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US4522971A Expired / Lapsed US ⏱️ 0.0 years remaining

Polymers containing resorcinol monobenzoate

Assignee: EIDP Inc
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Filing: 1983-02-25
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Granted: 1985-06-11
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Expires: 2003-02-25
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Abstract

Abstract Resorcinol monobenzoate is reacted through the hydroxyl group preferably with an acrylic prepolymer containing glycidyl methacrylate. The product can be used in coating compositions and films to give highly ultraviolet absorbent properties.

Inventors

  • 👤 Michael DeBergalis

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-31 14:15
CPC Classifications
C; C08; C08F; C08F8/00; C08F20/00; C08F20/02; C08F20/10; C08F20/26; C08F20/30; C08G; C08G85/00; C09; C09D; C09D7/00; C09D7/40; C09D7/48; C08K; C08K5/00; C08K5/04; C08K5/10; C08K5/101; C08K5/103

Claims Analysis

Total Claims: 17
Claim 1
Independent Claim 113 words
A polymer comprising a polymeric moiety reacted with resorcinol monobenzoate or a derivative containing resorcinol monobenzoate, said moiety being bound to the hydroxyl group on the resorcinol monobenzoate through a linking group, wherein the polymer contains, by weight, 12.5-80% resorcinol monobenzoate, the balance being said moiety, said linking group including at least one group selected from the group consisting of ether, carbonate, and urethane groups and ester groups containing at least two carbon atoms, said derivative fitting the structure ##STR10## wherein R and R' are hydrogen or alkyl or alkoxy groups containing 1-14 carbon atoms, and wherein there is at least one unsubstituted position on the a ring ortho to the carbonyl groups.
Claim 2
Dependent Claim 113 words
A polymer comprising a polymeric moiety reacted with resorcinol monobenzoate or a derivative containing resorcinol monobenzoate, said moiety being bound to the hydroxyl group on the resorcinol monobenzoate through a linking group, wherein the polymer contains, by weight, 12.5-80% resorcinol monobenzoate, the balance being said moiety, said linking group including at least one group selected from the group consisting of ether, carbonate, and urethane groups and ester groups containing at least two carbon atoms, said derivative fitting the structure ##STR10## wherein R and R' are hydrogen or alkyl or alkoxy groups containing 1-14 carbon atoms, and wherein there is at least one unsubstituted position on the a ring ortho to the carbonyl groups.
Claim 3
Dependent Claim 26 words
A coating composition comprising a polymer of claim 1 wherein the solids portion of the coating composition contains by weight at least about 12.5% resorcinol monobenzoate.
Claim 4
Dependent Claim 22 words
A coating composition comprising a polymer of claim 2 wherein the coating composition containing by weight at least about 15-50% resorcinol monobenzoate.
Claim 5
Dependent Claim 43 words
A coating composition of claim 2 wherein the resorcinol monobenzoate absorbs incident ultraviolet radiation and photorearranges to produce dihydroxy benzophenone which remains bonded to the polymer, and wherein said dihydroxy benzophenone absorbs incident ultraviolet radiation and dissipates the resulting energy largely as heat.
Claim 6
Dependent Claim 12 words
The coating composition of claim 2 which also contains a liquid carrier.
Claim 7
Dependent Claim 18 words
The coating composition of claim 5 wherein the liquid carrier contains at least 10% by weight organic solvents.
Claim 8
Dependent Claim 22 words
The coating composition of claim 5 wherein the liquid carrier is aqueous and contains not more than 10% by weight organic solvents.
Claim 9
Dependent Claim 12 words
The coating composition of claim 5 which also contains a cross linker.
Claim 10
Dependent Claim 13 words
The coating composition of claim 5 which does not contain a cross linker.
Claim 11
Dependent Claim 15 words
The coating composition of claim 2 wherein said polymer is used as a dry powder.
Claim 12
Dependent Claim 20 words
A film comprising a polymer of claim 1 wherein the film contains, by weight, at least about 12.5% resorcinol monobenzoate.
Claim 13
Dependent Claim 35 words
The polymer of claim 1 wherein said moiety comprises one or more acrylic monomers which include glycidyl methacrylate, and the hydroxyl group on the resorcinol monobenzoate bonds to the epoxy group on the glycidyl methacrylate.
Claim 14
Dependent Claim 12 words
The polymer of claim 1 which contains, by weight, 20-50% resorcinol monobenzoate.
Claim 15
Dependent Claim 18 words
The polymer of claim 1 which has a number average molecular weight about in the range of 1,500-45,000.
Claim 16
Dependent Claim 20 words
The polymer of claim 1 which contains on the average at least about 2.1 mers of resorcinol monobenzoate per molecule.
Claim 17
Dependent Claim 39 words
The polymer of claim 1 which contains, by weight, about 15-80% resorcinol monobenzoate, which has a number average molecular weight about in the range of 1,500-45,000 and which contains at least about 2.1 mers of resorcinol monobenzoate per molecule.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1988-06-10 1988-12-10 1989-06-11 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1992-06-10 1992-12-10 1993-06-11 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1996-06-10 1996-12-10 1997-06-11 $7700.00 Window Closed / Lapsed

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