US4294949A
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Novel polymeric compounds
Assignee: BASF Corp
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Filing: 1980-01-25
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Granted: 1981-10-13
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Expires: 2000-01-25
Abstract
Abstract Homopolymeric acrylates and methacrylates which carry N-heterocyclic rings in a side position and their copolymers with compounds containing at least one polymerizable double bond are suitable as additives for plastics.
Inventors
- 👤 Friedrich Karrer
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-01 19:13
CPC Classifications
C; C07; C07D; C07D471/00; C07D471/02; C07D471/10; C07D211/00; C07D211/04; C07D211/06; C07D211/36; C07D211/40; C07D211/44; C07D211/46; C07D211/56; C07D211/58; C08; C08F; C08F20/00; C08F20/02; C08F20/10; C08F20/34; C08F20/52; C08F20/54; C08F20/60; C08L; C08L101/00
Claims Analysis
Total Claims: 13
Claim 1
Independent Claim
369 words
A copolymer of a compound which carries N-heterocyclic rings in a side position and has the recurring structural unit of the formula I ##STR19## in which R 1 is a group, containing an N-heterocyclic ring, of the formulae II, III, IV and V ##STR20## in which R 5 is hydrogen, oxyl, C 1 -C 18 alkyl, 2-hydroxyethyl, 2-hydroxypropyl, C 3 -C 8 alkenyl, C 3 -C 6 alkynyl, C 7 -C 12 aralkyl, C 2 -C 21 alkoxyalkyl, an aliphatic acyl group having 1-4 C atoms or one of the groups --CH 2 COOR 7 or --COOR 8 , in which R 7 is C 1 -C 12 alkyl, C 3 -C 8 alkenyl, phenyl, C 7 -C 8 aralkyl or cyclohexyl and R 8 is C 1 -C 12 alkyl, phenyl, benzyl or cyclohexyl, and R 6 is hydrogen or C 1 -C 4 alkyl and Y is --O-- or ##STR21## in which R 9 is hydrogen, C 1 -C 12 alkyl, C 7 -C 12 aralkyl or cyclohexyl, and X 1 is a group of the formula --O--CH(R 10 )--CH 2 -- (VI) or denotes --O--CH 2 --CH 2 --CH 2 --, in which R 10 is hydrogen, methyl, ethyl, phenoxymethyl or phenyl, and n is 0 or 1, and X 2 is a group of the formula VI, in which R 10 is as defined above, or a group of the formula --O--CH 2 --CH(OH)--CH 2 -- (VII), and m is 0 or 1, and R 11 is C 1 -C 18 alkyl or is cyclohexyl, phenyl or benzyl which are unsubstituted or substituted by C 1 -C 4 alkyl or C 1 -C 4 alkoxy, and R 2 is hydrogen or C 1 -C 4 alkyl, and, if R 2 and R 4 are hydrogen, R 1 and R 3 together form a group of the formula VIII ##STR22## in which R 5 and R 6 are as defined above and R 3 is hydrogen or C 1 -C 2 alkyl and R 4 is hydrogen or methyl, with a compound containing at least one polymerisable double bond, the molar ratio of the component of the formula I to the co-component being up to 1:10.
Claim 2
Dependent Claim
369 words
A copolymer of a compound which carries N-heterocyclic rings in a side position and has the recurring structural unit of the formula I ##STR19## in which R 1 is a group, containing an N-heterocyclic ring, of the formulae II, III, IV and V ##STR20## in which R 5 is hydrogen, oxyl, C 1 -C 18 alkyl, 2-hydroxyethyl, 2-hydroxypropyl, C 3 -C 8 alkenyl, C 3 -C 6 alkynyl, C 7 -C 12 aralkyl, C 2 -C 21 alkoxyalkyl, an aliphatic acyl group having 1-4 C atoms or one of the groups --CH 2 COOR 7 or --COOR 8 , in which R 7 is C 1 -C 12 alkyl, C 3 -C 8 alkenyl, phenyl, C 7 -C 8 aralkyl or cyclohexyl and R 8 is C 1 -C 12 alkyl, phenyl, benzyl or cyclohexyl, and R 6 is hydrogen or C 1 -C 4 alkyl and Y is --O-- or ##STR21## in which R 9 is hydrogen, C 1 -C 12 alkyl, C 7 -C 12 aralkyl or cyclohexyl, and X 1 is a group of the formula --O--CH(R 10 )--CH 2 -- (VI) or denotes --O--CH 2 --CH 2 --CH 2 --, in which R 10 is hydrogen, methyl, ethyl, phenoxymethyl or phenyl, and n is 0 or 1, and X 2 is a group of the formula VI, in which R 10 is as defined above, or a group of the formula --O--CH 2 --CH(OH)--CH 2 -- (VII), and m is 0 or 1, and R 11 is C 1 -C 18 alkyl or is cyclohexyl, phenyl or benzyl which are unsubstituted or substituted by C 1 -C 4 alkyl or C 1 -C 4 alkoxy, and R 2 is hydrogen or C 1 -C 4 alkyl, and, if R 2 and R 4 are hydrogen, R 1 and R 3 together form a group of the formula VIII ##STR22## in which R 5 and R 6 are as defined above and R 3 is hydrogen or C 1 -C 2 alkyl and R 4 is hydrogen or methyl, with a compound containing at least one polymerisable double bond, the molar ratio of the component of the formula I to the co-component being up to 1:10.
Claim 3
Dependent Claim
227 words
A copolymer of a compound according to claim 1, of the formula I, in which R 1 is a group of the formulae II, III, IV or V, in which R 5 is hydrogen, C 1 -C 12 alkyl, 2-hydroxyethyl, 2-hydroxypropyl, C 3 -C 5 alkenyl, propargyl, C 7 -C 8 aralkyl, acetyl or C 2 -C 10 alkoxyalkyl and R 6 is hydrogen or methyl and Y is --O-- or ##STR23## in which R 9 is hydrogen, C 1 -C 12 alkyl or benzyl, and X 1 is a group of the formula VI or denotes --O--CH 2 --CH 2 --CH 2 --, in which R 10 is hydrogen or methyl, and n is 0 or 1, and X 2 is a group of the formulae VI or VII, in which R 10 is as defined above, and m is 0 or 1, and R 11 is C 1 -C 12 alkyl or benzyl, and R 2 is hydrogen or C 1 -C 2 alkyl, or, if R 2 and R 4 are hydrogen, R 1 and R 3 together form a group of the formula VIII, in which R 5 and R 6 are as defined above, and R 3 is hydrogen or C 1 -C 2 alkyl and R 4 is hydrogen or methyl, with a compound containing at least one polymerisable double bond.
Claim 4
Dependent Claim
154 words
A copolymer of a compound according to claim 1, of the formula I, in which R 1 is a group of the formula II or IV, in which R 5 is hydrogen, C 1 -C 8 alkyl, benzyl or acetyl and R 6 is hydrogen or methyl and Y is --O-- or ##STR24## in which R 9 is hydrogen or C 1 -C 8 alkyl, and X 2 is a group of the formula IV or VII, in which R 10 is hydrogen, methyl or ethyl, and m is 0 or 1, and R 2 is hydrogen or methyl or, if R 2 and R 4 are hydrogen, R 1 and R 3 together are a group of the formula VIII, in which R 5 and R 6 are as defined above, and R 3 is hydrogen or methyl and R 4 is hydrogen, with a compound containing at least one polymerisable double bond.
Claim 5
Dependent Claim
127 words
A copolymer of a compound according to claim 1, of the formula I, in which R 1 is a group of the formula II or IV, in which R 5 is hydrogen, C 1 -C 4 alkyl, benzyl or acetyl and R 6 is hydrogen and Y is --O-- or ##STR25## in which R 9 is hydrogen or C 1 -C 4 alkyl, and X 2 is a group of the formula VI or VII, in which R 10 is hydrogen or methyl, and m is 0 or 1, and R 2 and R 3 independently of one another are hydrogen or methyl and R 4 is hydrogen, with styrene, acrylonitrile, an acrylate or a methacrylate, a vinyl ester, a vinyl ether or an acrylamide or methacrylamide.
Claim 6
Dependent Claim
114 words
A copolymer of a compound according to claim 1, of the formula I, in which R 1 is a group of the formula II or IV, in which R 5 is hydrogen, methyl or acetyl and R 6 is hydrogen and Y is --O-- or ##STR26## in which R 9 is hydrogen or C 1 -C 4 alkyl, and X 2 is group of the formula VI or VII, in which R 10 is hydrogen, and m is 0 or 1, and R 3 and R 4 are hydrogen and R 2 is hydrogen or methyl, with styrene, acrylonitrile, an acrylate or methacrylate, a vinyl ester, a vinyl ether or an acrylamide or methacrylamide.
Claim 7
Dependent Claim
46 words
A copolymer of a compound of the formula I according to claim 1, with a methyl, ethyl or butyl acrylate or methacrylate, a maleimide, N-vinyl-pyrrolidone or a glycidyl acrylate, the molar ratio of the component of the formula I to the co-component being up to 1:10.
Claim 8
Dependent Claim
40 words
A homopolymeric compound with the recurring structural unit of the formula I, according to claim 1, in which R 1 is a group of the formula III, IV or V and the other symbols are as defined in claim 1.
Claim 9
Dependent Claim
21 words
A homopolymeric compound according to claim 1, wherein R 1 and R 3 together form a group of the formula VIII.
Claim 10
Dependent Claim
17 words
A homopolymeric compound according to claim 7, wherein R 1 is a group of the formula IV.
Claim 11
Dependent Claim
17 words
A homopolymeric compound according to claim 7, wherein R 1 is a group of the formula V.
Claim 12
Dependent Claim
28 words
A homopolymeric or copolymeric compound according to claim 1, of the formula I, in which R 1 and R 3 together are a grouping of the formula VIII.
Claim 13
Dependent Claim
7 words
A copolymeric compound according to claim 11.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1984-10-12 | 1985-04-13 | 1985-10-13 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1988-10-12 | 1989-04-13 | 1989-10-13 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1992-10-12 | 1993-04-13 | 1993-10-13 | $7700.00 | Window Closed / Lapsed |