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US4363672A Expired / Lapsed US ⏱️ 0.0 years remaining

Separation process using cellulose acetate butyrate bound zeolite adsorbents

Assignee: Honeywell UOP LLC
•
Filing: 1981-04-09
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Granted: 1982-12-14
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Expires: 2001-04-09
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Abstract

Abstract An improved process for separating a component from a feed mixture comprising an aqueous solution of a mixture of different components, such as a mixture of saccharides. In the process the mixture is contacted with an adsorbent comprising a crystalline aluminosilicate, which selectively adsorbs a component from the feed mixture. The adsorbed component is then recovered by contacting the adsorbent with a desorbent material such as water to effect the desorption of the adsorbed component from the adsorbent. There is an undesirable tendency for the silicon constituent of the crystalline aluminosilicate to dissolve in the aqueous system. The improvement to the adsorbent and process comprises the incorporation of a binder material in the adsorbent comprising cellulose acetate butyrate which substantially reduces the undesirable dissolution. The adsorbent is manufactured by mixing together powder of the crystalline aluminosilicate, powders of the binder, and a liquid organic solvent, extruding the mixture into an extrudate and drying the extrudate.

Inventors

  • 👤 Santi Kulprathipanja

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-30 07:40
CPC Classifications
B; B01; B01J; B01J20/00; B01J20/02; B01J20/10; B01J20/16; B01J20/18; B01J20/183; C; C13; C13K; C13K13/00; C13K13/007

Claims Analysis

Total Claims: 9
Claim 1
Independent Claim 135 words
In a process for the separation of a component from a feed mixture comprising an aqueous solution of a mixture of components, by contacting said solution with an adsorbent comprising a crystalline aluminosilicate zeolite exhibiting an adsorptive selectivity towards said component, thereby selectively adsorbing said component from said mixture, separating the solution from contact with said adsorbent and thereafter recovering said adsorbed component by desorption thereof from said adsorbent, the silicon constituent of said adsorbent tending to dissolve in said solution resulting in the undesirable disintegration of said adsorbent, the improvement which comprises impregnation of said adsorbent, prior to said contacting with said aqueous solution, with a water permeable binder material comprising cellulose acetate butyrate to substantially reduce the extent of dissolution of said silicon constituent and the extent of said disintegration of said adsorbent.
Claim 2
Dependent Claim 135 words
In a process for the separation of a component from a feed mixture comprising an aqueous solution of a mixture of components, by contacting said solution with an adsorbent comprising a crystalline aluminosilicate zeolite exhibiting an adsorptive selectivity towards said component, thereby selectively adsorbing said component from said mixture, separating the solution from contact with said adsorbent and thereafter recovering said adsorbed component by desorption thereof from said adsorbent, the silicon constituent of said adsorbent tending to dissolve in said solution resulting in the undesirable disintegration of said adsorbent, the improvement which comprises impregnation of said adsorbent, prior to said contacting with said aqueous solution, with a water permeable binder material comprising cellulose acetate butyrate to substantially reduce the extent of dissolution of said silicon constituent and the extent of said disintegration of said adsorbent.
Claim 3
Dependent Claim 25 words
The process of claim 1 further characterized in that said crystalline aluminosilicate zeolite is selected from the group consisting of X zeolites and Y zeolites.
Claim 4
Dependent Claim 30 words
The process of claim 2 further characterized in that said aluminosilicate zeolite contains cations at exchangeable cationic sites selected from the group consisting of alkali metals and alkali earth metals.
Claim 5
Dependent Claim 18 words
The process of claim 2 further characterized in that said feed mixture comprises an aqueous solution of saccharides.
Claim 6
Dependent Claim 18 words
The process of claim 4 further characterized in that said saccharides comprise a mixture of fructose and glucose.
Claim 7
Dependent Claim 21 words
The process of claim 4 further characterized in that recovery of said adsorbed component is effected with a desorbent comprising water.
Claim 8
Dependent Claim 22 words
The process of claim 4 further characterized in that the pH of said aqueous solution is from about 5.0 to about 8.0.
Claim 9
Dependent Claim 28 words
The process of claim 1 further characterized in that the content of said cellulose acetate butyrate in said adsorbent is from about 2.0 wt.% to about 50.0 wt.%.

References Cited (Backward Citations)

US3951859A Cited
US4014711A Cited
US4248737A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1985-12-13 1986-06-14 1986-12-14 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1989-12-13 1990-06-14 1990-12-14 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1993-12-13 1994-06-14 1994-12-14 $7700.00 Window Closed / Lapsed

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