US3935151A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Blended latex binder for exterior paints with wet primed adhesion
Assignee: Goodrich Corp
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Filing: 1974-08-05
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Granted: 1976-01-27
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Expires: 1994-08-05
Abstract
Abstract A water-based paint confers wet primed adhesion if its binder is a latex whose polymer is a vinyl chloride/acrylic or an all-acrylic containing polymerized therein (based on weight of main monomers) not only 0.3-5% of (meth) acrylic acid but also a fraction of hydroxymethyl diacetone acrylamide (HMDAA) which must be at least 1 % in case of vinyl chloride/acrylics and at least 2% in case of all-acrylics. But, surprisingly, when such a latex is diluted by blending with a vinyl acetate/acrylic latex which by itself does not confer wet primed adhesion, superior wet primed adhesion is obtainable even when the overall level of HMDAA is only 0.65% when the HMDAA latex is an all-acrylic and only 0.40% when the HMDAA latex is a vinyl chloride/acrylic.
Inventors
- 👤 Richard Gorham Nickerson
- 👤 Robert Thomas Bouchard
- 👤 Paul Joseph Charles Hurtubise
- 👤 Eugene Alfred Duchesneau, Jr.
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-26 00:31
CPC Classifications
C; C09; C09D; C09D127/00; C09D127/02; C09D127/04; C09D127/06; C09D131/00; C09D131/02; C09D131/04; C08; C08L; C08L27/00; C08L27/02; C08L27/04; C08L27/06; C08L35/00; C08L35/02; Y; Y10; Y10T; Y10T428/00; Y10T428/31504; Y10T428/31786; Y10T428/31797
Claims Analysis
Total Claims: 7
Claim 1
Independent Claim
418 words
A latex blend capable of conferring wet primed adhesion to paints comprising I. up to about 85% of the total solids of an emulsion copolymer containing polymerized therein a. at least about 50 parts by weight of a monomer selected from the group consisting of vinyl acetate and vinyl chloride. b. sufficient monomer selected from the group consisting of C 1 -C 10 alkyl esters of acrylic and methacrylic acids, and the C 1 -C 10 alkyl diesters of maleic acid and fumaric acid to make 100 parts by weight of (a) and (b) monomers, and c. about 0.3-5% based on the total of said (a) and (b) monomers of a carboxylated monomer selected from the group consisting of acrylic acid, methacrylic acid, itaconic acid, aconitic acid, methacrylic acid dimer, crotonic acid, isocrotonic acid, angelic acid, teglic acid, senecioic acid, hexenic acid and the C 1 -C 10 alkyl monoesters of maleic acid and fumaric acid; and Ii. to make 100% of the total solids, at least about 15% of an emulsion copolymer chosen from the group consisting of A. an emulsion copolymer containing copolymerized therein d. about 50-70 parts of vinyl chloride, e. about 30-50 parts of monomers selected from the group consisting of C 1 14 C 10 alkyl diesters of maleic acid and fumaric acid to make 100 parts by weight of (d) and (e) monomers, f. about 0.3-5%, based on said (d) and (e) monomers, of a carboxylated monomer selected from the group consisting of acrylic acid, methacrylic acid, itaconic acid, aconitic acid, methacrylic acid dimer, crotonic acid, isocrotonic acid, angelic acid, teglic acid, senecioic acid, hexenic acid and the C 1 -C 10 alkyl monoesters of maleic acid and fumaric acid, and g. sufficient hydroxymethyl diacetone acrylamide (HMDAA) to achieve an HMDAA level of at least about 0.40% with respect to total monomers in the entire latex blend; and B. an emulsion copolymer containing copolymerized therein h. monomers selected from the group of monomers consisting of C 1 -C 10 alkyl diesters of maleic acid and fumaric acid, j. about 0.3-5% based on (h) monomers of a carboxylated monomer selected from the group consisting of acrylic acid, methacrylic acid, itaconic acid, itaconic acid, aconitic acid, methacrylic acid dimer, crotonic acid, hexenic acid and the C 1 -C 10 alkyl monoesters of maleic acid and fumaric acid, and k, sufficient hydroxymethyl diacetone acrylamide (HMDAA) to achieve an HMDAA level of at least about 0.65% with respect to total monomers in the entire latex blend.
Claim 2
Dependent Claim
418 words
A latex blend capable of conferring wet primed adhesion to paints comprising I. up to about 85% of the total solids of an emulsion copolymer containing polymerized therein a. at least about 50 parts by weight of a monomer selected from the group consisting of vinyl acetate and vinyl chloride. b. sufficient monomer selected from the group consisting of C 1 -C 10 alkyl esters of acrylic and methacrylic acids, and the C 1 -C 10 alkyl diesters of maleic acid and fumaric acid to make 100 parts by weight of (a) and (b) monomers, and c. about 0.3-5% based on the total of said (a) and (b) monomers of a carboxylated monomer selected from the group consisting of acrylic acid, methacrylic acid, itaconic acid, aconitic acid, methacrylic acid dimer, crotonic acid, isocrotonic acid, angelic acid, teglic acid, senecioic acid, hexenic acid and the C 1 -C 10 alkyl monoesters of maleic acid and fumaric acid; and Ii. to make 100% of the total solids, at least about 15% of an emulsion copolymer chosen from the group consisting of A. an emulsion copolymer containing copolymerized therein d. about 50-70 parts of vinyl chloride, e. about 30-50 parts of monomers selected from the group consisting of C 1 14 C 10 alkyl diesters of maleic acid and fumaric acid to make 100 parts by weight of (d) and (e) monomers, f. about 0.3-5%, based on said (d) and (e) monomers, of a carboxylated monomer selected from the group consisting of acrylic acid, methacrylic acid, itaconic acid, aconitic acid, methacrylic acid dimer, crotonic acid, isocrotonic acid, angelic acid, teglic acid, senecioic acid, hexenic acid and the C 1 -C 10 alkyl monoesters of maleic acid and fumaric acid, and g. sufficient hydroxymethyl diacetone acrylamide (HMDAA) to achieve an HMDAA level of at least about 0.40% with respect to total monomers in the entire latex blend; and B. an emulsion copolymer containing copolymerized therein h. monomers selected from the group of monomers consisting of C 1 -C 10 alkyl diesters of maleic acid and fumaric acid, j. about 0.3-5% based on (h) monomers of a carboxylated monomer selected from the group consisting of acrylic acid, methacrylic acid, itaconic acid, itaconic acid, aconitic acid, methacrylic acid dimer, crotonic acid, hexenic acid and the C 1 -C 10 alkyl monoesters of maleic acid and fumaric acid, and k, sufficient hydroxymethyl diacetone acrylamide (HMDAA) to achieve an HMDAA level of at least about 0.65% with respect to total monomers in the entire latex blend.
Claim 3
Dependent Claim
34 words
The latex blend of claim 1 wherein the emulsion copolymer of (I) contains polymerized therein about 50-70 parts of vinyl chloride and wherein the emulsion copolymer of (II) is the emulsion copolymer of (A).
Claim 4
Dependent Claim
33 words
The latex blend of claim 1 wherein the emulsion copolymer of (I) contains polymerized therein about 50-70 parts of vinyl chloride and the emulsion copolymer of (II) is the emulsion copolymer of (B).
Claim 5
Dependent Claim
33 words
The latex blend of claim 1 wherein the emulsion copolymmer of (I) contains polymerized therein about 50-98 parts of vinyl acetate and the emulsion copolymer of (II) is the emulsion copolymer of (A).
Claim 6
Dependent Claim
33 words
The latex blend of claim 1 wherein the emulsion copolymer of (I) contains polymerized therein about 50-98 parts of vinyl acetate and the emulsion copolymer of (II) is the emulsion copolymer of (B).
Claim 7
Dependent Claim
14 words
A latex paint comprising a pigmentary material and the latex blend of claim 1.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1979-01-26 | 1979-07-28 | 1980-01-27 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1983-01-26 | 1983-07-28 | 1984-01-27 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1987-01-26 | 1987-07-28 | 1988-01-27 | $7700.00 | Window Closed / Lapsed |