Photopolymerizable photosensitive composition

Claim 2

A photopolymerizable photosensitive composition comprising: (a) a photopolymerizable photosensitive high molecular weight compound having polyfunctional ethylenically unsaturated groups in the side chains or end groups thereof, wherein said polyfunctional ethylenically unsaturated groups have structural units of the general formula ##STR10## wherein R 1 represents a hydrogen atom, alkyl group or hydroxyalkyl group, R 2 represents an alkylene group, R 3 and R 4 independently represent a hydrogen atom or methyl group, R 5 represents a hydrogen atom or carboxyl group, m is 0 or 1 and n is 2 or 3 provided that m+n=3, p is an integer of 1 to 3, and q is an integer of 0 to 3 and (b) a photopolymerization initiator.

Claim 3

A photopolymerizable photosensitive composition of claim 1 wherein R 2 is methylene group and p is 1.

Claim 4

A photopolymerizable photosensitive composition according to claim 1, further comprising an ethylenically unsaturated compound.

Claim 5

The photopolymerizable photosensitive composition of claim 1 wherein R 1 is --CH 3 or --C 2 H 5 .

Claim 6

The photopolymerizable photosensitive composition of claim 1 wherein R 1 is hydroxymethyl or hydroxyethyl.

Claim 7

The photopolymerizable photosensitive composition of claim 1 wherein R 2 is ethylene or trimethylene.

Claim 8

The photopolymerizable photosensitive composition of claim 1 which further includes 5-500 parts by weight of an additional polymer per 100 parts by weight of said photopolymerizable photosensitive resin.

Claim 9

The photopolymerizable photosensitive composition of claim 7 wherein said additional polymer is an acrylic acid or methacrylic acid homopolymer.

Claim 10

The photopolymerizable photosensitive composition of claim 7 wherein said additional polymer is a copolymer of acrylic or methacrylic acid and at least one compound selected from the group consisting of vinyl ether, vinyl acetate, styrene, vinylpyrrolidone, butadiene and saponified vinyl acetate.

Claim 11

The photopolymerizable photosensitive composition of claim 7 wherein said additional polymer is a copolymer of (i) at least one compound selected from the group consisting of polyacrylic anhydride, maleic acid, maleic acid semiester, maleic acid semiamide, maleic anhydride or itaconic acid and (ii) at least one compound selected from the group consisting of styrene, ethylene, vinyl ether and vinyl acetate.

Claim 12

The photopolymerizable photosensitive composition of claim 7 wherein said additional polymer is a derivative of cellulose.

Claim 13

The photopolymerizable photosensitive composition of claim 3 wherein said ethylenically unsaturated compound is selected from the group consisting of ethylenically unsaturated carboxylic

Claim 14

acids, esters of aliphatic polyhydroxy compounds and unsaturated carboxylic acids, esters of aromatic polyhydroxy compounds and unsaturated carboxylic acids, and polyesters from unsaturated polycarboxylic acids and polyhydroxy compounds.

Claim 15

acids, esters of aliphatic polyhydroxy compounds and unsaturated carboxylic acids, esters of aromatic polyhydroxy compounds and unsaturated carboxylic acids, and polyesters from unsaturated polycarboxylic acids and polyhydroxy compounds.

Claim 16

The photopolymerizable photosensitive composition of claim 12 wherein said ethylenically unsaturated carboxylic acid is selected from the group consisting of acrylic acid, methacrylic acid, itaconic acid, crotonic acid and maleic acid.

Claim 17

The photopolymerizable photosensitive composition of claim 12 wherein said esters of aliphatic polyhydroxy compounds and unsaturated carboxylic acids are selected from the group consisting of ethylene glycol diacrylate, triethylene glycol diacrylate, tetramethylene glycol diacrylate, trimethylolpropane triacrylate, trimethylolethane triacrylate, pentaerythritol diacrylate, pentaerythritol triacrylate, pentaerythritol tetraacrylate, dipentaerythritol tetraacrylate, dipentaerythritol pentaacrylate, dipentaerythritol hexaacrylate, tripentaerythritol octaacrylate, glycerol diacrylate, triethylene glycol dimethacrylate, tetramethylene glycol dimethacrylate, trimethylolpropane trimethacrylate, trimethylolethane trimethacrylate, pentaerythritol dimethacrylate, pentaerythritol trimethacrylate, pentaerythritol tetraacrylate, dipentaerythritol dimethacrylate, dipentaerythritol trimethacrylate, dipentaerythritol tetramethacrylate, tripentaerythritol octamethacrylate, ethylene glycol dimethacrylate, 1,2-butanediol dimethacrylate, sorbitol tetramethacrylate, ethylene gylcol diitaconate, propylene glycol diitaconate, 1,2-butanediol diitaconate, tetramethylene glycol diitaconate, pentaerythritol triitaconate, ethylene glycol dicrotonate, diethylene glycol dicrotonate, pentaerythritol tetracrotonate, ethylene glycol dimaleate, triethylene glycol dimaleate, and pentaerythritol dimaleate.

Claim 18

The photopolymerizable photosensitive composition of claim 14 wherein said esters of aliphatic polyhydroxy compounds and unsaturated carboxylic acids are selected from the group consisting of trimethylolpropane triacrylate, trimethylolethane triacrylate and pentaerythritol tetraacrylate.

Claim 19

The photopolymerizable photosensitive composition of claim 12 wherein said esters of aromatic polyhydroxy compounds and unsaturated carboxylic acids are selected from the group consisting of hydroquinone diacrylate, hydroquinone dimethacrylate, resorcin diacrylate, resorcin dimethacrylate, and pyrogallol triacrylate.

Claim 20

The photopolymerizable photosensitive composition of claim 12 wherein said polyesters from unsaturated polycarboxylic acids and polyhydroxy compounds are selected from the group consisting of ##STR11## wherein Z is an acryloyl or methacryloyl group.

Claim 21

The photopolymerizable photosensitive composition of claim 3, wherein said ethylenically unsaturated compound is selected from the group consisting of acrylamide, ethylene bisacrylamide, hexamethylene bisacrylamide, ethylene bismethacrylamide, hexamethylene bismethacrylamide, diallyl phthalate, diallyl malonate, diallyl fumarate, triallyl isocyanurate, divinyl adipate, divinyl phthalate, and ethylene glycol divinyl ether.

Claim 22

The photopolymerizable photosensitive composition of claim 1 wherein said photopolymerization initiator is selected from the group consisting of benzoin, benzoin alkyl ethers, benzophenone, anthraquinone, benzil, Michler's ketone, a biimidazole Michler's ketone mixture, a biimidazoledialkylaminostyryl derivative mixture, a S-triazinecyanine derivative mixture, and S-triazine-thiapyrylium derivative mixture.

Claim 23

The photopolymerizable photosensitive composition of claim 2 wherein said composition comprises 10-80 weight percent of said photopolymerizable photosensitive high molecular weight compound, 90-20 weight percent of said ethylenically unsaturated compound and 0.1-20 weight percent of said photopolymerization initiator.

Claim 24

The photopolymerizable photosensitive composition of claim 20 wherein said composition comprises 20-60 weight percent of said photopolymerizable photosensitive high molecular weight compound, 80-40 weight percent of said ethylenically unsaturated compound and 1-10 weight percent of said photopolymerization initiator.

Claim 25

The photopolymerizable photosensitive composition of claim 1 wherein said composition further comprises 0.1 to 20 weight percent of a thermal polymerization inhibitor, antioxidant, colorant, plasticizer, application aid or a combination thereof.

Claim 26

The photopolymerizable photosensitive composition of claim 22 further comprising an organic solvent selected from the group consisting of methyl ethyl ketone, acetone, cyclohexanone, ethyl acetate, butyl acetate, amyl acetate, ethyl propionate, toluene, xylene, benzene, monochlorobenzene, chloroform, carbon tetrachloride, trichloroethylene, trichloroethane, dimethylformamide, methyl cellosolve, ethyl cellosolve, butyl cellosolve, tetrahydrofuran, 4-methyl-4-methoxy-2-pentanone, methanol, ethanol, and propanol.

Claim 27

The photopolymerizable photosensitive composition of claim 3 wherein said composition further comprises 0.1 to 20 weight percent of a thermal polymerization inhibitor, antioxidant, colorant, plasticizer, application aid or a combination thereof.

Claim 28

The photopolymerizable photosensitive composition of claim 24 further comprising an organic solvent selected from the group consisting of methyl ethyl ketone, acetone, cyclohexanone, ethyl acetate, butyl acetate, amyl acetate, ethyl propionate, toluene, xylene, benzene, monochlorobenzene, chloroform, carbon tetrachloride, trichloroethylene, trichloroethane, dimethylformamide, methyl cellosolve, ethyl cellosolve, butyl cellosolve, tetrahydrofuran, 4-methyl-4-methoxy-2-pentanone, methanol, ethanol, and propanol.