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US4473618A
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Chrome-free sizing composition containing titanium acetyl acetonate for glass fiber gun roving
Assignee: Owens Corning Fiberglas Technology Inc
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Filing: 1983-05-13
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Granted: 1984-09-25
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Expires: 2003-05-13
Abstract
Abstract Chrome-free aqueous sizing composition for glass fiber gun roving contains a mixture of emulsified film-forming polymers, titanium acetyl acetonate, silylated polyazamide, cationic lubricant and methacryloxypropylsilane.
Inventors
- 👤 Leonard J. Adzima
- 👤 Jeffrey L. Antle
- 👤 David E. Musick
- 👤 Fred G. Krautz
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-31 07:42
CPC Classifications
C; C03; C03C; C03C25/00; C03C25/10; C03C25/24; C03C25/26; Y; Y10; Y10T; Y10T428/00; Y10T428/29; Y10T428/2913; Y10T428/2933; Y10T428/2938; Y10T428/294; Y10T428/2956; Y10T428/2958; Y10T428/2962; Y10T428/2964; Y10T428/2967
Claims Analysis
Total Claims: 15
Claim 1
Independent Claim
65 words
A substantially chrome-free aqueous sizing composition for glass fiber gun roving which comprises (A) a mixture of emulsified film-forming polymers comprising a polymer of vinyl acetate and ethylene, a polymer of vinyl acetate and an epoxy-functional vinyl monomer, and an unsaturated polyester resin; (B) titanium acetyl acetonate; (C) a silylated polyamino-polyamide hydrochloride or hydrolysate thereof; (D) a cationic lubricant; and (E) 3-methacryloxypropyltrimethoxysilane or hydrolysate thereof.
Claim 2
Dependent Claim
65 words
A substantially chrome-free aqueous sizing composition for glass fiber gun roving which comprises (A) a mixture of emulsified film-forming polymers comprising a polymer of vinyl acetate and ethylene, a polymer of vinyl acetate and an epoxy-functional vinyl monomer, and an unsaturated polyester resin; (B) titanium acetyl acetonate; (C) a silylated polyamino-polyamide hydrochloride or hydrolysate thereof; (D) a cationic lubricant; and (E) 3-methacryloxypropyltrimethoxysilane or hydrolysate thereof.
Claim 3
Dependent Claim
90 words
An aqueous composition according to claim 1 wherein the proportions by weight of the components relative to the total weight of the aqueous composition, are about: (A) 1 to 5% of said emulsified polymer of vinylacetate and ethylene, 1 to 5% of said emulsified epoxy-functional vinyl monomer, and 0.5 to 1.5% of said emulsified polyester resin; (B) 0.5 to 1.5% of said titanium acetyl acetonate; (C) 0.01 to 0.2% of said silylated polyamide hydrochloride; (D) 0.005 to 0.1% of said cationic lubricant; and (E) 0.005 to 0.1% of said silane.
Claim 4
Dependent Claim
52 words
An aqueous composition according to claim 2 wherein said epoxy-functional vinyl monomer is glycidyl acrylate or methacrylate, said unsaturated polyester resin comprises a minor proportion by weight at an unsaturated plasticizer latently reactive therewith, and said cationic lubricant is a weak acid salt of a partial fatty acid amide of a polyamine.
Claim 5
Dependent Claim
18 words
A glass fiber coated with the in situ dried residue of an aqueous composition according to claim 1.
Claim 6
Dependent Claim
18 words
A glass fiber coated with the in situ dried residue of an aqueous composition according to claim 2.
Claim 7
Dependent Claim
18 words
A glass fiber coated with the in situ dried residue of an aqueous composition according to claim 3.
Claim 8
Dependent Claim
24 words
A coated glass fiber according to claim 4 wherein the coating comprises about 0.5 to about 2 percent of the weight of the glass.
Claim 9
Dependent Claim
23 words
A glass fiber according to claim 5 wherein the coating comprises about 0.5 to about 2 percent of the weight of the fiber.
Claim 10
Dependent Claim
23 words
A glass fiber according to claim 6 wherein the coating comprises about 0.5 to about 2 percent of the weight of the fiber.
Claim 11
Dependent Claim
16 words
A glass fiber gun roving comprising a plurality of coated glass fibers according to claim 4.
Claim 12
Dependent Claim
16 words
A glass fiber gun roving comprising a plurality of coated glass fibers according to claim 5.
Claim 13
Dependent Claim
16 words
A glass fiber gun roving comprising a plurality of coated glass fibers according to claim 6.
Claim 14
Dependent Claim
21 words
A glass fiber gun roving according to claim 12 wherein the fibers are about 10 to about 13 μm in diameter.
Claim 15
Dependent Claim
44 words
A glass fiber roving according to claim 13 comprising about 30 to about 70 strands weakly integrated with each other, each strand comprising about 100 to about 300 of said coated glass fibers tightly integrated into said strand by the coating on said fibers.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1987-09-25 | 1988-03-26 | 1988-09-25 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1991-09-25 | 1992-03-26 | 1992-09-25 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1995-09-25 | 1996-03-26 | 1996-09-25 | $7700.00 | Window Closed / Lapsed |