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US4237293A
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Metal complexes of azomethines
Assignee: BASF Corp
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Filing: 1978-10-26
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Granted: 1980-12-02
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Expires: 1998-10-26
Abstract
Abstract Metal complexes of azomethines of the formula ##STR1## are useful for coloring plastics and lacquers in yellow to red shades of excellent fastness properties.
Inventors
- 👤 Francois L'Eplattenier
- 👤 Andre Pugin
- 👤 Jost VON DER Crone
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-02 17:05
CPC Classifications
C; C09; C09B; C09B57/00; C09B57/04; C09B26/00; C09B26/02; C09B26/04; C09B57/10
Claims Analysis
Total Claims: 6
Claim 1
Independent Claim
143 words
An azomethine metal complex of the formula ##STR162## in which R 3 is alkyl of 1 to 4 carbon atoms, M 1 is Ni, Cu, Co or Zn, A is a radical for the formulae ##STR163## in which Q is methyl, alkoxycarbonyl with 2 to 5 carbon atoms or carbamoyl, R 8 is cyano, or carbamoyl, R 9 is hydrogen, or hydroxy, Y 2 and Y 3 are hydrogen, halogen, alkyl of 1 to 4 carbon atoms, alkoxy of 1 to 4 carbon atoms, or nitro, Y 4 is --NH--, Y 6 is hydrogen, carboxy, carbamoyl, alkoxycarbamoyl of 2 to 6 carbon atoms, alkylcarbamoyl of 2 to 6 carbon atoms, phenylcarbamoyl, phenylcarbamoyl substituted in the phenyl moiety by halogen, alkyl of 1 to 4 carbon atoms, or alkoxy of 1 to 4 carbon atoms, Y 7 is hydrogen, halogen, methoxy, nitro or cyano.
Claim 2
Dependent Claim
143 words
An azomethine metal complex of the formula ##STR162## in which R 3 is alkyl of 1 to 4 carbon atoms, M 1 is Ni, Cu, Co or Zn, A is a radical for the formulae ##STR163## in which Q is methyl, alkoxycarbonyl with 2 to 5 carbon atoms or carbamoyl, R 8 is cyano, or carbamoyl, R 9 is hydrogen, or hydroxy, Y 2 and Y 3 are hydrogen, halogen, alkyl of 1 to 4 carbon atoms, alkoxy of 1 to 4 carbon atoms, or nitro, Y 4 is --NH--, Y 6 is hydrogen, carboxy, carbamoyl, alkoxycarbamoyl of 2 to 6 carbon atoms, alkylcarbamoyl of 2 to 6 carbon atoms, phenylcarbamoyl, phenylcarbamoyl substituted in the phenyl moiety by halogen, alkyl of 1 to 4 carbon atoms, or alkoxy of 1 to 4 carbon atoms, Y 7 is hydrogen, halogen, methoxy, nitro or cyano.
Claim 3
Dependent Claim
22 words
An azomethine metal complex according to claim 1 of the formula ##STR164## wherein R 3 is methyl; and M 1 is Cu.
Claim 4
Dependent Claim
143 words
An azomethine metal complex of the formula ##STR165## in which R 3 is alkyl of 1 to 4 carbon atoms, M 1 is Ni, Cu, Co or Zn, A is a radical of the formulae ##STR166## in which Q is methyl, alkoxycarbonyl with 2 to 5 carbon atoms or carbamoyl, R 8 is cyano, or carbamoyl, R 9 is hydrogen, or hydroxy, Y 2 and Y 3 are hydrogen, halogen, alkyl of 1 to 4 carbon atoms, alkoxy of 1 to 4 carbon atoms, or nitro, Y 4 is --NH--, Y 6 is hydrogen, carboxy, carbamoyl, alkoxycarbamoyl containing 2 to 6 carbon atoms, alkylcarbamoyl containing 2 to 6 carbon atoms, phenylcarbamoyl, phenylcarbamoyl substituted in the phenyl moiety by halogen, alkyl of 1 to 4 carbon atoms, or alkoxy of 1 to 4 carbon atoms, Y 7 is hydrogen, halogen, methoxy, nitro or cyano.
Claim 5
Dependent Claim
143 words
An azomethine metal complex of the formula ##STR165## in which R 3 is alkyl of 1 to 4 carbon atoms, M 1 is Ni, Cu, Co or Zn, A is a radical of the formulae ##STR166## in which Q is methyl, alkoxycarbonyl with 2 to 5 carbon atoms or carbamoyl, R 8 is cyano, or carbamoyl, R 9 is hydrogen, or hydroxy, Y 2 and Y 3 are hydrogen, halogen, alkyl of 1 to 4 carbon atoms, alkoxy of 1 to 4 carbon atoms, or nitro, Y 4 is --NH--, Y 6 is hydrogen, carboxy, carbamoyl, alkoxycarbamoyl containing 2 to 6 carbon atoms, alkylcarbamoyl containing 2 to 6 carbon atoms, phenylcarbamoyl, phenylcarbamoyl substituted in the phenyl moiety by halogen, alkyl of 1 to 4 carbon atoms, or alkoxy of 1 to 4 carbon atoms, Y 7 is hydrogen, halogen, methoxy, nitro or cyano.
Claim 6
Dependent Claim
24 words
An azomethine metal complex according to claim 3 of the formula ##STR167## wherein R 3 is methyl; and M 1 is Ni or Cu.
References Cited (Backward Citations)
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1983-12-02 | 1984-06-02 | 1984-12-02 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1987-12-02 | 1988-06-02 | 1988-12-02 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1991-12-02 | 1992-06-02 | 1992-12-02 | $7700.00 | Window Closed / Lapsed |