Abstract A process for separating a component from a feed blend comprising an aqueous solution of a mixture of different components, such as a blend of saccharides. In the process the blend is contacted with an adsorbent comprising a crystalline aluminosilicate and cation exchange resin mixture which selectively adsorbs a component from the feed blend. The adsorbed component is then recovered by contacting the adsorbent with a desorbent material such as water to effect the desorption of the adsorbed component from the adsorbent. There is an undesirable tendency for the silicon constituent of a crystalline aluminosilicate to dissolve in an aqueous system and for the volume of a cationic exchange resin to change with the ionic strength of an aqueous medium. The adsorbent of this invention is dispersed in a binder material comprising a water permeable organic polymer and the effect is a substantial reduction of the undesirable dissolution and volume changes. The adsorbent is manufactured by mixing together powder of the crystalline aluminosilicate, powder of the cationic exchange resin, powder of the organic polymer binder, and a liquid organic solvent, extruding the mixture into an extrudate and drying the extrudate.
A process for the separation of one sugar component from a feed stream comprising an aqueous solution of a blend of sugar components, which process comprises: (a) contacting said aqueous solution with an adsorbent comprising a mixture of a Type X or Type Y zeolite, from about 20.0 wt% to about 35.0 wt% of a alkali or alkaline earth exchange resin and from about 20.0 wt% to about 35.0 wt% of a water permeable organic polymer binder, wherein the weight ratio of said Type X or Type Y zeolite to said alkali or alkaline earth exchange resin is from about 1.0 to about 3.0, said mixture exhibiting an adsorptive selectivity toward one of said components, thereby selectively adsorbing said component from said blend; (b) separating the solution from said adsorbent; and (c) thereafter recovering said adsorbed component by desorption thereof from said adsorbent.
Claim 2
Dependent Claim
143 words
A process for the separation of one sugar component from a feed stream comprising an aqueous solution of a blend of sugar components, which process comprises: (a) contacting said aqueous solution with an adsorbent comprising a mixture of a Type X or Type Y zeolite, from about 20.0 wt% to about 35.0 wt% of a alkali or alkaline earth exchange resin and from about 20.0 wt% to about 35.0 wt% of a water permeable organic polymer binder, wherein the weight ratio of said Type X or Type Y zeolite to said alkali or alkaline earth exchange resin is from about 1.0 to about 3.0, said mixture exhibiting an adsorptive selectivity toward one of said components, thereby selectively adsorbing said component from said blend; (b) separating the solution from said adsorbent; and (c) thereafter recovering said adsorbed component by desorption thereof from said adsorbent.
Claim 3
Dependent Claim
21 words
The process of claim 1 further characterized in that said water permeable organic polymer comprises a cellulose ester or cellulose nitrate.
Claim 4
Dependent Claim
34 words
The process of claim 1 further characterized in that said cation exchange resin comprises an alkali metal or alkaline earth metal salt of a nuclearly sulfonated polystyrene cation exchange resin containing a cross-linking agent.
Claim 5
Dependent Claim
34 words
The process of claim 3 further characterized in that said cation exchange resin comprises a calcium salt and said cross-linking agent comprises divinylbenzene in an amount comprising about 4.0% by weight of said resin.
Claim 6
Dependent Claim
18 words
The process of claim 1 further characterized in that said feed mixture comprises an aqueous solution of saccharides.
Claim 7
Dependent Claim
18 words
The process of claim 5 further characterized in that said saccharides comprise a mixture of fructose and glucose.
Claim 8
Dependent Claim
21 words
The process of claim 5 further characterized in that recovery of said adsorbed component is effected with a desorbent comprising water.
Claim 9
Dependent Claim
22 words
The process of claim 5 further characterized in that the pH of said aqueous solution is from about 5.0 to about 8.0.