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US4500628A Expired / Lapsed US ⏱️ 0.0 years remaining

Process of making solid state devices using silicon containing organometallic plasma developed resists

Assignee: Nokia Bell Labs
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Filing: 1983-06-27
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Granted: 1985-02-19
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Expires: 2003-06-27
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Abstract

Abstract Solid state devices are produced by dry etching of a resist film to produce a negative resist pattern. The film comprises a polymer typically containing a halogen, and at least one type of silicon-containing or nonsilicon-containing organometallic monomer. The radiation, typically X-ray radiation, locks the monomer or monomers into the polymer, with a subsequent fixing step removing the unlocked monomer or monomers in the unirradiated portion of the resist. The film is then exposed to a plasma comprising oxygen, which removes the unirradiated portion at a faster rate than the radiated portion, producing a negative resist pattern. The plasma development is typically accomplished by reactive ion etching. Sensitizers can be used to extend the wavelength response of the films, typically into the ultraviolet or visible regions.

Inventors

  • 👤 Gary N. Taylor

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-03 18:31
CPC Classifications
G; G03; G03F; G03F7/00; G03F7/26; G03F7/36; C; C07; C07F; C07F7/00; C07F7/02; C07F7/08; C07F7/0803; C07F7/081; C07F7/18; C07F7/1804; G03F7/004; G03F7/075; G03F7/0755; Y; Y10; Y10S; Y10S148/00; Y10S148/137; Y10S430/00; Y10S430/167; Y10S430/168; Y10S438/00; Y10S438/942; Y10S438/948; Y10S438/949

Claims Analysis

Total Claims: 12
Claim 1
Independent Claim 133 words
In a method of producing a solid state device that includes at least one pattern delineation steps, the steps comprising: (a) selectively irradiating a resist film on a substrate with actinic radiation, wherein said film comprises a polymer and at least one type of monomer; (b) treating said film to reduce the amount of said at least one type of monomer in the unirradiated portion of said film; and (c) developing said film in a plasma comprising oxygen, thereby removing the unirradiated portion of the film at a faster rate than the irradiated portion, thereby producing a negative resist pattern, the invention CHARACTERIZED in that said at least one type of monomer includes at least one type of silicon-containing organometallic monomer selected from the group consisting of bis-acryloxybutyltetramethyldisiloxane, bis-methacryloxybutyltetramethyldisiloxane, m-dimethylphenylsilylphenyl acrylate or methacrylate.
Claim 2
Dependent Claim 133 words
In a method of producing a solid state device that includes at least one pattern delineation steps, the steps comprising: (a) selectively irradiating a resist film on a substrate with actinic radiation, wherein said film comprises a polymer and at least one type of monomer; (b) treating said film to reduce the amount of said at least one type of monomer in the unirradiated portion of said film; and (c) developing said film in a plasma comprising oxygen, thereby removing the unirradiated portion of the film at a faster rate than the irradiated portion, thereby producing a negative resist pattern, the invention CHARACTERIZED in that said at least one type of monomer includes at least one type of silicon-containing organometallic monomer selected from the group consisting of bis-acryloxybutyltetramethyldisiloxane, bis-methacryloxybutyltetramethyldisiloxane, m-dimethylphenylsilylphenyl acrylate or methacrylate.
Claim 3
Dependent Claim 34 words
The method of claim 14 FURTHER CHARACTERIZED in that said at least one type of silicon-containing organometallic monomer is m-dimethylphenylsilylphenyl acrylate, and said polymer is poly(2,3-dichloro-1-propyl acrylate) or poly(2,3-dibromo-1-propyl acrylate) or a copolymer thereof.
Claim 4
Dependent Claim 26 words
The method of claim 1 FURTHER CHARACTERIZED in that said at least one type of silicon-containing organometallic monomer is bis-acryloxybutyltetramethyldisiloxane, and said polymer is poly(2,3-dichloro-1-propyl acrylate).
Claim 5
Dependent Claim 27 words
The method of claim 1 FURTHER CHARACTERIZED in that said plasma further comprises at least one halocarbon species so that cracking of said film is substantially eliminated.
Claim 6
Dependent Claim 33 words
The method of claim 1 FURTHER CHARACTERIZED in that an electrical bias is applied to said substrate relative to the source of said plasma, whereby said developing is accomplished by reactive ion etching.
Claim 7
Dependent Claim 21 words
The method of claim 1 FURTHER CHARACTERIZED in that said polymer is poly(2,3-dichloro-1-propyl acrylate), or poly(2,3-dibromo-1-propyl acrylate), or a copolymer thereof.
Claim 8
Dependent Claim 28 words
The method of claim 1 FURTHER CHARACTERIZED in that said resist film further comprises a sensitizer to enhance the sensitivity of said resist to ultraviolet or visible radiation.
Claim 9
Dependent Claim 39 words
The method of claim 1 FURTHER CHARACTERIZED in that said polymer is a rubbery polymer, and said film comprises at least one silicon-containing organometallic monomer type having a molecular weight in the range of 200 grams/mole to 800 grams/mole.
Claim 10
Dependent Claim 15 words
The method of claim 1 FURTHER CHARACTERIZED in that said polymer is a glassy polymer.
Claim 11
Dependent Claim 16 words
The method of claim 1 FURTHER CHARACTERIZED in that one type of monomer is m-dimethylphenylsilylphenyl acrylate.
Claim 12
Dependent Claim 15 words
The method of claim 1 FURTHER CHARACTERIZED in that one type of monomer is bis-acryloxybutyltetramethyldisiloxane.

References Cited (Backward Citations)

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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1988-02-19 1988-08-20 1989-02-19 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1992-02-19 1992-08-20 1993-02-19 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1996-02-19 1996-08-20 1997-02-19 $7700.00 Window Closed / Lapsed

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