US4147676A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Cathodically depositable coating compositions and method of preparing
Assignee: Allnex Austria GmbH
•
Filing: 1977-11-07
•
Granted: 1979-04-03
•
Expires: 1997-11-07
Abstract
Abstract Heat curable binders for use in cathodically depositable aqueous coating compositions characterized in that curing is through alpha, beta-double bonds on end or side chains of the binders are described. The binders are the reaction product of 2 moles of a diepoxide; 1 mole of a secondary-secondary or primary-tertiary diamine; 2 moles of monocarboxylic acid, and an alpha, beta-unsaturated monoisocyanate, and have an alpha, beta-functionality of from about 0.8 to 2.5. The binders are rendered water soluble by neutralization with inorganic and/or organic acids. Coating compositions comprising such binders cure at low temperatures and short curing times to provide films having excellent resistance to water, chemicals, and corrosion.
Inventors
- 👤 Georgios Pampouchidis
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-26 16:54
CPC Classifications
C; C09; C09D; C09D5/00; C09D5/44; C09D5/4419; C09D5/443; C09D5/4434; C08; C08G; C08G18/00; C08G18/06; C08G18/28; C08G18/40; C08G18/64; C08G18/6407; C08G18/70; C08G18/81; C08G18/8141; C08G18/815; C08G18/8158; Y; Y10; Y10S; Y10S524/00; Y10S524/901
Claims Analysis
Total Claims: 21
Claim 1
Independent Claim
110 words
Self-crosslinking cathodically depositable binders comprising the reaction product of (A) the reaction product of (a) 2 moles of a diepoxy compound having an epoxy equivalent of at least 100; (b) 1 mole of a member of the group consisting of aliphatic diamines, cycloaliphatic diamines, aromatic diamines, and mixtures thereof, the nitrogen atoms of said diamines being secondary-secondary or primary-tertiary nitrogen atoms; and (c) 2 moles of a member of the group consisting of saturated monocarboxylic acids, unsaturated monocarboxylic acids, and mixtures thereof; and (B) an alpha,beta-ethylenically unsaturated monoisocyanate; the alpha,beta-double bond functionality of said binder being at least 0.5 and said binder being water soluble upon neutralization with an acid.
Claim 2
Dependent Claim
110 words
Self-crosslinking cathodically depositable binders comprising the reaction product of (A) the reaction product of (a) 2 moles of a diepoxy compound having an epoxy equivalent of at least 100; (b) 1 mole of a member of the group consisting of aliphatic diamines, cycloaliphatic diamines, aromatic diamines, and mixtures thereof, the nitrogen atoms of said diamines being secondary-secondary or primary-tertiary nitrogen atoms; and (c) 2 moles of a member of the group consisting of saturated monocarboxylic acids, unsaturated monocarboxylic acids, and mixtures thereof; and (B) an alpha,beta-ethylenically unsaturated monoisocyanate; the alpha,beta-double bond functionality of said binder being at least 0.5 and said binder being water soluble upon neutralization with an acid.
Claim 3
Dependent Claim
17 words
The binder of claim 1 wherein the alpha,beta-double bond functionality is from about 0.8 to about 2.5.
Claim 4
Dependent Claim
20 words
The binder of claim 1 wherein there are at least 0.5 basic nitrogen atoms per 1000 grams of binder solids.
Claim 5
Dependent Claim
20 words
The binder of claim 1 wherein there are more than 0.7 basic nitrogen atoms per 1000 grams of binder solids.
Claim 6
Dependent Claim
34 words
The binder of claim 1 wherein the alpha,beta-ethylenically unsaturated monoisocyanate is the reaction product of a polyisocyanate and an alpha,beta-ethylenically unsaturated monomer carrying at least one isocyanate reactive hydrogen atom and the group ##STR4##
Claim 7
Dependent Claim
9 words
The binder of claim 1 including a plasticizing isocyanate.
Claim 8
Dependent Claim
25 words
The binder of claim 6 wherein the plasticizing isocyanate is the reaction product of a polyisocyanate and a monoalcohol having at least six carbon atoms.
Claim 9
Dependent Claim
10 words
The binder of claim 7 wherein the monoalcohol is unsaturated.
Claim 10
Dependent Claim
10 words
The binder of claim 7 wherein the monoalcohol is saturated.
Claim 11
Dependent Claim
125 words
Process of producing self-crosslinking cathodically depositable binders comprising reacting (a) 2 moles of a diepoxy compound having an epoxy equivalent of at least 100; (b) 1 mole of a member of the group consisting of aliphatic diamines, cycloaliphatic diamines, aromatic diamines, and mixtures thereof, the nitrogen atoms of said diamines being secondary-secondary or primary-tertiary nitrogen atoms, and (c) 2 moles of the member of the group consisting of saturated monocarboxylic acids, unsaturated monocarboxylic acids, and mixtures thereof; and subsequently reacting the hydroxyl groups of the reaction product of (a), (b), and (c) with (d) an alpha,beta-ethylenically unsaturated monoisocyanate, the quantities of monocarboxylic acid (c) and unsaturated monoisocyanate (d) being selected in order that the reaction product has an alpha,beta-double bond functionality of at least 0.5.
Claim 12
Dependent Claim
125 words
Process of producing self-crosslinking cathodically depositable binders comprising reacting (a) 2 moles of a diepoxy compound having an epoxy equivalent of at least 100; (b) 1 mole of a member of the group consisting of aliphatic diamines, cycloaliphatic diamines, aromatic diamines, and mixtures thereof, the nitrogen atoms of said diamines being secondary-secondary or primary-tertiary nitrogen atoms, and (c) 2 moles of the member of the group consisting of saturated monocarboxylic acids, unsaturated monocarboxylic acids, and mixtures thereof; and subsequently reacting the hydroxyl groups of the reaction product of (a), (b), and (c) with (d) an alpha,beta-ethylenically unsaturated monoisocyanate, the quantities of monocarboxylic acid (c) and unsaturated monoisocyanate (d) being selected in order that the reaction product has an alpha,beta-double bond functionality of at least 0.5.
Claim 13
Dependent Claim
22 words
The process of claim 10 including the steps of rendering said binder water soluble by neutralization with an inorganic or organic acid.
Claim 14
Dependent Claim
20 words
The process of claim 10 wherein the double bond functionality of said binder is from about 0.8 to about 2.5.
Claim 15
Dependent Claim
31 words
The process of claim 10 wherein the ratio of components (a)-(d) are selected in order that at least 0.5 basic nitrogen atoms are present for each 1000 grams of binder solids.
Claim 16
Dependent Claim
31 words
The process of claim 10 wherein the ratio of components (a)-(d) are selected in order that more than 0.7 basic nitrogen atoms are present for each 1000 grams of binder solids.
Claim 17
Dependent Claim
34 words
The process of claim 10 wherein the alpha,beta-ethylenically unsaturated monoisocyanate is the reaction product of a polyisocyanate and an alpha,beta-ethylenically unsaturated monomer carrying at least one isocyanate reactive hydrogen atom and the group ##STR5##
Claim 18
Dependent Claim
51 words
The process of claim 10 wherein (c) is an alpha,beta-unsaturated monocarboxylic acid and the reaction between components (a) and (b) is carried out at from about 100° to 170° C. prior to the introduction of component (c), followed by introduction of (c) and reaction at from about 100° to 130° C.
Claim 19
Dependent Claim
39 words
The process of claim 10 wherein component (c) is a saturated monocarboxylic acid or an unsaturated monocarboxylic acid without alpha,beta-double bonds, and (a), (b), and (c) are simultaneously reacted at a temperature of from about 100° to 170° C.
Claim 20
Dependent Claim
11 words
The process of claim 10 wherein a plasticizing isocyanate is added.
Claim 21
Dependent Claim
25 words
The process of claim 18 wherein the plasticizing isocyanate is the reaction product of a polyisocyanate and a monoalcohol having at least six carbon atoms.
References Cited (Backward Citations)
US3499824A
Cited
US3799854A
Cited
US4031050A
Cited
US3804786A
Cited
US3883483A
Cited
US3922253A
Cited
US3947339A
Cited
US3891602A
Cited
US3992345A
Cited
US4036795A
Cited
US4036800A
Cited
US4016120A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1982-04-02 | 1982-10-02 | 1983-04-03 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1986-04-02 | 1986-10-02 | 1987-04-03 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1990-04-02 | 1990-10-02 | 1991-04-03 | $7700.00 | Window Closed / Lapsed |