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Flame resistant sulfur-bearing copolycarbonate

Assignee: Bayer Corp
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Filing: 1980-09-09
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Granted: 1985-05-07
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Expires: 2000-09-09
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Abstract

Abstract The invention relates to an aromatic, high molecular weight thermoplastic copolycarbonate comprising the reaction product of a sulfur-free aromatic diphenol, a sulfur-containing diphenol, a branching agent and a carbonic acid derivative, characterized in having improved flame resistance. The invention further relates to a process for the preparation of said copolycarbonate.

Inventors

  • 👤 Arthur L. Baron
  • 👤 Sivaram Krishnan

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-08 09:56
CPC Classifications
C; C08; C08G; C08G64/00; C08G64/04; C08G64/06; C08G64/08; C08G64/081

Claims Analysis

Total Claims: 7
Claim 1
Independent Claim 195 words
An aromatic high molecular weight copolycarbonate comprising the polymeric reaction product of solely (i) an aromatic sulfur-free diphenol represented by the structural formula ##STR5## wherein b is zero or 1, Y denotes an alkylene or alkylidene radical with 1 to 7 carbon atoms, a cycloalkylene or cycloalkylidene radical with 5 to 12 carbon atoms, --O-- or --CO--; (ii) a sulfur-containing diphenol represented by the formula ##STR6## wherein R 1 and R 2 independently denote a lower alkyl selected from a group consisting of methyl, ethyl, propyl and butyl; n is equal to from 0 to 2 and T is either S, SO or SO 2 ; (iii) a branching agent for polycarbonates; (iv) a monophenol; and (v) a carbonic acid derivative selected from a group consisting of phosgene, carbonyl bromide or bis-chloroformic esters of an aromatic dihydroxy compound; characterized in that said branching agent comprises between 0.05 and 2%, relative to the molar sum of said (i) plus said (ii) and in that said copolycarbonate comprises at least 15 mol percent of said (ii) and in that they are classified V-O for 1/16" class specimens as evaluated by the procedure of Underwriter's Laboratories Bulletin 94.
Claim 2
Dependent Claim 195 words
An aromatic high molecular weight copolycarbonate comprising the polymeric reaction product of solely (i) an aromatic sulfur-free diphenol represented by the structural formula ##STR5## wherein b is zero or 1, Y denotes an alkylene or alkylidene radical with 1 to 7 carbon atoms, a cycloalkylene or cycloalkylidene radical with 5 to 12 carbon atoms, --O-- or --CO--; (ii) a sulfur-containing diphenol represented by the formula ##STR6## wherein R 1 and R 2 independently denote a lower alkyl selected from a group consisting of methyl, ethyl, propyl and butyl; n is equal to from 0 to 2 and T is either S, SO or SO 2 ; (iii) a branching agent for polycarbonates; (iv) a monophenol; and (v) a carbonic acid derivative selected from a group consisting of phosgene, carbonyl bromide or bis-chloroformic esters of an aromatic dihydroxy compound; characterized in that said branching agent comprises between 0.05 and 2%, relative to the molar sum of said (i) plus said (ii) and in that said copolycarbonate comprises at least 15 mol percent of said (ii) and in that they are classified V-O for 1/16" class specimens as evaluated by the procedure of Underwriter's Laboratories Bulletin 94.
Claim 3
Dependent Claim 15 words
The aromatic high molecular weight copolycarbonate of claim 1, wherein said aromatic diphenol is 2,2-bis-(4-hydroxy-phenyl)-propane.
Claim 4
Dependent Claim 15 words
The aromatic high molecular weight copolycarbonate of claim 1, wherein said sulfur-containing diphenol is 4,4'-thiodiphenol.
Claim 5
Dependent Claim 38 words
The aromatic high molecular weight copolycarbonate of claim 1, wherein said branching agent is represented by the general formula ##STR7## wherein R 1 denotes a 4-hydroxyaryl radical and R 2 and R 3 independently denote hydrogen or halogen.
Claim 6
Dependent Claim 16 words
The aromatic high molecular weight copolycarbonate of claim 4, wherein said branching agent is isatin biscresol.
Claim 7
Dependent Claim 31 words
The aromatic high molecular weight copolycarbonate of claim 1 or claim 5, wherein said sulfur-containing diphenol comprises between 15 and 30 mol percent relative to the number of mols of diphenols.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1988-05-06 1988-11-05 1989-05-07 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1992-05-06 1992-11-05 1993-05-07 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1996-05-06 1996-11-05 1997-05-07 $7700.00 Window Closed / Lapsed

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