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Microemulsions from vegetable oil and aqueous alcohol with 1-butanol surfactant as alternative fuel for diesel engines

Assignee: United States Department of Agriculture
•
Filing: 1982-09-24
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Granted: 1985-07-02
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Expires: 2002-09-24
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Abstract

Abstract Hybrid fuel microemulsions are prepared from vegetable oil, a C 1 -C 3 alcohol, water, and 1-butanol as the nonionic surfactant. These fuels are characterized by an acceptable viscosity and compare favorably to No. 2 diesel fuel in terms of engine performance properties.

Inventors

  • 👤 Arthur W. Schwab
  • 👤 Everett H. Pryde

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-08 18:17
CPC Classifications
C; C10; C10L; C10L1/00; C10L1/32; C10L1/328; F; F02; F02B; F02B3/00; F02B3/06; Y; Y10; Y10S; Y10S516/00; Y10S516/01; Y10S516/06; Y10S516/07

Claims Analysis

Total Claims: 7
Claim 1
Independent Claim 142 words
A nonionic hybrid fuel composition comprising: (a) from about 40-65% by volume vegetable oil composed of vegetable triglycerides in which the preponderance of the fatty acid ester moieties have a chain length of 18 or more carbon atoms; (b) a lower (C 1 14 C 3 ) alcohol; (c) water, in an amount of at least about 0.1% by volume; and (d) 1-butanol wherein the ratio of the lower (C 1 -C 3 ) alcohol:water is at least 4:1 and wherein said butanol is present in the fuel composition in an amount effective for said composition to exist as a thermodynamically stable microemulsion and the combined amount of lower alcohol, water, and 1-butanol relative to said vegetable oil is 35-60% by volume and is sufficient to impart to said composition a kinematic viscosity in the range of 2-9 centistokes at 37.8° C.
Claim 2
Dependent Claim 142 words
A nonionic hybrid fuel composition comprising: (a) from about 40-65% by volume vegetable oil composed of vegetable triglycerides in which the preponderance of the fatty acid ester moieties have a chain length of 18 or more carbon atoms; (b) a lower (C 1 14 C 3 ) alcohol; (c) water, in an amount of at least about 0.1% by volume; and (d) 1-butanol wherein the ratio of the lower (C 1 -C 3 ) alcohol:water is at least 4:1 and wherein said butanol is present in the fuel composition in an amount effective for said composition to exist as a thermodynamically stable microemulsion and the combined amount of lower alcohol, water, and 1-butanol relative to said vegetable oil is 35-60% by volume and is sufficient to impart to said composition a kinematic viscosity in the range of 2-9 centistokes at 37.8° C.
Claim 3
Dependent Claim 35 words
A hybrid fuel composition as described in claim 1 wherein said vegetable oil is selected from the group consisting of soybean, corn, rapeseed, sesame, cottonseed, crambe, sunflower seed, peanut, linseed, safflower, and high oleic safflower.
Claim 4
Dependent Claim 16 words
A hybrid fuel composition as described in claim 1 wherein said vegetable oil is soybean oil.
Claim 5
Dependent Claim 17 words
A hybrid fuel composition as described in claim 1 wherein said vegetable oil is sunflower seed oil.
Claim 6
Dependent Claim 15 words
A hybrid fuel composition as described in claim 1 wherein said lower alcohol is ethanol.
Claim 7
Dependent Claim 17 words
A hybrid fuel composition as described in claim 5 wherein the ratio of ethanol:water is about 19:1.

References Cited (Backward Citations)

US2892694A Cited
US4083698A Cited
US4297107A Cited
US4300912A Cited
US4359324A Cited
US4397655A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1988-07-01 1988-12-31 1989-07-02 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1992-07-01 1992-12-31 1993-07-02 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1996-07-01 1996-12-31 1997-07-02 $7700.00 Window Closed / Lapsed

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