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US4474860A Expired / Lapsed US ⏱️ 0.0 years remaining

High solids latexes for paper coatings

Assignee: Dow Chemical Co
•
Filing: 1983-05-16
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Granted: 1984-10-02
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Expires: 2003-05-16
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Abstract

Abstract Bimodal latexes having two separate and distinct particle size distributions have high solids content, good high shear rheology and good low shear viscosity. These bimodal latexes, e.g., styrene/butadiene/acrylic acid/itaconic acid latexes are employed in coating paper in conjunction with a mineral filler using a coating device such as a blade coater to yield high quality coatings which can be easily applied.

Inventors

  • 👤 Ronald L. Van Gilder
  • 👤 Do I. Lee

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-24 17:14
CPC Classifications
D; D21; D21H; D21H19/00; D21H19/36; D21H19/44; D21H19/56; D21H19/58; C; C09; C09D; C09D125/00; C09D125/02; C09D125/04; C09D125/08; C09D125/10; C08; C08L; C08L2205/00; C08L2205/02; C08L25/00; C08L25/02; C08L25/04; C08L25/08; C08L25/10; Y; Y10; Y10T; Y10T428/00; Y10T428/31504; Y10T428/31855; Y10T428/3188; Y10T428/31895

Claims Analysis

Total Claims: 15
Claim 1
Independent Claim 233 words
An improved hight solids formulation for coating paper which comprises an aqueous medium having dispersed therein a functionally effective amount of a finely divided mineral filler and a high solids synthetic bimodal latex comprising two separate and distinct particles size distributions and comprising in polymerized form open chain conjugated diene and alkenyl mononuclear aromatic monomers; wherein each of said distributions comprises particles which are substantially uniform in diameter such that said latex, when mixed with said filler in said aqueous medium, provides a coating formulation which approaches a viscosity which is no longer manageable at a higher solids content than that solids content exhibited by a formulation comprising an aqueous medium, a filler and a monodisperse or highly multi-disperse latex; whereby the small latex particles of said distribution of the bimodal latex provide the capability to provide an increase in the solids content and a decrease in viscosity at high shear of the formulation over that of a formulation comprising a monodisperse latex of a particle size similar to that of the large latex particle distribution of the bimodal latex; and whereby the large latex particles of said distribution of the bimodal latex provide the capability to increase the solids contend of the formulation at low shear over that of a formulation comprising a monodisperse latex of a particle size similar to that of the small latex particle distribution of the bimodal latex.
Claim 2
Dependent Claim 233 words
An improved hight solids formulation for coating paper which comprises an aqueous medium having dispersed therein a functionally effective amount of a finely divided mineral filler and a high solids synthetic bimodal latex comprising two separate and distinct particles size distributions and comprising in polymerized form open chain conjugated diene and alkenyl mononuclear aromatic monomers; wherein each of said distributions comprises particles which are substantially uniform in diameter such that said latex, when mixed with said filler in said aqueous medium, provides a coating formulation which approaches a viscosity which is no longer manageable at a higher solids content than that solids content exhibited by a formulation comprising an aqueous medium, a filler and a monodisperse or highly multi-disperse latex; whereby the small latex particles of said distribution of the bimodal latex provide the capability to provide an increase in the solids content and a decrease in viscosity at high shear of the formulation over that of a formulation comprising a monodisperse latex of a particle size similar to that of the large latex particle distribution of the bimodal latex; and whereby the large latex particles of said distribution of the bimodal latex provide the capability to increase the solids contend of the formulation at low shear over that of a formulation comprising a monodisperse latex of a particle size similar to that of the small latex particle distribution of the bimodal latex.
Claim 3
Dependent Claim 43 words
A formulation of claim 1 wherein the latex has a particle size of said two separate and distinct distributions are in the range from about 500 Å to about 1000 Å and from about 1500 Å to about 10,000 Å in diameter, respectively.
Claim 4
Dependent Claim 24 words
A formulation of claim 1 comprising a bimodal latex comprising styrene/butadiene, styrene/butadiene/acrylic acid, styrene/butadiene/vinylidene chloride, styrene/butadiene/β-hydroxyethyl acrylate, styrene/butadiene/β-hydroxyethlacrylate/acrylic acid and/or styrene/butadiene/acrylic acid/itaconic acid latexes.
Claim 5
Dependent Claim 12 words
A formulation of claim 1 comprising a styrene/butadiene/acrylic acid/itaconic acid bimodal latex.
Claim 6
Dependent Claim 15 words
A process for coating paper which comprises applying the formulation of claim 1 to paper.
Claim 7
Dependent Claim 19 words
A process for coating paper which comprises applying the formulation of claim 1 to paper using a blade coater.
Claim 8
Dependent Claim 20 words
A coated article comprising a fibrous sheet continuously coated on at least one surface with the formulation of claim 1.
Claim 9
Dependent Claim 42 words
A formulation of claim 1 wherein the latex has a particle size of said separate and distinct distributions are in the range from about 600 Å to about 800 Å and from about 1800 Å to about 3000 Å in diameter, respectively.
Claim 10
Dependent Claim 28 words
A formulation of claim 1 wherein the diameter of the large latex particles range from about 2.5 to about 10 times the diameter of the small latex particles.
Claim 11
Dependent Claim 28 words
A formulation of claim 1 wherein the diameter of the large latex particles range from about 3 to about 4 times the diameter of the small latex particles.
Claim 12
Dependent Claim 33 words
A formulation of claim 1 wherein said bimodal latex comprises from about 50 to about 98 weight percent large size particles and from about 2 to about 50 weight percent small size particles.
Claim 13
Dependent Claim 33 words
A formulation of claim 1 wherein said bimodal latex comprises from about 60 to about 80 weight percent large size particles and from about 20 to about 40 weight percent small size particles.
Claim 14
Dependent Claim 29 words
A formulation of claim 1 wherein said formulation has a solids content of from about 60 to about 75 weight percent based on the total weight of the formulation.
Claim 15
Dependent Claim 24 words
A formulation of claim 13 wherein said solids content comprises about 100 parts filler and from about 2 to about 20 parts bimodal latex.

References Cited (Backward Citations)

US3399080A Cited
US4046730A Cited
US4069188A Cited
US4247438A Cited
US4254004A Cited
US4322330A Cited
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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1987-10-02 1988-04-02 1988-10-02 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1991-10-02 1992-04-02 1992-10-02 $3760.00 Window Closed / Lapsed
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