Crosslinkable composition of matter-IV

Claim 2

A self-crosslinkable substantially gel-free conjugated diene-functionalized dieneophile-functionalized epoxy-amine adduct, preferably of number average molecular weight about 500-8000, comprising the reaction product of (i) polyhydroxy functional epoxy-amine reactant comprising the reaction product of polyepoxy reactant having an average of at least about 2 epoxy groups per molecule with secondary amine reactant having a total of less than about 20 carbons per amino nitrogen, wherein each hydroxy group, if any, of the secondary amine is removed at least 1 carbon from each amino nitrogen, with (ii) conjugated diene functional mono-isocyanate reactant and with (iii) dieneophile functional mono-isocyanate reactant other than said conjugated diene functional mono-isocyanate reactant.

Claim 3

The self-crosslinkable epoxy-amine adduct of claim 1, wherein the polyepoxy reactant for said polyhydroxy functional epoxy-amine reactant is selected from the group consisting of Bisphenol A-epichlorohydrin epoxy resin, Novolak epoxy resin, aliphatic epoxy resins and a compatible mixture of any of them.

Claim 4

The self-crosslinkable epoxy-amine adduct of claim 1, wherein the polyepoxy reactant for said polyhydroxy functional epoxy-amine reactant has number average molecular weight about 700-8000.

Claim 5

The self-crosslinkable epoxy-amine adduct of claim 1, wherein said secondary amine reactant said polyhydroxy functional epoxy-amine reactant is selected from the group consisting of dialkylamine, dialkanolamine, N-alkylaniline and a compatible mixture of any of them, wherein each alkyl moiety and each alkanol moiety has from one to about ten carbons.

Claim 6

The self-crosslinkable epoxy-amine adduct of claim 3, wherein said secondary amine reactant for said polyhydroxy functional epoxy-amine reactant consists essentially of diethanolamine.

Claim 7

The self-crosslinkable epoxy-amine adduct of claim 1, wherein said diene functional mono-isocyanate reactant comprises the reaction product of (a) diisocyanate reactant in approximately one-to-one molar ratio with (b) diene reactant selected from the group consisting of monohydroxy functional diene reactant, monoamino functional diene reactant and a compatible mixture of any of them.

Claim 8

The self-crosslinkable epoxy-amine adduct of claim 6, wherein said diisocyanate reactant is selected from the group consisting of phenylene diisocyanate, toluene diisocyanate, isophorone diisocyanate, diisocyanatoalkane wherein the alkyl moiety has about three to about ten carbons and a compatible mixture of any of them.

Claim 9

The self-crosslinkable epoxy-amine adduct of claim 6, wherein said diene reactant is selected from the group consisting of furfuryl alcohol, furfuryl amine, 2-hydroxymethyl-1,3-butadiene, 2-aminomethyl-1,3-butadiene and a compatible mixture of any of them.

Claim 10

The self-crosslinkable epoxy-amine adduct of claim 1, wherein said dieneophile functional mono-isocyanate reactant comprises the reaction product of (i) diisocyanate reactant in approximately 1:1 molar ratio with (ii) dieneophile reactant selected from the group consisting of monohydroxy functional dieneophile reactant, monoamino functional dieneophile reactant and a compatible mixture of any of them.

Claim 11

The self-crosslinkable epoxy-amine adduct of claim 9, wherein said dieneophile reactant is selected from the group consisting of methylolmaleimide, hydroxypropyl-methacrylate, allyl alcohol, allyl amine, hydroxyethyl-methacrylate, hydroxyethylacrylate, and a compatible mixture of any of them.

Claim 12

The self-crosslinkable epoxy-amine adduct of claim 9, wherein said diisocyanate reactant is selected from the group consisting of phenylene diisocyanate, toluene diisocyanate, isophorone diisocyanate, diisocyanatoalkane wherein the alkyl moiety has about three to about ten carbons and a compatible mixture of any of them.

Claim 13

The self-crosslinkable epoxy-amine adduct of claim 1, wherein at least a portion of said diene-functionalized dieneophile-functionalized epoxy-amine adduct bears hydroxy functionality, said composition further comprising crosslinking agent substantially reactive with hydroxy functionality.

Claim 14

The self-crosslinkable epoxy-amine adduct of claim 1 adapted for use in coating compositions that retard corrosion of corrosion susceptible substrates, further comprising organic solvent, wherein said diene-functionalized dieneophile-functionalized epoxy-amine adduct is of number average molecular weight about 500-5000.

Claim 15

A crosslinkable composition of matter adapted for use in electrodeposition of coatings on a substrate, which coatings are heat curable, which composition comprises: substantially gel-free conjugated diene-functionalized dieneophile-functionalized epoxy-amine adduct, at least partially neutralized with solubilizing acid, comprising the reaction product of: (i) polyhydroxy functional epoxy-amine reactant comprising the reaction product of polyepoxy reactant having an average of at least about 2 epoxy groups per molecule, with secondary amine reactant having a total of less than about 20 carbons per amino nitrogen, wherein each hydroxy group, if any, of the secondary amine is removed at least 1 carbon from each amino nitrogen; with (ii) conjugated diene functional mono-isocyanate reactant; and with (iii) dieneophile functional mono-isocyanate reactant other than said conjugated diene functional mono-isocyanate reactant which at least partially neutralized diene-functionalized dieneophile-functionalized epoxy-amine adduct is dispersed in aqueous solvent.

Claim 16

A crosslinkable composition of matter adapted for use in electrodeposition of coatings on a substrate, which coatings are heat curable, which composition comprises: substantially gel-free conjugated diene-functionalized dieneophile-functionalized epoxy-amine adduct, at least partially neutralized with solubilizing acid, comprising the reaction product of: (i) polyhydroxy functional epoxy-amine reactant comprising the reaction product of polyepoxy reactant having an average of at least about 2 epoxy groups per molecule, with secondary amine reactant having a total of less than about 20 carbons per amino nitrogen, wherein each hydroxy group, if any, of the secondary amine is removed at least 1 carbon from each amino nitrogen; with (ii) conjugated diene functional mono-isocyanate reactant; and with (iii) dieneophile functional mono-isocyanate reactant other than said conjugated diene functional mono-isocyanate reactant which at least partially neutralized diene-functionalized dieneophile-functionalized epoxy-amine adduct is dispersed in aqueous solvent.

Claim 17

The crosslinkable composition of matter of claim 14, wherein said polyepoxy reactant for said polyhydroxy functional epoxy-amine reactants has number average molecular weight about 700-8000.

Claim 18

The crosslinkable composition of matter of claim 14, wherein said secondary amine reactant for said polyhydroxy functional epoxy-amine reactant is selected from the group consisting of dialkylamine, dialkanolamine, N-alkylaniline or a compatible mixture of any of them, wherein each alkyl moiety and each alkanol moiety has from one to about ten carbons.

Claim 19

The crosslinkable composition of matter of claim 14, wherein said secondary amine reactant for said polyhydroxy functional epoxy-amine reactant consists essentially of diethanolamine.

Claim 20

The crosslinkable composition of matter of claim 14, wherein said diene functional mono-isocyanate reactant comprises the reaction product of (a) diisocyanate reactant in approximately 1:1 molar ratio with (b) diene reactant selected from the group consisting of monohydroxy functional diene reactant, monoamino functional diene reactant and a compatible mixture of any of them.

Claim 21

The crosslinkable composition of matter of claim 18, wherein said diisocyanate reactant is selected from the group consisting of phenylene diisocyanate, toluene diisocyanate, isophorone diisocyanate, diisocyanatoalkane wherein the alkyl moiety has about three to about ten carbons and a compatible mixture of any of them.

Claim 22

The crosslinkable composition of matter of claim 18, wherein said diene reactant is selected from the group consisting of furfuryl alcohol, furfuryl amine, 2-hydroxymethyl-1,3-butadiene, 2-aminomethyl-1,3-butadiene and the like and a compatible mixture of any of them.

Claim 23

The crosslinkable composition of matter of claim 14, wherein said dieneophile functional mono-isocyanate reactant comprises the reaction product of (i) diisocyanate reactant in approximately 1:1 molar ratio with (ii) dieneophile reactant selected from the group consisting of monohydroxy functional dieneophile reactant, monoamino functional dieneophile reactant and a compatible mixture of any of them.

Claim 24

The crosslinkable composition of matter of claim 21, wherein said dieneophile reactant is selected from the group consisting of methylolmaleimide, hydroxypropyl-methacrylate, allyl alcohol, allyl amine, hydroxyethyl-methacrylate, hydroxyethylacrylate and a compatible mixture of any of them.

Claim 25

The crosslinkable composition of matter of claim 21, wherein said diisocyanate reactant is selected from the group consisting of phenylene diisocyanate, toluene diicoyanate, isophorone diisocyanate, diisocyanatoalkane wherein the alkyl moiety has about three to about ten carbons and a compatible mixture of any of them.

Claim 26

The crosslinkable composition of matter of claim 14, wherein said diene-functionalized epoxy-amine adduct and said dieneophile-functionalized epoxy-amine adduct are each at least partially neutralized with organic acid selected from the group consisting of acetic acid, lactic acid, formic acid, butyric acid and a compatible mixture of any of them.

Claim 27

The crosslinkable composition of matter according to claim 14, wherein at least a portion of diene-functionalized dieneophile-functionalized epoxy-amine adduct bears hydroxy functionality, said composition further comprising crosslinking agent substantially reactive with said hydroxy functionality.

Claim 28

The crosslinkable composition of matter of claim 14 further comprising an organic coupling solvent miscible with water.

Claim 29

The crosslinkable composition of matter according to claim 14, wherein said diene-functionalized dieneophile-functionalized epoxy-amine adduct is of number average molecular weight about 500-800.

Claim 30

A crosslinkable composition of matter adapted for use in electrodeposition of coatings on a substrate, which coatings are heat curable, which composition comprises: substantially gel-free diene-functionalized dieneophile-functionalized epoxy-amine adduct of number average molecular weight about 500-8000, at least partially neutralized with solubilizing acid selected from the group consisting of acetic acid, lactic acid, formic acid, buryric acid and a compatible mixture of any of them, which diene-functionalized epoxy-amine adduct comprises the reaction product of: (i) polyhydroxy functional epoxy-amine reactant comprising the reaction product of polyepoxide reactant having an average of at least about two epoxy groups per molecule with secondary amine reactant selected from the group consisting of dialkanolamine wherein each alkanol moiety has about one to three carbons; with (ii) diene functional mono-isocyante reactant comprising the reaction product of (a) diisocyanate reactant selected from the group consisting of phenylene diisocyanate, toluene diisocyanate, isophorone diisocyanate, diisocyanatoalkane wherein the alkyl moiety has about three to about ten carbons, and a compatible mixture of any of them, with (b) diene reactant selected from the group consisting of furfuryl amine, 2-aminomethyl-1,3-butadiene and a compatible mixture of any of them; and with (iii) dieneophile functional mono-isocyanate reactant comprising the reaction product of (a) diisocyanate reactant selected from the group consisting of phenylene diisocyanate, toluene diisocyanate, isophorone diisocyanate, diisocyanatoalkane wherein the alkyl moiety has about three to about ten carbons, and a compatible mixture of any of them, with (b) dieneophile reactant selected from the group consisting of methylolmaleimide, hydroxypropyl-methacrylate, allyl alcohol, allyl amine, hydroxyethyl-methacrylate, hydroxyethylacrylate and a compatible mixture of any of them; which at least partially neutralized diene-functionalized dieneophile-functionalized epoxy-amine adduct is dispersed together in aqueous solvent.

Claim 31

A crosslinkable composition of matter adapted for use in electrodeposition of coatings on a substrate, which coatings are heat curable, which composition comprises: substantially gel-free diene-functionalized dieneophile-functionalized epoxy-amine adduct of number average molecular weight about 500-8000, at least partially neutralized with solubilizing acid selected from the group consisting of acetic acid, lactic acid, formic acid, buryric acid and a compatible mixture of any of them, which diene-functionalized epoxy-amine adduct comprises the reaction product of: (i) polyhydroxy functional epoxy-amine reactant comprising the reaction product of polyepoxide reactant having an average of at least about two epoxy groups per molecule with secondary amine reactant selected from the group consisting of dialkanolamine wherein each alkanol moiety has about one to three carbons; with (ii) diene functional mono-isocyante reactant comprising the reaction product of (a) diisocyanate reactant selected from the group consisting of phenylene diisocyanate, toluene diisocyanate, isophorone diisocyanate, diisocyanatoalkane wherein the alkyl moiety has about three to about ten carbons, and a compatible mixture of any of them, with (b) diene reactant selected from the group consisting of furfuryl amine, 2-aminomethyl-1,3-butadiene and a compatible mixture of any of them; and with (iii) dieneophile functional mono-isocyanate reactant comprising the reaction product of (a) diisocyanate reactant selected from the group consisting of phenylene diisocyanate, toluene diisocyanate, isophorone diisocyanate, diisocyanatoalkane wherein the alkyl moiety has about three to about ten carbons, and a compatible mixture of any of them, with (b) dieneophile reactant selected from the group consisting of methylolmaleimide, hydroxypropyl-methacrylate, allyl alcohol, allyl amine, hydroxyethyl-methacrylate, hydroxyethylacrylate and a compatible mixture of any of them; which at least partially neutralized diene-functionalized dieneophile-functionalized epoxy-amine adduct is dispersed together in aqueous solvent.