← Back to Patent Explorer
US4384056A Expired / Lapsed US ⏱️ 0.0 years remaining

Aqueous dispersions based on (meth)acrylic acid alkyl ester polymers with two pronounced, substantially non-overlapping peaks in the particle size distribution within specific particle size ranges, and a process for the preparation and use thereof

Assignee: Bayer AG
•
Filing: 1981-04-28
•
Granted: 1983-05-17
•
Expires: 2001-04-28
📄 Original PDF 🌐 Google Patents 🔄 Sync Now

Abstract

Abstract Aqueous dispersions of polymers containing (meth)acrylic acid alkyl ester units which contain the polymer in the form of relatively large, non-agglomerated, spherical particles (=main spheres) and relatively small, non-agglomerated, spherical particles (=filler spheres), wherein the smaller filler spheres have an average particle diameter dF measured using an electron microscope of from 50 to 150 nanometers (nm) and the average diameter of the large main spheres dH is from 1.35 to 3.5 times larger than the average particle diameter dF, provided that dH is at least 140 nm, and wherein the ratio of the total mass of the polymer composed of main spheres MH to the total mass of the polymer composed of filler spheres MF is MH:MF=20:1 to MH:MF=1:20 and wherein at least 70% of the number of main spheres and at least 70% of the number of filler spheres lie in the range of +/-25% of the respective average value of dH or dF. Dispersions of this type dry to form clear, lustrous and waterproof films, even with a solids content of from 37 to 45% by weight, and even if that solids content has been obtained from more highly concentrated dispersions by dilution with water. The dispersions are used as binders in or as aqueous paint and coating agents for plastics, metals, wood, glass, paper, and cardboard articles, as binders in print dyes, road marking paints and in impregnation or reinforcing agents for paper, leather, woven and non-woven textiles.

Inventors

  • 👤 Adolf Schmidt
  • 👤 Gunter Kolb
  • 👤 Werner Clarenz

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-25 02:02
CPC Classifications
C; C08; C08J; C08J3/00; C08J3/02; C08J3/03; C09; C09D; C09D133/00; C09D133/04; C09D133/06; C08J2333/00; C08J2333/04; C08J2333/06; C08L; C08L2205/00; C08L2205/02; C08L33/00; C08L33/04; C08L33/06

Claims Analysis

Total Claims: 10
Claim 1
Independent Claim 234 words
An aqueous dispersion containing as binder at least one film-forming polymer comprising copolymerized units of from 48 to 60% by weight n-butyl acrylate; from 35 to 48% by weight styrene; from 4 to 6% by weight methacrylic acid or acrylic acid or a mixture thereof, and from 0 to 13% by weight N-methoxymethylmethacrylamide, the sum of the percentages by weight being 100, said polymer being in the form of larger, non-agglomerated, spherical particles or main spheres and smaller, non-agglomerated spherical particles or filler spheres, wherein the filler spheres have an average particle diameter d F measured using an electron microscope of from 50 to 150 nanometers and the average diameter of the main spheres d H is at least 140 mn--there are two pronounced, substantially non-overlapping peaks in the particle size distribution within the specified particle size ranges and the ratio of the total mass of the polymer composed of main spheres M H to the total mass of the polymer composed of filler spheres M F is M.sub.H :M.sub.F =20:1 to M.sub.H :M.sub.F =1:20 and wherein at least 70% of the number of main spheres and at least 70% of the number of filler spheres lie in the range of ±25% of the respective given average value of d H or d F and wherein, if the dispersion contains several differing polymers with respect to chemical and percentage composition, they are mutually compatible.
Claim 2
Dependent Claim 234 words
An aqueous dispersion containing as binder at least one film-forming polymer comprising copolymerized units of from 48 to 60% by weight n-butyl acrylate; from 35 to 48% by weight styrene; from 4 to 6% by weight methacrylic acid or acrylic acid or a mixture thereof, and from 0 to 13% by weight N-methoxymethylmethacrylamide, the sum of the percentages by weight being 100, said polymer being in the form of larger, non-agglomerated, spherical particles or main spheres and smaller, non-agglomerated spherical particles or filler spheres, wherein the filler spheres have an average particle diameter d F measured using an electron microscope of from 50 to 150 nanometers and the average diameter of the main spheres d H is at least 140 mn--there are two pronounced, substantially non-overlapping peaks in the particle size distribution within the specified particle size ranges and the ratio of the total mass of the polymer composed of main spheres M H to the total mass of the polymer composed of filler spheres M F is M.sub.H :M.sub.F =20:1 to M.sub.H :M.sub.F =1:20 and wherein at least 70% of the number of main spheres and at least 70% of the number of filler spheres lie in the range of ±25% of the respective given average value of d H or d F and wherein, if the dispersion contains several differing polymers with respect to chemical and percentage composition, they are mutually compatible.
Claim 3
Dependent Claim 50 words
An aqueous dispersion according to claim 1, wherein the average particle diameter d H is from 80 to 130 nm, the average diameter d F is from 1.8 to 3.5 times greater than d F and the total mass ratio M H to M F is from 1:10 to 2:1.
Claim 4
Dependent Claim 22 words
An aqueous dispersion according to claim 1, wherein the solids content of the film-forming polymer is from 37 to 55% by weight.
Claim 5
Dependent Claim 108 words
A method for the preparation of an aqueous dispersion according to claim 1, wherein a dispersion containing the polymer in the form of the larger, non-agglomerated spherical particles or main spheres is intimately distributed in a dispersion containing the polymer in the form of the smaller, non-agglomerated, spherical particles or filler spheres in the given mass ratio according to claim 1, wherein the pH of the total dispersion thus obtained is adjusted to a pH value of from 7 to 9 by addition of a non-ionogenic emulsifier in a quantity of from 0.5 to 3% by weight, based on polymer, and wherein the resulting total dispersion is stabilized.
Claim 6
Dependent Claim 11 words
An aqueous paint containing an aqueous dispersion according to claim 1.
Claim 7
Dependent Claim 20 words
A coating agent for plastics, metals, wood, glass, paper or cardboard articles containing an aqueous dispersion according to claim 1.
Claim 8
Dependent Claim 14 words
A road-marking paint containing an aqueous dispersion according to claim 1 as a binder.
Claim 9
Dependent Claim 17 words
Print dyes for textiles and leather containing an aqueous dispersion according to claim 1 as a binder.
Claim 10
Dependent Claim 23 words
Impregnation or compacting agents for paper, woven or non-woven textiles and leather containing an aqueous dispersion according to claim 1 as a binder.

References Cited (Backward Citations)

US3876578A Cited
US4046730A Cited
US4247438A Cited
US4219454A Cited
US4254004A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1986-05-16 1986-11-15 1987-05-17 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1990-05-16 1990-11-15 1991-05-17 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1994-05-16 1994-11-15 1995-05-17 $7700.00 Window Closed / Lapsed

Assigned Categories & Tags

No categories assigned to this patent yet.

Assign Category Tag