US4244844A
Expired / Lapsed
US
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Aqueous size for glass fibers
Assignee: Saint Gobain Industries SA
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Filing: 1978-01-18
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Granted: 1981-01-13
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Expires: 1998-01-18
Abstract
Abstract Aqueous compositions for the coating of glass fibers used particularly for textiles, a method of applying these compositions to the fibers, and the fibers themselves are disclosed. The aqueous compositions comprise at least one starch, a non-ionic lubricant, a cationic lubricant, emulsifier and at least one organo-silane from the group made up of the organo-silanes comprising an organic chain of the polyazamide type and of the organo-silanes whose organic chain contains at least one phenyl radical and at least one secondary or tertiary amine group.
Inventors
- 👤 Jacques Molinier
- 👤 Jacques Mahler
- 👤 Gilbert Bocquet
- 👤 Bernard de Massey
- 👤 Robert Holtmann
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-31 09:00
CPC Classifications
C; C03; C03C; C03C25/00; C03C25/10; C03C25/24; C03C25/26; C03C25/40; C08; C08J; C08J5/00; C08J5/04; C08J5/06; C08J5/08; Y; Y10; Y10T; Y10T428/00; Y10T428/29; Y10T428/2913; Y10T428/2933; Y10T428/2962
Claims Analysis
Total Claims: 12
Claim 1
Independent Claim
141 words
Aqueous composition for the coating of glass fibers, characterized in that it comprises: 0.5 to 15% in weight of at least one starch, 0.05 to 5% of non-ionic lubricant, 0.03 to 2% of cationic lubricant, 0.02 to 1% of emulsifier, 0.1 to 2% of at least one organo silane selected from the group consisting of ##STR11## in which: x/y is 0.5 to 15; n is 2 to 6, R is a methoxy, ethoxy, propoxy, n-butoxy or β-methoxyethoxy radical, R 1 and R 3 are alkylene divalent radicals containing 1 to 3 carbon atoms, and R 2 represents a substituted or non-substituted cycloaliphatic or aromatic, aliphatic divalent radical; or ##STR12## in which: n is 2 to 6, preferably n=2 or 3 m is 1 to 10, preferably m is 1 to 4 R is a methoxy, ethoxy, propoxy, n-butoxy or β-methoxyethoxy radical.
Claim 2
Dependent Claim
141 words
Aqueous composition for the coating of glass fibers, characterized in that it comprises: 0.5 to 15% in weight of at least one starch, 0.05 to 5% of non-ionic lubricant, 0.03 to 2% of cationic lubricant, 0.02 to 1% of emulsifier, 0.1 to 2% of at least one organo silane selected from the group consisting of ##STR11## in which: x/y is 0.5 to 15; n is 2 to 6, R is a methoxy, ethoxy, propoxy, n-butoxy or β-methoxyethoxy radical, R 1 and R 3 are alkylene divalent radicals containing 1 to 3 carbon atoms, and R 2 represents a substituted or non-substituted cycloaliphatic or aromatic, aliphatic divalent radical; or ##STR12## in which: n is 2 to 6, preferably n=2 or 3 m is 1 to 10, preferably m is 1 to 4 R is a methoxy, ethoxy, propoxy, n-butoxy or β-methoxyethoxy radical.
Claim 3
Dependent Claim
32 words
Aqueous sizing for the coating of glass fibers according to claim 1, characterized in that it contains up to 7% of supplementary film forming materials and/or up to 1% of another organo-silane.
Claim 4
Dependent Claim
11 words
Aqueous sizing according to claim 1, characterized in that it comprises:
Claim 5
Dependent Claim
43 words
5 to 10% in weight of modified starch, 0.1 to 5% of acrylic polymer, 1 to 5% of emulsified, non-ionic lubricant(s), 0.2 to 2% of polyethylene wax, 0.03 to 0.6% of a cationic emulsifier for polyethylene wax, 0.1 to 2% of the organo-silane.
Claim 6
Dependent Claim
43 words
5 to 10% in weight of modified starch, 0.1 to 5% of acrylic polymer, 1 to 5% of emulsified, non-ionic lubricant(s), 0.2 to 2% of polyethylene wax, 0.03 to 0.6% of a cationic emulsifier for polyethylene wax, 0.1 to 2% of the organo-silane.
Claim 7
Dependent Claim
23 words
Aqueous sizing according to claim 1, characterized in that the at least one organo-silane is selected from the general formulas II and IV.
Claim 8
Dependent Claim
38 words
Aqueous sizing for coating glass fibers according to claim 1, characterized in that it contains at least one of the organo-silanes of the following formulas: ##STR13## in which n equals 2 or 3, m is 1 to 4.
Claim 9
Dependent Claim
89 words
Aqueous composition for the coating of glass fibers according to claim 1, characterized in that it contains at least one organo-silane of the general formulas: ##STR14## in which n is 2 to 6, m is 1 to 10, R is a methoxy, ethoxy, propoxy, n-butoxy or β-methoxyethoxy radical, ##STR15## in which: m is 1 to 10, R is a methoxy, ethoxy, propoxy, n-butoxy or β-methoxyethoxy radical, ##STR16## in which: n is 2 to 6, m is 1 to 10, R is a methoxy, ethoxy, propoxy, n-butoxy or β-methoxyethoxy radical.
Claim 10
Dependent Claim
38 words
Aqueous sizing according to claim 1, characterized in that it comprises: 0.5 to 10% in weight of modified starch, 0.1 to 5% of acrylic polymer, 1 to 5% of emulsified, non-ionic lubricants(s), 0.2 to 2% of polyethylene wax,
Claim 11
Dependent Claim
26 words
03 to 0.6% of a cationic emulsifier for polyethylene wax, 0.1 to 2% of at least one organo-silane of the general formulas (II), (III), and (IV).
Claim 12
Dependent Claim
26 words
03 to 0.6% of a cationic emulsifier for polyethylene wax, 0.1 to 2% of at least one organo-silane of the general formulas (II), (III), and (IV).
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1984-01-13 | 1984-07-14 | 1985-01-13 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1988-01-13 | 1988-07-14 | 1989-01-13 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1992-01-13 | 1992-07-14 | 1993-01-13 | $7700.00 | Window Closed / Lapsed |