US4465500A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Method for sizing glass fibers
Assignee: PPG Industries Inc
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Filing: 1982-09-23
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Granted: 1984-08-14
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Expires: 2002-09-23
Abstract
Abstract An aqueous sizing composition with a cationic lubricant, amide compound, and water soluble or dispersible polyol which is used to produce wet chopped sized glass fiber strands. The sized wet or dried chopped glass fiber strands can be used to produce non-woven glass fiber strand mat, having good tensile strength, and good flexibility and reduced tendency for static generation. The wet chopped glass fiber strands also have good flowability in bulk handling apparatus.
Inventors
- 👤 Donald L. Motsinger
- 👤 Daniel G. Brown
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-09 06:09
CPC Classifications
D; D21; D21H; D21H13/00; D21H13/36; D21H13/38; D21H13/40; C; C03; C03C; C03C25/00; C03C25/10; C03C25/24; C03C25/26
Claims Analysis
Total Claims: 13
Claim 1
Independent Claim
194 words
Method of producing flowable wet chopped glass fiber strands comprising: attenuating glass fibers from molten cones of glass from a bushing, applying an aqueous sizing composition to the glass fibers, where the composition has one or more cationic lubricants, one or more water soluble or dispersible nonpolymeric amide compounds selected from the group consisting of urea (carbamide), methyl urea; 1,3-diethyl urea; 1,3-diaminourea (carbohydrazide); methylurea; acetyleneurea; acetylenediurea; melamine; acetamide; propionic amide up to caproamide; and diamides of saturated dicarboxylic acids and sebacamide, and semicarbazide, carbohydrazide, cabamidourea, allophanamide (biuret) and 1-carbomoylsemicarbamide (biurea) in an effective amount to provide moisture control of the wet chopped glass fibers in the range of about 9 to about 20 weight percent of the chopped glass fibers, and one or more water soluble or dispersible polyols that comprises a predominant amount of the nonaqueous components of the sizing composition, and water in a major amount of the aqueous sizing composition, gathering the glass fibers into one or more strands, chopping the glass fiber strands to produce wet chopped glass fiber strands having a moisture content in the range of at least 9 to about 20 weight percent of the chopped strand.
Claim 2
Dependent Claim
194 words
Method of producing flowable wet chopped glass fiber strands comprising: attenuating glass fibers from molten cones of glass from a bushing, applying an aqueous sizing composition to the glass fibers, where the composition has one or more cationic lubricants, one or more water soluble or dispersible nonpolymeric amide compounds selected from the group consisting of urea (carbamide), methyl urea; 1,3-diethyl urea; 1,3-diaminourea (carbohydrazide); methylurea; acetyleneurea; acetylenediurea; melamine; acetamide; propionic amide up to caproamide; and diamides of saturated dicarboxylic acids and sebacamide, and semicarbazide, carbohydrazide, cabamidourea, allophanamide (biuret) and 1-carbomoylsemicarbamide (biurea) in an effective amount to provide moisture control of the wet chopped glass fibers in the range of about 9 to about 20 weight percent of the chopped glass fibers, and one or more water soluble or dispersible polyols that comprises a predominant amount of the nonaqueous components of the sizing composition, and water in a major amount of the aqueous sizing composition, gathering the glass fibers into one or more strands, chopping the glass fiber strands to produce wet chopped glass fiber strands having a moisture content in the range of at least 9 to about 20 weight percent of the chopped strand.
Claim 3
Dependent Claim
10 words
Method of claim 1, wherein the polyol is diethylene glycol.
Claim 4
Dependent Claim
29 words
Method of claim 1, wherein the cationic lubricant is present in an amount in the range of about 0.05 to about 0.5 weight percent of the aqueous treating composition.
Claim 5
Dependent Claim
31 words
Method of claim 1, wherein the cationic lubricant is present in an amount in the range of about 4 to about 20 weight percent of the solids of the treating composition.
Claim 6
Dependent Claim
28 words
Method of claim 1, wherein the polyol is present in the aqueous treating composition in an amount in the range of about 0.5 to about 3 weight percent.
Claim 7
Dependent Claim
20 words
Method of claim 1, wherein the cationic lubricant is an alkyl imidazoline reaction product of tetraethylene pentamine and stearic acid.
Claim 8
Dependent Claim
13 words
Method of claim 1, wherein the water soluble or dispersible amide is urea.
Claim 9
Dependent Claim
73 words
Method of claim 1, wherein the polyol is selected from di or polyfunctional hydroxy compounds or polymeric compounds including alkylene glycols having up to 6 carbon atoms, neopentyl glycol, hexylene glycol, pentaerythritol, dispentaerythritol, trimethyol propane, sorbitol, glycerine, and polyalkylene glycols having the formula HO(CH 2 CH 2 O) n H or HO(CH 2 CH 2 CH 2 O) n H, where n is a positive integer of at least 2 to about 25.
Claim 10
Dependent Claim
31 words
Method of claim 1, wherein the amide compound is present in an amount in the range of about 3 to about 40 weight percent of the solids of the treating composition.
Claim 11
Dependent Claim
14 words
Method of claim 1, wherein the aqueous treating composition has a silane coupling agent.
Claim 12
Dependent Claim
20 words
Method of claim 1, wherein the aqueous treating composition has a film forming polymer selected from starch or polyvinyl acetate.
Claim 13
Dependent Claim
33 words
Method of claim 1, wherein the amide compound is present in an effective amount to control the moisture of the chopped strands in the range of about 10 to about 15 weight percent.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1987-08-14 | 1988-02-13 | 1988-08-14 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1991-08-14 | 1992-02-13 | 1992-08-14 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1995-08-14 | 1996-02-13 | 1996-08-14 | $7700.00 | Window Closed / Lapsed |