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US4421567A Expired / Lapsed US ⏱️ 0.0 years remaining

Separatory process using organic bound adsorbents

Assignee: Honeywell UOP LLC
•
Filing: 1982-04-05
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Granted: 1983-12-20
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Expires: 2002-04-05
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Abstract

Abstract A process for separating a component from a feed blend comprising an aqueous solution of a mixture of different components, such as a blend of saccharides. In the process the blend is contacted with an adsorbent comprising a crystalline aluminosilicate and cation exchange resin mixture which selectively adsorbs a component from the feed blend. The adsorbed component is then recovered by contacting the adsorbent with a desorbent material such as water to effect the desorption of the adsorbed component from the adsorbent. There is an undesirable tendency for the silicon constituent of a crystalline aluminosilicate to dissolve in an aqueous system and for the volume of a cationic exchange resin to change with the ionic strength of an aqueous medium. The adsorbent of this invention is dispersed in a binder material comprising a water permeable organic polymer and the effect is a substantial reduction of the undesirable dissolution and volume changes. The adsorbent is manufactured by mixing together powder of the crystalline aluminosilicate, powder of the cationic exchange resin, powder of the organic polymer binder, and a liquid organic solvent, extruding the mixture into an extrudate and drying the extrudate.

Inventors

  • 👤 Santi Kulprathipanja
  • 👤 Armand J. DERosset

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-30 05:14
CPC Classifications
B; B01; B01J; B01J20/00; B01J20/28; B01J20/28014; B01J20/2803; B01J20/28026; B01J47/00; B01J47/018

Claims Analysis

Total Claims: 9
Claim 1
Independent Claim 143 words
A process for the separation of one sugar component from a feed stream comprising an aqueous solution of a blend of sugar components, which process comprises: (a) contacting said aqueous solution with an adsorbent comprising a mixture of a Type X or Type Y zeolite, from about 20.0 wt% to about 35.0 wt% of a alkali or alkaline earth exchange resin and from about 20.0 wt% to about 35.0 wt% of a water permeable organic polymer binder, wherein the weight ratio of said Type X or Type Y zeolite to said alkali or alkaline earth exchange resin is from about 1.0 to about 3.0, said mixture exhibiting an adsorptive selectivity toward one of said components, thereby selectively adsorbing said component from said blend; (b) separating the solution from said adsorbent; and (c) thereafter recovering said adsorbed component by desorption thereof from said adsorbent.
Claim 2
Dependent Claim 143 words
A process for the separation of one sugar component from a feed stream comprising an aqueous solution of a blend of sugar components, which process comprises: (a) contacting said aqueous solution with an adsorbent comprising a mixture of a Type X or Type Y zeolite, from about 20.0 wt% to about 35.0 wt% of a alkali or alkaline earth exchange resin and from about 20.0 wt% to about 35.0 wt% of a water permeable organic polymer binder, wherein the weight ratio of said Type X or Type Y zeolite to said alkali or alkaline earth exchange resin is from about 1.0 to about 3.0, said mixture exhibiting an adsorptive selectivity toward one of said components, thereby selectively adsorbing said component from said blend; (b) separating the solution from said adsorbent; and (c) thereafter recovering said adsorbed component by desorption thereof from said adsorbent.
Claim 3
Dependent Claim 21 words
The process of claim 1 further characterized in that said water permeable organic polymer comprises a cellulose ester or cellulose nitrate.
Claim 4
Dependent Claim 34 words
The process of claim 1 further characterized in that said cation exchange resin comprises an alkali metal or alkaline earth metal salt of a nuclearly sulfonated polystyrene cation exchange resin containing a cross-linking agent.
Claim 5
Dependent Claim 34 words
The process of claim 3 further characterized in that said cation exchange resin comprises a calcium salt and said cross-linking agent comprises divinylbenzene in an amount comprising about 4.0% by weight of said resin.
Claim 6
Dependent Claim 18 words
The process of claim 1 further characterized in that said feed mixture comprises an aqueous solution of saccharides.
Claim 7
Dependent Claim 18 words
The process of claim 5 further characterized in that said saccharides comprise a mixture of fructose and glucose.
Claim 8
Dependent Claim 21 words
The process of claim 5 further characterized in that recovery of said adsorbed component is effected with a desorbent comprising water.
Claim 9
Dependent Claim 22 words
The process of claim 5 further characterized in that the pH of said aqueous solution is from about 5.0 to about 8.0.

References Cited (Backward Citations)

US3044904A Cited
US3044905A Cited
US3416961A Cited
US3951859A Cited
US4025357A Cited
US4101338A Cited
US4140653A Cited
US4133755A Cited
US4248737A Cited
US4363672A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1986-12-19 1987-06-20 1987-12-20 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1990-12-19 1991-06-20 1991-12-20 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1994-12-19 1995-06-20 1995-12-20 $7700.00 Window Closed / Lapsed

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