US4366312A
Expired / Lapsed
US
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Metal complexes of isoindolinazines, process for their preparation and use
Assignee: Novartis Corp
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Filing: 1981-03-09
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Granted: 1982-12-28
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Expires: 2001-03-09
Abstract
Abstract 1:1 metal complexes of azines of the formula ##STR1## in which the ring A can be further substituted, R is an H atom or an alkyl or aryl group, B is an isocyclic or heterocyclic aromatic radical or an alicyclic radical, R 1 is the OH or SH group and Y is a radical of the formula ##STR2## in which Z is an O or S atom, n is the number 1 or 2 and R 2 is an alkyl, aralkyl, cycloalkyl or aryl radical or an amino group which is unsubstituted or substituted by an alkyl, cycloalkyl, aralkyl or aryl radical. In plastics and surface coatings, the novel pigments give intense pure orange to violet colorations with good fastness properties.
Inventors
- 👤 Abul Iqbal
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-02 13:05
CPC Classifications
C; C07; C07D; C07D209/00; C07D209/02; C07D209/44; C09; C09B; C09B26/00; C09B26/02; C09B57/00; C09B57/04
Claims Analysis
Total Claims: 8
Claim 1
Independent Claim
167 words
A 1:1 metal complex of an azine of the formula ##STR41## wherein ring A is unsubstituted or is substituted by two to four halogen atoms, by one or two alkyl of 1 to 4 carbon atoms, by one or two alkoxy of 1 to 4 carbon atoms, by phenyl, by phenoxy, by nitro, by benzoylamino or by alkanoylamino having 2 to 6 carbon atoms, R is hydrogen, alkyl of 1 to 4 carbon atoms, phenyl or naphthyl, B is phenylene, naphthylene, cyclohexenylene or a pyrazole, pyridine, pyrimidine, quinoline or coumarin radical, R 1 is OH or SH, Y is a radical of the formula ##STR42## in which Z is an O or S atom, n is the number 1 or 2 and R 2 is an alkyl, aralkyl, cycloalkyl or aryl radical or an amino group which is unsubstituted or substituted by an alkyl, cycloalkyl, aralkyl or aryl radical, and the metal is selected from the group consisting of zinc, cadmium, manganese, cobalt, iron, copper and nickel.
Claim 2
Dependent Claim
167 words
A 1:1 metal complex of an azine of the formula ##STR41## wherein ring A is unsubstituted or is substituted by two to four halogen atoms, by one or two alkyl of 1 to 4 carbon atoms, by one or two alkoxy of 1 to 4 carbon atoms, by phenyl, by phenoxy, by nitro, by benzoylamino or by alkanoylamino having 2 to 6 carbon atoms, R is hydrogen, alkyl of 1 to 4 carbon atoms, phenyl or naphthyl, B is phenylene, naphthylene, cyclohexenylene or a pyrazole, pyridine, pyrimidine, quinoline or coumarin radical, R 1 is OH or SH, Y is a radical of the formula ##STR42## in which Z is an O or S atom, n is the number 1 or 2 and R 2 is an alkyl, aralkyl, cycloalkyl or aryl radical or an amino group which is unsubstituted or substituted by an alkyl, cycloalkyl, aralkyl or aryl radical, and the metal is selected from the group consisting of zinc, cadmium, manganese, cobalt, iron, copper and nickel.
Claim 3
Dependent Claim
129 words
A metal complex of the formula ##STR43## in which M is nickel or copper, R' is H or methyl, B' is a quinoline radical and Y' is a radical of the formula ##STR44## in which R 3 is an H atom, an alkyl group having 1-4 C or a radical of the formula ##STR45## in which X 1 is an H, chlorine or bromine atom, a nitro, trifluoromethyl, carbamoyl or sulfamoyl group, an alkyl, alkoxy or alkylsulfamoyl group having 1-4 C, an alkanoylamino, alkylcarbamoyl or alkoxycarbonyl group having 2-6 C, or a phenoxy, phenylcarbamoyl or phenylsulfamoyl group which is unsubstituted or substituted by chlorine or bromine atoms or methyl groups, and X 2 is an H, chlorine or bromine atom or an alkyl or alkoxy group having 1-4 C.
Claim 4
Dependent Claim
129 words
A metal complex of the formula ##STR43## in which M is nickel or copper, R' is H or methyl, B' is a quinoline radical and Y' is a radical of the formula ##STR44## in which R 3 is an H atom, an alkyl group having 1-4 C or a radical of the formula ##STR45## in which X 1 is an H, chlorine or bromine atom, a nitro, trifluoromethyl, carbamoyl or sulfamoyl group, an alkyl, alkoxy or alkylsulfamoyl group having 1-4 C, an alkanoylamino, alkylcarbamoyl or alkoxycarbonyl group having 2-6 C, or a phenoxy, phenylcarbamoyl or phenylsulfamoyl group which is unsubstituted or substituted by chlorine or bromine atoms or methyl groups, and X 2 is an H, chlorine or bromine atom or an alkyl or alkoxy group having 1-4 C.
Claim 5
Dependent Claim
13 words
A metal complex according to claim 1 wherein B is a quinoline radical.
Claim 6
Dependent Claim
140 words
A metal complex of the formula ##STR46## in which M is nickel or copper, R' is H or methyl, B' is a quinoline radical, and Y' is a radical of the formula ##STR47## in which Z is an O or S atom and R 4 is an alkyl group having 1-4 C, a cyclohexyl group, a benzyl group or a group of the formula ##STR48## in which X 1 is an H, chlorine or bromine atom, a nitro, trifluoromethyl, carbamoyl or sulfamoyl group, an alkyl, alkoxy or alkylsulfamoyl group having 1-4 C, an alkanoylamino, alkylcarbamoyl or alkoxycarbonyl group having 2-6 C, or a phenoxy, phenylcarbamoyl or phenylsulfamoyl group which is unsubstituted or substituted by chlorine or bromine atoms or methyl groups, and X 2 is an H, chlorine or bromine atom or an alkyl or alkoxy group having 1-4 C.
Claim 7
Dependent Claim
140 words
A metal complex of the formula ##STR46## in which M is nickel or copper, R' is H or methyl, B' is a quinoline radical, and Y' is a radical of the formula ##STR47## in which Z is an O or S atom and R 4 is an alkyl group having 1-4 C, a cyclohexyl group, a benzyl group or a group of the formula ##STR48## in which X 1 is an H, chlorine or bromine atom, a nitro, trifluoromethyl, carbamoyl or sulfamoyl group, an alkyl, alkoxy or alkylsulfamoyl group having 1-4 C, an alkanoylamino, alkylcarbamoyl or alkoxycarbonyl group having 2-6 C, or a phenoxy, phenylcarbamoyl or phenylsulfamoyl group which is unsubstituted or substituted by chlorine or bromine atoms or methyl groups, and X 2 is an H, chlorine or bromine atom or an alkyl or alkoxy group having 1-4 C.
Claim 8
Dependent Claim
19 words
A nickel complex according to claim 2 which has the formula ##STR49## or is an isomer or tautomer thereof.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1985-12-27 | 1986-06-28 | 1986-12-28 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1989-12-27 | 1990-06-28 | 1990-12-28 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1993-12-27 | 1994-06-28 | 1994-12-28 | $7700.00 | Window Closed / Lapsed |