Patent US3432308A successfully refreshed from Google Patents.
Patent US4465500A successfully refreshed from Google Patents.
← Back to Patent Explorer
US4465500A Expired / Lapsed US ⏱️ 0.0 years remaining

Method for sizing glass fibers

Assignee: PPG Industries Inc
•
Filing: 1982-09-23
•
Granted: 1984-08-14
•
Expires: 2002-09-23
📄 Original PDF 🌐 Google Patents 🔄 Sync Now

Abstract

Abstract An aqueous sizing composition with a cationic lubricant, amide compound, and water soluble or dispersible polyol which is used to produce wet chopped sized glass fiber strands. The sized wet or dried chopped glass fiber strands can be used to produce non-woven glass fiber strand mat, having good tensile strength, and good flexibility and reduced tendency for static generation. The wet chopped glass fiber strands also have good flowability in bulk handling apparatus.

Inventors

  • 👤 Donald L. Motsinger
  • 👤 Daniel G. Brown

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-09 06:23
CPC Classifications
D; D21; D21H; D21H13/00; D21H13/36; D21H13/38; D21H13/40; C; C03; C03C; C03C25/00; C03C25/10; C03C25/24; C03C25/26

Claims Analysis

Total Claims: 13
Claim 1
Independent Claim 194 words
Method of producing flowable wet chopped glass fiber strands comprising: attenuating glass fibers from molten cones of glass from a bushing, applying an aqueous sizing composition to the glass fibers, where the composition has one or more cationic lubricants, one or more water soluble or dispersible nonpolymeric amide compounds selected from the group consisting of urea (carbamide), methyl urea; 1,3-diethyl urea; 1,3-diaminourea (carbohydrazide); methylurea; acetyleneurea; acetylenediurea; melamine; acetamide; propionic amide up to caproamide; and diamides of saturated dicarboxylic acids and sebacamide, and semicarbazide, carbohydrazide, cabamidourea, allophanamide (biuret) and 1-carbomoylsemicarbamide (biurea) in an effective amount to provide moisture control of the wet chopped glass fibers in the range of about 9 to about 20 weight percent of the chopped glass fibers, and one or more water soluble or dispersible polyols that comprises a predominant amount of the nonaqueous components of the sizing composition, and water in a major amount of the aqueous sizing composition, gathering the glass fibers into one or more strands, chopping the glass fiber strands to produce wet chopped glass fiber strands having a moisture content in the range of at least 9 to about 20 weight percent of the chopped strand.
Claim 2
Dependent Claim 194 words
Method of producing flowable wet chopped glass fiber strands comprising: attenuating glass fibers from molten cones of glass from a bushing, applying an aqueous sizing composition to the glass fibers, where the composition has one or more cationic lubricants, one or more water soluble or dispersible nonpolymeric amide compounds selected from the group consisting of urea (carbamide), methyl urea; 1,3-diethyl urea; 1,3-diaminourea (carbohydrazide); methylurea; acetyleneurea; acetylenediurea; melamine; acetamide; propionic amide up to caproamide; and diamides of saturated dicarboxylic acids and sebacamide, and semicarbazide, carbohydrazide, cabamidourea, allophanamide (biuret) and 1-carbomoylsemicarbamide (biurea) in an effective amount to provide moisture control of the wet chopped glass fibers in the range of about 9 to about 20 weight percent of the chopped glass fibers, and one or more water soluble or dispersible polyols that comprises a predominant amount of the nonaqueous components of the sizing composition, and water in a major amount of the aqueous sizing composition, gathering the glass fibers into one or more strands, chopping the glass fiber strands to produce wet chopped glass fiber strands having a moisture content in the range of at least 9 to about 20 weight percent of the chopped strand.
Claim 3
Dependent Claim 10 words
Method of claim 1, wherein the polyol is diethylene glycol.
Claim 4
Dependent Claim 29 words
Method of claim 1, wherein the cationic lubricant is present in an amount in the range of about 0.05 to about 0.5 weight percent of the aqueous treating composition.
Claim 5
Dependent Claim 31 words
Method of claim 1, wherein the cationic lubricant is present in an amount in the range of about 4 to about 20 weight percent of the solids of the treating composition.
Claim 6
Dependent Claim 28 words
Method of claim 1, wherein the polyol is present in the aqueous treating composition in an amount in the range of about 0.5 to about 3 weight percent.
Claim 7
Dependent Claim 20 words
Method of claim 1, wherein the cationic lubricant is an alkyl imidazoline reaction product of tetraethylene pentamine and stearic acid.
Claim 8
Dependent Claim 13 words
Method of claim 1, wherein the water soluble or dispersible amide is urea.
Claim 9
Dependent Claim 73 words
Method of claim 1, wherein the polyol is selected from di or polyfunctional hydroxy compounds or polymeric compounds including alkylene glycols having up to 6 carbon atoms, neopentyl glycol, hexylene glycol, pentaerythritol, dispentaerythritol, trimethyol propane, sorbitol, glycerine, and polyalkylene glycols having the formula HO(CH 2 CH 2 O) n H or HO(CH 2 CH 2 CH 2 O) n H, where n is a positive integer of at least 2 to about 25.
Claim 10
Dependent Claim 31 words
Method of claim 1, wherein the amide compound is present in an amount in the range of about 3 to about 40 weight percent of the solids of the treating composition.
Claim 11
Dependent Claim 14 words
Method of claim 1, wherein the aqueous treating composition has a silane coupling agent.
Claim 12
Dependent Claim 20 words
Method of claim 1, wherein the aqueous treating composition has a film forming polymer selected from starch or polyvinyl acetate.
Claim 13
Dependent Claim 33 words
Method of claim 1, wherein the amide compound is present in an effective amount to control the moisture of the chopped strands in the range of about 10 to about 15 weight percent.

References Cited (Backward Citations)

US3850869A Cited
US4002445A Cited
US4009132A Cited
US4067835A Cited
JPS5337957A Cited
US4169062A Cited
US4170673A Cited
US4265704A Cited
US4361465A Cited
US4370169A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1987-08-14 1988-02-13 1988-08-14 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1991-08-14 1992-02-13 1992-08-14 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1995-08-14 1996-02-13 1996-08-14 $7700.00 Window Closed / Lapsed

Assigned Categories & Tags

No categories assigned to this patent yet.

Assign Category Tag