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US4126729A Expired / Lapsed US ⏱️ 0.0 years remaining

Glass fibers sized with vinyl acetate copolymers

Assignee: Owens Corning
•
Filing: 1977-05-05
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Granted: 1978-11-21
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Expires: 1997-05-05
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Abstract

Abstract Disclosed are gun roving glass fibers coated with an aqueous-based size comprising an epoxidized polyvinyl acetate copolymer in combination with a vinyl acetate-ethylene copolymer and a vinyl acetate copolymer.

Inventors

  • 👤 Tom A. Richardson
  • 👤 William N. Haggerty
  • 👤 Fred G. Krautz

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-30 22:34
CPC Classifications
C; C03; C03C; C03C25/00; C03C25/10; C03C25/24; C03C25/26; C03C25/28; Y; Y10; Y10T; Y10T428/00; Y10T428/29; Y10T428/2913; Y10T428/2933; Y10T428/2938; Y10T428/294; Y10T428/2958; Y10T428/2962

Claims Analysis

Total Claims: 15
Claim 1
Independent Claim 33 words
Glass fibers coated with an effective amount of a substance derived from an aqueous composition comprising an epoxidized polyvinyl acetate copolymer, an ethylene vinyl acetate copolymer, and a vinyl acetate ethyl acrylate copolymer.
Claim 2
Dependent Claim 33 words
Glass fibers coated with an effective amount of a substance derived from an aqueous composition comprising an epoxidized polyvinyl acetate copolymer, an ethylene vinyl acetate copolymer, and a vinyl acetate ethyl acrylate copolymer.
Claim 3
Dependent Claim 34 words
The glass fibers of claim 1 in which said epoxidized polyvinyl acetate copolymer is present in said aqueous composition in an amount within the range of from about 1.5 to about 3 weight percent.
Claim 4
Dependent Claim 30 words
The glass fibers of claim 1 in which said ethylene vinyl acetate copolymer is present in an amount within the range of from about 1.8 to about 3.6 weight percent.
Claim 5
Dependent Claim 31 words
The glass fibers of claim 1 in which said vinyl acetate ethyl acrylate copolymer is present in an amount within the range of from about 3.7 to about 7.4 weight percent.
Claim 6
Dependent Claim 24 words
The glass fibers of claim 1 in which said aqueous composition comprises a silane coupling agent, a methacrylate chromic chloride and a polyethyleneimine condensate.
Claim 7
Dependent Claim 26 words
The glass fibers of claim 1 in which said aqueous composition comprises a silane coupling agent, a methacrylate chromic chloride, a polyethyleneimine condensate and a lubricant.
Claim 8
Dependent Claim 42 words
Glass fibers coated with the dried residue of an aqueous mixture consisting essentially of an epoxidized polyvinyl acetate copolymer, an ethylene vinyl acetate copolymer, a vinyl acetate ethyl acrylate copolymer, a silane coupling agent, a methacrylate chromic chloride and a polyethyleneimine condensate.
Claim 9
Dependent Claim 42 words
Glass fibers coated with the dried residue of an aqueous mixture consisting essentially of an epoxidized polyvinyl acetate copolymer, an ethylene vinyl acetate copolymer, a vinyl acetate ethyl acrylate copolymer, a silane coupling agent, a methacrylate chromic chloride and a polyethyleneimine condensate.
Claim 10
Dependent Claim 43 words
Glass fibers coated with the dried residue of an aqueous mixture consisting essentially of an epoxidized polyvinyl acetate copolymer, an ethylene vinyl acetate copolymer, a vinyl acetate ethyl acrylate copolymer, a silane glass coupling agent, a Werner-type chromium complex and a polyethyleneimine condensate.
Claim 11
Dependent Claim 43 words
Glass fibers coated with the dried residue of an aqueous mixture consisting essentially of an epoxidized polyvinyl acetate copolymer, an ethylene vinyl acetate copolymer, a vinyl acetate ethyl acrylate copolymer, a silane glass coupling agent, a Werner-type chromium complex and a polyethyleneimine condensate.
Claim 12
Dependent Claim 93 words
Glass fibers coated with the dried residue of an aqueous mixture consisting essentially of from about 1.5 to about 3% of an epoxidized polyvinyl acetate copolymer; from about 1.8 to about 3.6% of an ethylene vinyl acetate copolymer; from about 3.7 to about 7.4% of a vinyl acetate ethyl acrylate copolymer; from about 0.05 to about 0.50% of a silane glass coupling agent; from about 0.5 to about 5.0% of a Werner-type chromium complex; and from about 0.03 to about 0.10% of a polyethyleneimine; said percentages being by weight of the aqueous mixture.
Claim 13
Dependent Claim 93 words
Glass fibers coated with the dried residue of an aqueous mixture consisting essentially of from about 1.5 to about 3% of an epoxidized polyvinyl acetate copolymer; from about 1.8 to about 3.6% of an ethylene vinyl acetate copolymer; from about 3.7 to about 7.4% of a vinyl acetate ethyl acrylate copolymer; from about 0.05 to about 0.50% of a silane glass coupling agent; from about 0.5 to about 5.0% of a Werner-type chromium complex; and from about 0.03 to about 0.10% of a polyethyleneimine; said percentages being by weight of the aqueous mixture.
Claim 14
Dependent Claim 25 words
The glass fibers of claim 9 wherein the epoxidized polyvinyl acetate copolymer is a copolymer of vinyl acetate and a minor amount of glycidyl methacrylate.
Claim 15
Dependent Claim 16 words
The glass fibers of claim 9 wherein the glycidyl methacrylate comprises approximately 2% of the copolymer.

References Cited (Backward Citations)

US2931739A Cited
US3418094A Cited
US3534004A Cited
US3655353A Cited
US3827230A Cited
US3935344A Cited
US3705125A Cited
US3772870A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1981-11-20 1982-05-22 1982-11-21 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1985-11-20 1986-05-22 1986-11-21 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1989-11-20 1990-05-22 1990-11-21 $7700.00 Window Closed / Lapsed

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