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Patent US4378415A successfully refreshed from Google Patents.
US4378415A
Expired / Lapsed
US
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Color imaging, layered organic photoresponsive device having hole injection and transport layers, red sensitive layer and short wavelength sensitive layer
Assignee: Xerox Corp
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Filing: 1981-10-13
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Granted: 1983-03-29
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Expires: 2001-10-13
Abstract
Abstract This invention is directed to a layered organic photoresponsive device, and a method of highlight color imaging, the device being comprised of (1) a supporting substrate, (2) a layer of material capable of injecting holes into a layer on its surface, this layer being comprised of a material selected from the group consisting of carbon dispersed in a polymer, and graphite dispersed in a polymer, (3) a hole transport layer in operative contact with the layer of hole injecting material, which transport layer comprises a combination of a highly insulating organic resin having dispersed therein small molecules of an electrically active material, the combination of which is substantially nonabsorbing to visible light but allows injection of photogenerated holes from a photogenerating layer in contact with the hole transport layer, and electrically induced holes from the layer of injecting material, (4) a red sensitive charge carrier photogenerating layer sensitive to wavelengths ranging from about the visible range to about 620 millimicrons, said layer being transparent to light of wavelengths of greater than 620 millimicrons, (5) a top layer of a photoconductive material sensitive only to relatively short wavelengths ranging from about the visible range to about 620 millimicrons, said layer being transparent to light of wavelengths of greater than 620 millimicrons. Highlight imaging is accomplished by subjecting the above device to negative charges, followed by subjecting the device to positive charges, imagewise exposing the member, and developing with a colored developer composition comprised of positively charged toner components and negatively charged toner components, and carrier particles.
Inventors
- 👤 Joseph Y. C. Chu
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-29 14:59
CPC Classifications
G; G03; G03G; G03G13/00; G03G13/01; G03G5/00; G03G5/02; G03G5/04; G03G5/043; G03G5/0436; G03G5/047
Claims Analysis
Total Claims: 23
Claim 1
Independent Claim
196 words
An improved layered organic photoresponsive device, useful in highlight color imaging processes, which device is comprised in the order stated of (1) a supporting substrate, (2) a layer of material capable of injecting holes into a layer on its surface, this layer being comprised of a material selected from the group consisting of carbon dispersed in a polymer, and graphite dispersed in a polymer, (3) a hole transport layer in operative contact with the layer of hole injecting material, which transport layer comprises a combination of a highly insulating organic resin having dispersed therein small molecules of an electrically active material, the combination of which is substantially non-absorbing to visible light but allows injection of photogenerated holes from a photogenerating layer in contact with the hole transport layer, and electrically induced holes from the layer of injecting material, (4) a red sensitive charge carrier photogenerating layer sensitive to wavelengths ranging from about 610 millimicrons to about 680 millimicrons, and (5) a top layer of a photoconductive material sensitive only to relatively short wavelengths ranging from about the visible range to about 620 millimicrons, said layer being transparent to light of wavelengths of greater than 620 millimicrons.
Claim 2
Dependent Claim
196 words
An improved layered organic photoresponsive device, useful in highlight color imaging processes, which device is comprised in the order stated of (1) a supporting substrate, (2) a layer of material capable of injecting holes into a layer on its surface, this layer being comprised of a material selected from the group consisting of carbon dispersed in a polymer, and graphite dispersed in a polymer, (3) a hole transport layer in operative contact with the layer of hole injecting material, which transport layer comprises a combination of a highly insulating organic resin having dispersed therein small molecules of an electrically active material, the combination of which is substantially non-absorbing to visible light but allows injection of photogenerated holes from a photogenerating layer in contact with the hole transport layer, and electrically induced holes from the layer of injecting material, (4) a red sensitive charge carrier photogenerating layer sensitive to wavelengths ranging from about 610 millimicrons to about 680 millimicrons, and (5) a top layer of a photoconductive material sensitive only to relatively short wavelengths ranging from about the visible range to about 620 millimicrons, said layer being transparent to light of wavelengths of greater than 620 millimicrons.
Claim 3
Dependent Claim
40 words
An improved layered organic photoresponsive device in accordance with claim 1 wherein the supporting substrate is electrically conductive, the red sensitive layer is comprised of vanadyl phthalocyanine, or x-metal free phthalocyanine and the top layer is comprised of amorphous selenium.
Claim 4
Dependent Claim
20 words
An improved layered photoresponsive device in accordance with claim 1 wherein the red sensitive layer is a selenium tellurium alloy.
Claim 5
Dependent Claim
21 words
An improved layered photoresponsive device in accordance with claim 1 wherein the red sensitive layer is 1,3 bis(4-dimethyl amino-2-phenyl) cyclobutenediylium dioxide.
Claim 6
Dependent Claim
20 words
An improved layered photoresponsive device in accordance with claim 1 wherein the red sensitive layer is 1,3-bis(4'-dimethylamino-2-hydroxy phenyl) cyclobutenediylium dioxide.
Claim 7
Dependent Claim
20 words
An improved layered photoresponsive device in accordance with claim 1 wherein the red sensitive layer is 1,3-bis(4'-dimethylamino-2-methyl phenyl) cyclobutenediylium oxide.
Claim 8
Dependent Claim
23 words
An improved layered photoresponsive device in accordance with claim 1 wherein the red sensitive layer is a complex of polyvinyl carbazole and trinitrofluorene.
Claim 9
Dependent Claim
90 words
An improved layered organic photoresponsive device in accordance with claim 1 wherein the thickness of the substrate ranges from about 3 mils to about 100 mils, the thickness of the hole injecting layer ranges from about 1 micron to about 20 microns, the thickness of the charge transport layer ranges from about 5 microns to about 50 microns, the thickness of the red sensitive layer ranges from about 0.5 microns to about 10 microns, and the thickness of the top layer ranges from about 5 microns to about 40 microns.
Claim 10
Dependent Claim
59 words
An improved layered organic photoresponsive device in accordance with claim 1, wherein the electrically active material dispersed in an insulating organic resin is a nitrogen containing compound of the formula: ##STR2## wherein X is selected from the group consisting of (ortho) CH 3 , (meta) CH 3 , (para) CH 3 , (chloro) Cl, (meta) Cl and (para) Cl.
Claim 11
Dependent Claim
29 words
An improved layered organic photoresponsive device in accordance with claim 9 wherein the hole transport layer contains from about 10 to about 75 percent of a nitrogen containing composition.
Claim 12
Dependent Claim
17 words
An improved layered organic photoresponsive device in accordance with claim 9 wherein the transport layer is N,N'-diphenyl-N,N'-bis(3-methylphenyl)-[1,1'-biphenyl]-4,4'-diamine.
Claim 13
Dependent Claim
237 words
An improved process of color imaging which comprises subjecting an organic layered photoresponsive device comprised in the order stated of (1) a supporting substrate, (2) a layer of material capable of injecting holes into a layer on its surface, this layer being comprised of material selected from the group consisting of carbon dispersed in a polymer, and graphite dispersed in a polymer, (3) a hole transport layer in operative contact with the layer of hole injecting material, which transport layer comprises a combination of a highly insulating organic resin having dispersed therein small molecules of an electrically active material, the combination of which is substantially non-absorbing to visible light but allows injection of photogenerated holes from a photogenerating layer in contact with the hole transport layer, and electrically induced holes from the layer of injecting material, (4) a red sensitive charge carrier photogenerating layer sensitive to wavelengths ranging from about 610 millimicrons to about 680 millimicrons, and (5) a top layer of a photoconductive material sensitive only to relatively short wavelengths ranging from about the visible range to about 620 millimicrons, said layer being transparent to light of wavelengths of greater than 620 millimicrons, subjecting the device to negative charges, followed by subjecting the device to positive charges, imagewise exposing the member, and developing the resulting surface potential with a colored developer composition comprised of positively charged toner components and negatively charged toner components, and carrier particles.
Claim 14
Dependent Claim
237 words
An improved process of color imaging which comprises subjecting an organic layered photoresponsive device comprised in the order stated of (1) a supporting substrate, (2) a layer of material capable of injecting holes into a layer on its surface, this layer being comprised of material selected from the group consisting of carbon dispersed in a polymer, and graphite dispersed in a polymer, (3) a hole transport layer in operative contact with the layer of hole injecting material, which transport layer comprises a combination of a highly insulating organic resin having dispersed therein small molecules of an electrically active material, the combination of which is substantially non-absorbing to visible light but allows injection of photogenerated holes from a photogenerating layer in contact with the hole transport layer, and electrically induced holes from the layer of injecting material, (4) a red sensitive charge carrier photogenerating layer sensitive to wavelengths ranging from about 610 millimicrons to about 680 millimicrons, and (5) a top layer of a photoconductive material sensitive only to relatively short wavelengths ranging from about the visible range to about 620 millimicrons, said layer being transparent to light of wavelengths of greater than 620 millimicrons, subjecting the device to negative charges, followed by subjecting the device to positive charges, imagewise exposing the member, and developing the resulting surface potential with a colored developer composition comprised of positively charged toner components and negatively charged toner components, and carrier particles.
Claim 15
Dependent Claim
80 words
An improved imaging process in accordance with claim 12 wherein the positively charged components of the toner composition contain red toner particles, and the negatively charged components of the toner composition is comprised of black toner particles, wherein the red toner particles adhere to the red image area, or negative surface potential of the photoresponsive device, and the black toner particles adhere to the black image area or the area of the photoresponsive device containing a net positive surface potential.
Claim 16
Dependent Claim
23 words
An improved imaging process in accordance with claim 12 wherein the resulting image is transferred to a suitable substrate and permanently affixed thereto.
Claim 17
Dependent Claim
38 words
An improved imaging process in accordance with claim 12 wherein the supporting substrate is electrically conductive, the red sensitive layer is comprised of vanadyl phthalocyanine, or x-metal free phthalocyanine and the top layer is comprised of amorphous selenium.
Claim 18
Dependent Claim
19 words
An improved imaging process in accordance with claim 12 wherein the red sensitive layer is a selenium tellurium alloy.
Claim 19
Dependent Claim
19 words
An improved imaging process in accordance with claim 1 wherein the red sensitive layer is 1,3-bis(4-dimethyl amino-2-phenyl) cyclobutenediylium dioxide.
Claim 20
Dependent Claim
19 words
An improved imaging process in accordance with claim 12 wherein the red sensitive layer is 1,3-bis(4'-dimethylamino-2-hydroxy phenyl) cyclobutenediylium dioxide.
Claim 21
Dependent Claim
19 words
An improved imaging process in accordance with claim 12 wherein the red sensitive layer is 1,3-bis(4'-dimethylamino-2-methyl phenyl) cyclobutenediylium dioxide.
Claim 22
Dependent Claim
22 words
An improved imaging process in accordance with claim 12 wherein the red sensitive layer is a complex of polyvinyl carbazole and trinitrofluorene.
Claim 23
Dependent Claim
88 words
An improved imaging process in accordance with claim 12 wherein the thickness of the substrate ranges from about 3 mils to about 100 mils, the thickness of the hole injecting layer ranges from about 1 micron to about 20 microns, the thickness of the charge transport layer ranges from about 5 microns to about 50 microns, the thickness of the red sensitive layer ranges from about 0.5 microns to about 10 microns, and the thickness of the top layer ranges from about 5 microns to about 40 microns.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1986-03-28 | 1986-09-27 | 1987-03-29 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1990-03-28 | 1990-09-27 | 1991-03-29 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1994-03-28 | 1994-09-27 | 1995-03-29 | $7700.00 | Window Closed / Lapsed |