Patent US4337968A successfully refreshed from Google Patents.
US4337968A
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US
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Sensitized record sheet
Assignee: Standard Register Co
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Filing: 1980-10-24
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Granted: 1982-07-06
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Expires: 2000-10-24
Abstract
Abstract A very thin film of acidic color developing material which reacts with a dye precursor to form a color upon contact therewith is obtained in a substantially spongy capillary-like film firmly adhered to the paper substrate without diffusing thereinto in accordance with the present invention. The film contains a phenolic resin, and amorphous lipohilic silica, preferably pyrogenic hydrophobic silica, and a fatty alcohol, preferably cetyl alcohol. The composition further preferably includes a non-volatile solvent. This composition not only provides excellent color-forming ability with a very thin film which adheres firmly to the paper, but may be applied to the paper with a standard printing press.
Inventors
- 👤 Theodore Maierson
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-04 22:39
CPC Classifications
B; B41; B41M; B41M5/00; B41M5/124; B41M5/132; B41M5/155; Y; Y10; Y10S; Y10S428/00; Y10S428/914; Y10T; Y10T428/00; Y10T428/24; Y10T428/24802; Y10T428/24934; Y10T428/249921; Y10T428/249953; Y10T428/249994; Y10T428/249995; Y10T428/249996; Y10T428/25; Y10T428/259; Y10T428/27; Y10T428/273; Y10T428/277
Claims Analysis
Total Claims: 21
Claim 1
Independent Claim
162 words
A thin spongy porous color developler film for use in producing a color when in contact with a suitable dye precursor, produced by thinly depositing on a substrate a composition consisting essentially of: an organic solvent soluble phenolic resin capable of serving as an acidic image former when in combination with a suitable dye precursor, in an amount sufficient to serve as such an image former in the final film; a lipophilic amorphous silica having a stable size not exceeding 50 millimicrons; a fatty alcohol capable of serving as an adjunct in combination with said silica to obtain a porous film structure without substantially adversely affecting the color forming reaction or the color so formed, the combined amounts of said fatty alcohol and lipophilic silica being sufficient to form a spongy capillary skeletal structure in the deposited film; and an organic solvent capable of dissolving said phenolic resin and said fatty alcohol and which does not substantially interfere with the color-forming reaction.
Claim 2
Dependent Claim
162 words
A thin spongy porous color developler film for use in producing a color when in contact with a suitable dye precursor, produced by thinly depositing on a substrate a composition consisting essentially of: an organic solvent soluble phenolic resin capable of serving as an acidic image former when in combination with a suitable dye precursor, in an amount sufficient to serve as such an image former in the final film; a lipophilic amorphous silica having a stable size not exceeding 50 millimicrons; a fatty alcohol capable of serving as an adjunct in combination with said silica to obtain a porous film structure without substantially adversely affecting the color forming reaction or the color so formed, the combined amounts of said fatty alcohol and lipophilic silica being sufficient to form a spongy capillary skeletal structure in the deposited film; and an organic solvent capable of dissolving said phenolic resin and said fatty alcohol and which does not substantially interfere with the color-forming reaction.
Claim 3
Dependent Claim
26 words
A film in accordance with claim 1, wherein said phenolic resin is an acetylated phenolic resin, salicylic acid modified phenolic resin or a novolac-type phenolic resin.
Claim 4
Dependent Claim
37 words
A film in accordance with claim 1, wherein said phenolic resin is one which has been reacted with or is present in conjunction with a metal cation capable of enhancing the color forming ability of the resin.
Claim 5
Dependent Claim
12 words
A film in accordance with claim 3, wherein said cation is zinc.
Claim 6
Dependent Claim
14 words
A film in accordance with claim 1, wherein said fatty alcohol is cetyl alcohol.
Claim 7
Dependent Claim
19 words
A film in accordance with claim 1 or claim 5, wherein said lipophilic silica is a pyrogenic hydrophobic silica.
Claim 8
Dependent Claim
39 words
A film in accordance with claim 1, wherein said solvent is a non-volatile solvent having a boiling point above about 175° C. and present in an amount sufficient to act as a plasticizer when retained in the deposited film.
Claim 9
Dependent Claim
14 words
A film in accordance with claim 1, wherein said solvent is mineral seal oil.
Claim 10
Dependent Claim
48 words
A film in accordance with claim 1, wherein said composition further includes gelatinous polyethylene in an amount sufficient to provide mechanical rigidity to the deposited film structure without otherwise affecting the spongy nature thereof and which will not substantially affect the color-forming reaction or the color so formed.
Claim 11
Dependent Claim
13 words
A film in accordance with claim 9, wherein said polyethylene comprises oxidized polyethylene.
Claim 12
Dependent Claim
48 words
A film in accordance with claim 1, wherein said composition further includes a liquid zinc salt, soluble in the system, in an amount sufficient to improve the color forming ability of said phenolic resin and reduce the tack of the composition to improve press performance of the composition.
Claim 13
Dependent Claim
41 words
A film in accordance with claim 1, wherein said solvent is a volatile solvent and said phenolic resin, fatty alcohol and lipophilic silica are present in the following relative quantities: ______________________________________
phenolic resin 54-95%
fatty alcohol 2-40%
lipophilic silica 0.5-6%
______________________________________
Claim 14
Dependent Claim
31 words
A film in accordance with claim 7, wherein the relative proportions of components of said composition are: ______________________________________
phenolic resin 10-70%
fatty alcohol 2-20%
lipophilic silica 0.5-6%
non-volatile solvent 18-82%
______________________________________
Claim 15
Dependent Claim
25 words
A film in accordance with claim 13, wherein said proportions are: ______________________________________
phenolic resin 20-50%
fatty alcohol 2-15%
lipophilic silica 0.5-5%
non-volatile solvent 35-69.5%
______________________________________
Claim 16
Dependent Claim
16 words
A film in accordance with claim 1 in a quantity corresponding to 0.4-1.4 g/m 2 .
Claim 17
Dependent Claim
58 words
A film in accordance with claim 1, wherein said composition consists essentially of: ______________________________________
non-volatile solvent 25-32%
oil with volatility of no more
than 7% weight loss over 22
hour period at 225° F.
5-9%
liquid zinc salt 4-8%
granular oxidized polyethylene
2-4%
pyrogenic hydrophobic silica
2-4%
cetyl alcohol 5-10%
zinc abietate 5-12%
zincated novolac resin 30-40%
______________________________________
Claim 18
Dependent Claim
27 words
A film in accordance with one of claims 12, 13 or 14 wherein said fatty alcohol is cetyl alcohol and said lipophilic silica is pyrogenic hydrophobic silica.
Claim 19
Dependent Claim
21 words
A record sheet comprising a sheet substrate having deposited thereon a thin continuous or discontinuous film in accordance with claim 1.
Claim 20
Independent Claim
80 words
A method for producing a sheet having printed thereon a color developer being capable of producing a color when in contact with a suitable dye precursor, comprising: printing with a conventional printing press, in a quantity corresponding to 0.4 to 1.4 g/m 2 , a composition consisting essentially of: 10-70% of a zincated or non-zincated novolac resin; 2-20% of cetyl alcohol; 0.5-6% of pyrogenic hydrophobic silica; and 18-82% of a non-volatile solvent for said novolac resin and said cetyl alcohol.
Claim 21
Independent Claim
80 words
A method for producing a sheet having printed thereon a color developer being capable of producing a color when in contact with a suitable dye precursor, comprising: printing with a conventional printing press, in a quantity corresponding to 0.4 to 1.4 g/m 2 , a composition consisting essentially of: 10-70% of a zincated or non-zincated novolac resin; 2-20% of cetyl alcohol; 0.5-6% of pyrogenic hydrophobic silica; and 18-82% of a non-volatile solvent for said novolac resin and said cetyl alcohol.
References Cited (Backward Citations)
US3672935A
Cited
US3932695A
Cited
US3516845A
Cited
US3466184A
Cited
US3466185A
Cited
US3723156A
Cited
US3732120A
Cited
US4005237A
Cited
US4154462A
Cited
US4147830A
Cited
US4060262A
Cited
US4087284A
Cited
US4089547A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1985-07-05 | 1986-01-04 | 1986-07-06 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1989-07-05 | 1990-01-04 | 1990-07-06 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1993-07-05 | 1994-01-04 | 1994-07-06 | $7700.00 | Window Closed / Lapsed |