
Claim 13
Dependent Claim 17 words
An imaging member in accordance with claim 11 wherein the charge generating photoconductive layer is amorphous selenium.
Claim 14
Dependent Claim 17 words
An imaging member in accordance with claim 11 wherein the charge generating photoconductive layer is trigonal selenium.
Claim 15
Dependent Claim 14 words
An imaging member in accordance with claim 11 wherein the phthalocyanine is vanadyl phthalocyanine.
Claim 16
Dependent Claim 15 words
An imaging member in accordance with claim 1 wherein layer (e) is a polyurethane resin.

References Cited (Backward Citations)

US3639121A Cited
US3899327A Cited
US4015985A Cited
US4133684A Cited
US4123269A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1984-02-17 1984-08-18 1985-02-17 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1988-02-17 1988-08-18 1989-02-17 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1992-02-17 1992-08-18 1993-02-17 $7700.00 Window Closed / Lapsed

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