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US4395500A Expired / Lapsed US ⏱️ 0.0 years remaining

Protective colloid-free plastics dispersion having a bimodal particle size distribution

Assignee: Hoechst AG
•
Filing: 1981-09-29
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Granted: 1983-07-26
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Expires: 2001-09-29
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Abstract

Abstract A protective colloid-free plastics dispersion yielding after drying a polymer film which under the influence of moisture has no or little tendency to whitening contains polymer particles having a bimodal size distribution, that is, on the one hand relatively coarse particles and on the other hand relatively fine particles. The polymer component consists of at least 10 weight % of particles having an average diameter of less than 0.2 mu m and of 90 weight % at most of particles having an average diameter of more than 0.25 mu m, and the ratio of average grain size of coarse to fine polymer is at least 2:1. The plastics dispersion is suitable especially as binder dispersion in plasters and gloss paints.

Inventors

  • 👤 Gernot Lohr
  • 👤 Rolf Reinecke

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-26 15:34
CPC Classifications
C; C09; C09D; C09D5/00; C09D5/02; C08; C08J; C08J3/00; C08J3/02; C08J3/03; C09D5/34

Claims Analysis

Total Claims: 4
Claim 1
Independent Claim 145 words
A protective colloid free plastics aqueous dispersion having a bimodal particle size distribution, wherein the plastics portion consists of from 60 to 80 weight % of a coarse-grain polymer having an average particle size of more than 0.25 μm and from 40 to 20 weight % of a fine-grain polymer having an average particle size of below 0.2 μm, the average particle size ratio of said coarse-grain polymer to said fine-grain polymer being at least 2:1, and wherein the coarse-grain polymer and the fine-grain polymer are copolymers consisting essentially of styrene and/or esters of acrylic acid or esters of methacrylic acid and, optionally, unsaturated acids or amides of unsaturated acids in an amount of below 10 weight percent (relative to the total monomers) and, optionally, monomers capable of being cross-linked in an amount of up to 5 weight percent (relative to the total of monomers).
Claim 2
Dependent Claim 145 words
A protective colloid free plastics aqueous dispersion having a bimodal particle size distribution, wherein the plastics portion consists of from 60 to 80 weight % of a coarse-grain polymer having an average particle size of more than 0.25 μm and from 40 to 20 weight % of a fine-grain polymer having an average particle size of below 0.2 μm, the average particle size ratio of said coarse-grain polymer to said fine-grain polymer being at least 2:1, and wherein the coarse-grain polymer and the fine-grain polymer are copolymers consisting essentially of styrene and/or esters of acrylic acid or esters of methacrylic acid and, optionally, unsaturated acids or amides of unsaturated acids in an amount of below 10 weight percent (relative to the total monomers) and, optionally, monomers capable of being cross-linked in an amount of up to 5 weight percent (relative to the total of monomers).
Claim 3
Dependent Claim 15 words
Plastics bound plaster or gloss paint containing as binder the plastics dispersion of claim 1.
Claim 4
Dependent Claim 9 words
Unpigmented coating containing the plastics dispersion of claim 1.

References Cited (Backward Citations)

US3728418A Cited
US3992486A Cited
US3947528A Cited
US3784501A Cited
US3935151A Cited
US4009226A Cited
US4284433A Cited
US4247438A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1986-07-25 1987-01-24 1987-07-26 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1990-07-25 1991-01-24 1991-07-26 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1994-07-25 1995-01-24 1995-07-26 $7700.00 Window Closed / Lapsed

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