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US4022770A Expired / Lapsed US ⏱️ 0.0 years remaining

Metal complexes of azomethines and process for their manufacture

Assignee: Novartis Corp
•
Filing: 1975-01-30
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Granted: 1977-05-10
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Expires: 1995-01-30
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Abstract

Abstract Metal complexes of azomethines of the formula ##STR1## are useful for coloring plastics and lacquers in yellow to red shades of excellent fastness properties.

Inventors

  • 👤 Francois L'Eplattenier
  • 👤 Andre Pugin
  • 👤 Jost VON DER Crone

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-02 02:34
CPC Classifications
C; C09; C09B; C09B57/00; C09B57/04; C09B26/00; C09B26/02; C09B26/04; C09B57/10

Claims Analysis

Total Claims: 6
Claim 1
Independent Claim 226 words
An azomethine metal complex of the formula ##STR166## in which R 3 is hydrogen, M 1 is Ni, Cu, Co or Zn, A is a radical of the formulae ##STR167## in which Q is methyl, alkoxycarbonyl with 2 to 5 carbon atoms or carbamoyl, R 8 is cyano, or carbamoyl, R 9 is hydrogen, or hydroxy, Y 2 and Y 3 is hydrogen, halogen, alkyl of 1 to 4 carbon atoms, alkoxy of 1 to 4 carbon atoms, or nitro, Y 4 is oxygen, sulfur or amino, Y 6 is hydrogen, carboxy, carbamoyl, alkoxycarbamoyl containing 2 to 6 carbon atoms, alkylcarbamoyl containing 2 to 6 carbon atoms, phenylcarbamoyl, phenylcarbamoyl substituted in the phenyl moiety by halogen, alkyl of 1 to 4 carbon atoms, or alkoxy of 1 to 4 carbon atoms, Y 7 is hydrogen, halogen, methoxy, nitro or cyano, Y is a group of the formulae ##STR168## in which Y 2 , Y 3 and Y 4 have the above-indicated meanings, R 6 is hydrogen, alkyl of 1 to 4 carbon atoms, phenyl, phenyl substituted by halogen, alkyl of 1 to 4 carbon atoms or alkoxy of 1 to 4 carbon atoms, R 4 is cyano, acyl, alkoxycarbonyl, carbamoyl, sulphamoyl, or a radical of the formula ##STR169## in which V is oxygen, sulfur or imino, Y 2 and Y 3 have the meaning indicated above.
Claim 2
Dependent Claim 226 words
An azomethine metal complex of the formula ##STR166## in which R 3 is hydrogen, M 1 is Ni, Cu, Co or Zn, A is a radical of the formulae ##STR167## in which Q is methyl, alkoxycarbonyl with 2 to 5 carbon atoms or carbamoyl, R 8 is cyano, or carbamoyl, R 9 is hydrogen, or hydroxy, Y 2 and Y 3 is hydrogen, halogen, alkyl of 1 to 4 carbon atoms, alkoxy of 1 to 4 carbon atoms, or nitro, Y 4 is oxygen, sulfur or amino, Y 6 is hydrogen, carboxy, carbamoyl, alkoxycarbamoyl containing 2 to 6 carbon atoms, alkylcarbamoyl containing 2 to 6 carbon atoms, phenylcarbamoyl, phenylcarbamoyl substituted in the phenyl moiety by halogen, alkyl of 1 to 4 carbon atoms, or alkoxy of 1 to 4 carbon atoms, Y 7 is hydrogen, halogen, methoxy, nitro or cyano, Y is a group of the formulae ##STR168## in which Y 2 , Y 3 and Y 4 have the above-indicated meanings, R 6 is hydrogen, alkyl of 1 to 4 carbon atoms, phenyl, phenyl substituted by halogen, alkyl of 1 to 4 carbon atoms or alkoxy of 1 to 4 carbon atoms, R 4 is cyano, acyl, alkoxycarbonyl, carbamoyl, sulphamoyl, or a radical of the formula ##STR169## in which V is oxygen, sulfur or imino, Y 2 and Y 3 have the meaning indicated above.
Claim 3
Dependent Claim 13 words
The 1:1-nickel-complex according to claim 1 of the compound of the formula ##STR170##
Claim 4
Dependent Claim 10 words
The compound according to claim 1 of the formula ##STR171##
Claim 5
Dependent Claim 10 words
The compound according to claim 1 of the formula ##STR172##
Claim 6
Dependent Claim 10 words
The compound according to claim 1 of the formula ##STR173##

References Cited (Backward Citations)

US3389132A Cited
US3661898A Cited
US3891685A Cited
US3867404A Cited
US3892750A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1980-05-09 1980-11-08 1981-05-10 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1984-05-09 1984-11-08 1985-05-10 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1988-05-09 1988-11-08 1989-05-10 $7700.00 Window Closed / Lapsed

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