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US4060262A Expired / Lapsed US ⏱️ 0.0 years remaining

Record material

Assignee: Standard Register Co
•
Filing: 1976-03-24
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Granted: 1977-11-29
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Expires: 1996-03-24
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Abstract

Abstract A sensitized record sheet for developing useful color in oily, colorless, chromogenic dye-precursor inks applied thereto. Said record sheet is acid-reacting and bears a liquid ink comprising a non-evaporable liquid organic solvent having dissolved therein an acidic phenolic resin and a lower alkyl gallate.

Inventors

  • 👤 Theodore Maierson

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-05 06:29
CPC Classifications
B; B41; B41M; B41M5/00; B41M5/124; B41M5/132; B41M5/155; Y; Y10; Y10S; Y10S428/00; Y10S428/914; Y10T; Y10T428/00; Y10T428/31504; Y10T428/31942; Y10T428/31949; Y10T428/31964

Claims Analysis

Total Claims: 12
Claim 1
Independent Claim 107 words
A record sheet sensitized with an acidic reactant for developing a color in an oily printing liquid containing a colorless, basic, chromogenic dye-precursor applied thereto by expression of droplets retained by pressure-rupturable wall material located in the sensitized sheet or in an overlying sheet placed against the sensitized sheet, wherein at least one surface of the sensitized sheet bears a substantially colorless, liquid ink comprising an acidic phenolic resin and a lower-alkyl gallate with both the resin and the gallate dissolved in a liquid organic solvent having a boiling point above 300° C and a vapor pressure at 100° C of 1 mm. of mercury or less.
Claim 2
Dependent Claim 107 words
A record sheet sensitized with an acidic reactant for developing a color in an oily printing liquid containing a colorless, basic, chromogenic dye-precursor applied thereto by expression of droplets retained by pressure-rupturable wall material located in the sensitized sheet or in an overlying sheet placed against the sensitized sheet, wherein at least one surface of the sensitized sheet bears a substantially colorless, liquid ink comprising an acidic phenolic resin and a lower-alkyl gallate with both the resin and the gallate dissolved in a liquid organic solvent having a boiling point above 300° C and a vapor pressure at 100° C of 1 mm. of mercury or less.
Claim 3
Dependent Claim 14 words
The sensitized sheet of claim 1, wherein the phenolic resin is a phenol-formaldehyde resin.
Claim 4
Dependent Claim 33 words
The sensitized sheet of claim 2, wherein the liquid ink is about 10-50% of a first organic solvent, about 10-50% of a second organic solvent, about 0.5-10% gallate, and about 1-40% phenolic resin.
Claim 5
Dependent Claim 23 words
The sensitized sheet of claim 2, wherein the liquid ink is about 70% organic solvent, about 2% gallate and about 28% phenolic resin.
Claim 6
Dependent Claim 37 words
The sensitized sheet of claim 4, wherein the liquid ink includes about 35% of N-ethyl-o,p-toluenesulfonamide as part of the organic solvent, wherein the gallate is propyl gallate and wherin the phenolic resin is a tertiary-butylphenolformaldehyde condensation product.
Claim 7
Dependent Claim 32 words
The sensitized sheet of claim 5, wherein the liquid ink further includes about 35% of a second organic solvent selected from the group consisting of chlorinated paraffin oil and hydrogenated methyl abietate.
Claim 8
Dependent Claim 13 words
The sensitized sheet of claim 1, wherein the sheet is a paper sheet.
Claim 9
Dependent Claim 21 words
The sensitized sheet of claim 1 wherein the liquid ink includes about 1-4% of lipophilic pyrogenic silica and 10-35% butyl benzoate.
Claim 10
Dependent Claim 79 words
In a method of making a mark on a record sheet by applying an oily, colorless, basic chromogenic ink to a sensitized surface of the record sheet, the improvement wherein the sensitized surface of the record sheet bears a substantially colorless liquid ink comprising an acidic phenolic resin and a lower-alkyl gallate dissolved in a liquid organic solvent having a boiling point above 300° C and a vapor pressure at 100° C of 1 mm of mercury or less.
Claim 11
Dependent Claim 79 words
In a method of making a mark on a record sheet by applying an oily, colorless, basic chromogenic ink to a sensitized surface of the record sheet, the improvement wherein the sensitized surface of the record sheet bears a substantially colorless liquid ink comprising an acidic phenolic resin and a lower-alkyl gallate dissolved in a liquid organic solvent having a boiling point above 300° C and a vapor pressure at 100° C of 1 mm of mercury or less.
Claim 12
Dependent Claim 33 words
The method of claim 9 wherein the record sheet is paper and the liquid ink is about 35% N-ethyl-o,p-toluenesulfonamide, about 35% chlorinated paraffin oil, about 28% tertiary-butylphenol-formaldehyde resin and about 2% propyl gallate.

References Cited (Backward Citations)

US3932695A Cited
US3466184A Cited
US3466185A Cited
US3681390A Cited
US3732120A Cited
US3952132A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1980-11-28 1981-05-30 1981-11-29 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1984-11-28 1985-05-30 1985-11-29 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1988-11-28 1989-05-30 1989-11-29 $7700.00 Window Closed / Lapsed

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