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US4311729A Expired / Lapsed US ⏱️ 0.0 years remaining

Method for manufacturing a ceramic electronic component by electroless metal plating

Assignee: Panasonic Holdings Corp
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Filing: 1980-01-30
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Granted: 1982-01-19
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Expires: 2000-01-30
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Abstract

Abstract Method for manufacturing a ceramic electronic component such as a voltage-dependent non-linear resistor element and a semiconductive ceramic capacitor is disclosed, in which a precisely uniform metal coating is formed on a surface of a ceramic and the metal coating is then heat treated to convert the metal of the metal coating to a metal compound to form a metal compound coating on the surface of the ceramic and/or diffuse a portion of or all of the metal coating into the ceramic, for attaining completely different electric properties than those of untreated ceramic. The present method is particularly useful in the application to a semiconductive ceramic capacitor.

Inventors

  • 👤 Gen Itakura
  • 👤 Hideki Kuramitsu
  • 👤 Yamato Takada
  • 👤 Takayuki Kuroda
  • 👤 Yoshio Irie

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-05 17:47
CPC Classifications
H; H01; H01C; H01C7/00; H01C7/10; H01C7/102; H01C17/00; H01C17/06; H01C17/30; H01C7/006

Claims Analysis

Total Claims: 17
Claim 1
Independent Claim 100 words
A method for manufacturing a ceramic electronic component comprising the steps of forming through electroless plating a precisely uniform coating of metal over a surface of a ceramic body so that the amount of metal deposition is constant thereover; heat-treating the metal coating to form a metal oxide on the surface of said ceramic body whereby a portion of said metal oxide is diffused into said ceramic body; and providing at least two separate electrodes on portions of the surface of the ceramic body whereby ceramic electronic components are produced having uniform electrical characteristics with a relatively small sample variance.
Claim 2
Independent Claim 100 words
A method for manufacturing a ceramic electronic component comprising the steps of forming through electroless plating a precisely uniform coating of metal over a surface of a ceramic body so that the amount of metal deposition is constant thereover; heat-treating the metal coating to form a metal oxide on the surface of said ceramic body whereby a portion of said metal oxide is diffused into said ceramic body; and providing at least two separate electrodes on portions of the surface of the ceramic body whereby ceramic electronic components are produced having uniform electrical characteristics with a relatively small sample variance.
Claim 3
Dependent Claim 20 words
A method for manufacturing a ceramic electronic component according to claim 1, wherein said ceramic body is a semiconductive ceramic.
Claim 4
Dependent Claim 23 words
A method for manufacturing a ceramic electronic component according to claim 2, wherein said semiconductive ceramic is a strontium titanate based semiconductive ceramic.
Claim 5
Dependent Claim 23 words
A method for manufacturing a ceramic electronic component according to claim 2, wherein said semiconductive ceramic is a barium titanate based semiconductive ceramic.
Claim 6
Dependent Claim 26 words
A method for manufacturing a ceramic electronic component according to claim 2, wherein said semiconductive ceramic is a strontium titanate-barium titanate composite compound based semiconductive ceramic.
Claim 7
Dependent Claim 23 words
A method for manufacturing a ceramic electronic component according to claim 2, wherein said semiconductive ceramic is a cuprous oxide based semiconductive ceramic.
Claim 8
Dependent Claim 42 words
A method for manufacturing a ceramic electronic component according to claim 1, wherein said metal coating formed on the surface of said ceramic includes at least one of tin, silver, chromium, zinc, copper, nickel, cobalt, lead, bismuth, boron, iron, talium and manganese.
Claim 9
Dependent Claim 22 words
A method for manufacturing a ceramic electronic component according to claim 1, wherein said ceramic is a zinc oxide based sintered body.
Claim 10
Independent Claim 98 words
A method of manufacturing a non-linear voltage-dependent electronic component comprising the steps of: (a) uniformly forming a coating of a metal over a surface of a ceramic body by electroless plating so that the resulting metal deposition is constant thereover; (b) heat-treating the metal coated ceramic body to convert the metal coating into a metal oxide and simultaneously diffuse at least a portion of the metal oxide into the ceramic body; and (c) providing electrodes on a surface of said ceramic body, whereby an electronic component is produced having uniform electrical characteristics with a relatively small sample variance.
Claim 11
Independent Claim 98 words
A method of manufacturing a non-linear voltage-dependent electronic component comprising the steps of: (a) uniformly forming a coating of a metal over a surface of a ceramic body by electroless plating so that the resulting metal deposition is constant thereover; (b) heat-treating the metal coated ceramic body to convert the metal coating into a metal oxide and simultaneously diffuse at least a portion of the metal oxide into the ceramic body; and (c) providing electrodes on a surface of said ceramic body, whereby an electronic component is produced having uniform electrical characteristics with a relatively small sample variance.
Claim 12
Independent Claim 94 words
A method of making a non-linear voltage-dependent electronic component comprising the steps of: (a) electroless plating a metal coating over a surface of a ceramic body so that the amount of metal dispersion is constant thereover; (b) heat-treating the metal coated ceramic body to oxidize the metal coating and simultaneously diffuse at least a portion of the oxidized metal coating into said ceramic body; and (c) providing electrodes of the component on a surface of the ceramic body whereby an electronic component is produced having uniform electrical characteristics with a relatively small sample variance.
Claim 13
Independent Claim 94 words
A method of making a non-linear voltage-dependent electronic component comprising the steps of: (a) electroless plating a metal coating over a surface of a ceramic body so that the amount of metal dispersion is constant thereover; (b) heat-treating the metal coated ceramic body to oxidize the metal coating and simultaneously diffuse at least a portion of the oxidized metal coating into said ceramic body; and (c) providing electrodes of the component on a surface of the ceramic body whereby an electronic component is produced having uniform electrical characteristics with a relatively small sample variance.
Claim 14
Independent Claim 103 words
A method of making an intergranular barrier type semiconductive ceramic capacitor comprising the steps of: (a) electroless plating a metal over a surface of a sintered semiconductive ceramic body to form a metal coating thereon so that the resulting metal deposition is constant thereover; (b) heat-treating the metal plated ceramic body to oxidize the metal coating and simultaneously diffuse at least a portion of the oxidized metal coating into said ceramic body; and (c) providing metal electrodes for the capacitor on opposite surfaces of the ceramic body whereby an electronic component is produced having uniform electrical characteristics with a relatively small sample variance.
Claim 15
Independent Claim 103 words
A method of making an intergranular barrier type semiconductive ceramic capacitor comprising the steps of: (a) electroless plating a metal over a surface of a sintered semiconductive ceramic body to form a metal coating thereon so that the resulting metal deposition is constant thereover; (b) heat-treating the metal plated ceramic body to oxidize the metal coating and simultaneously diffuse at least a portion of the oxidized metal coating into said ceramic body; and (c) providing metal electrodes for the capacitor on opposite surfaces of the ceramic body whereby an electronic component is produced having uniform electrical characteristics with a relatively small sample variance.
Claim 16
Independent Claim 78 words
A method of making an intergranular barrier type semiconductive ceramic capacitor comprising the steps of: (a) electroless plating copper on a strontium titanate based sintered ceramic body so that the resulting metal deposition is constant thereover; (b) heat-treating said ceramic body at 900°-1200° C. for 1 to 5 hours; and (c) forming silver electrodes on opposite surfaces of the treated ceramic body whereby an electronic component is produced having uniform electrical characteristics with a relatively small sample variance.
Claim 17
Independent Claim 78 words
A method of making an intergranular barrier type semiconductive ceramic capacitor comprising the steps of: (a) electroless plating copper on a strontium titanate based sintered ceramic body so that the resulting metal deposition is constant thereover; (b) heat-treating said ceramic body at 900°-1200° C. for 1 to 5 hours; and (c) forming silver electrodes on opposite surfaces of the treated ceramic body whereby an electronic component is produced having uniform electrical characteristics with a relatively small sample variance.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1985-01-18 1985-07-20 1986-01-19 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1989-01-18 1989-07-20 1990-01-19 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1993-01-18 1993-07-20 1994-01-19 $7700.00 Window Closed / Lapsed

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