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US4283371A Expired / Lapsed US ⏱️ 0.0 years remaining

Process for the production of aluminum chloride and related products

Assignee: Kerr McGee Corp
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Filing: 1980-01-28
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Granted: 1981-08-11
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Expires: 2000-01-28
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Abstract

Abstract A continuous process for recovering substantially pure aluminum chloride from chlorination products of aluminum ore. The chlorination products are contacted with a first selective solvent to dissolve a substantial portion of the aluminum chloride and some ferric chloride. The solvent is separated from the chlorides which then are treated to produce a ferric chloride-rich stream and an aluminum chloride-rich stream in which the aluminum chloride to ferric chloride ratio is higher than the ratio prior to solvent separation. The aluminum chloride-rich stream is contacted with a second solvent to dissolve any ferric chloride present and saturate the solution with aluminum chloride. Aluminum chloride in excess of that soluble in the second solvent separates as a substantially pure solid phase. The solution is separated from solid phase and recycled in process to recover additional aluminum chloride.

Inventors

  • 👤 Theodore A. Rado

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-30 21:21
CPC Classifications
C; C01; C01F; C01F7/00; C01F7/48; C01F7/56; C01F7/62

Claims Analysis

Total Claims: 7
Claim 1
Independent Claim 234 words
A process for producing substantially pure aluminum chloride comprising: providing chlorination products of an aluminous ore containing iron and other impurities; contacting said chlorination products with a first solvent to dissolve at least a portion of the chlorides present including at least a portion of the aluminum chloride present in said chlorination products to form a solution; separating said solution from said undissolved chlorination products said solution containing aluminum chloride and at least one chloride of iron in a ratio essentially in proportion to their respective solubilities in the solvent; separating said first solvent from said solution to leave a mixture of molten chlorides; separating said mixture of molten chlorides into an aluminum chloride-rich stream and a second stream, said aluminum chloride-rich stream containing aluminum chloride in a ratio to any chloride of iron present in excess of the solubility ratio of the mixture of chlorides in a second solvent; contacting said molten aluminum chloride-rich stream with the second solvent to dissolve aluminum chloride and at least a portion of the chlorides other than aluminum chloride contained in said molten aluminum chloride-rich stream and saturate the solvent with aluminum chloride to form a second solution said second solution being in admixture with aluminum chloride in excess of that which is soluble as a solid phase; and; recovering said solid aluminum chloride from said second solution, said solid aluminum chloride being substantially pure aluminum chloride.
Claim 2
Dependent Claim 234 words
A process for producing substantially pure aluminum chloride comprising: providing chlorination products of an aluminous ore containing iron and other impurities; contacting said chlorination products with a first solvent to dissolve at least a portion of the chlorides present including at least a portion of the aluminum chloride present in said chlorination products to form a solution; separating said solution from said undissolved chlorination products said solution containing aluminum chloride and at least one chloride of iron in a ratio essentially in proportion to their respective solubilities in the solvent; separating said first solvent from said solution to leave a mixture of molten chlorides; separating said mixture of molten chlorides into an aluminum chloride-rich stream and a second stream, said aluminum chloride-rich stream containing aluminum chloride in a ratio to any chloride of iron present in excess of the solubility ratio of the mixture of chlorides in a second solvent; contacting said molten aluminum chloride-rich stream with the second solvent to dissolve aluminum chloride and at least a portion of the chlorides other than aluminum chloride contained in said molten aluminum chloride-rich stream and saturate the solvent with aluminum chloride to form a second solution said second solution being in admixture with aluminum chloride in excess of that which is soluble as a solid phase; and; recovering said solid aluminum chloride from said second solution, said solid aluminum chloride being substantially pure aluminum chloride.
Claim 3
Dependent Claim 16 words
The process of claim 1 wherein the first solvent is the same as the second solvent.
Claim 4
Dependent Claim 27 words
The process of claim 1 wherein the first solvent is at least one member selected from the group consisting of titanium tetrachloride, silicon tetrachloride and carbon tetrachloride.
Claim 5
Dependent Claim 25 words
The process of claim 1 wherein the second solvent is at least one member selected from the group consisting of titanium tetrachloride and silicon tetrachloride.
Claim 6
Dependent Claim 24 words
The process of claim 1 wherein separating said first solvent from said dissolved chlorides is defined further as separating said first solvent by distillation.
Claim 7
Dependent Claim 94 words
The process of claim 1 wherein providing chlorination products of an aluminous ore is defined further as: contacting an aluminous ore prior to chlorination with a mineral acid present in sufficient quantity to dissolve at least a portion of any acid soluble impurities that are present and form a solution of said dissolved impurities, said mineral acid having a concentration such that alumina in said aluminous ore remains substantially undissolved; separating said solution from the remaining aluminous ore to form a pretreated aluminous ore; and chlorinating said pretreated aluminous ore to form chlorination products.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1984-08-10 1985-02-09 1985-08-11 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1988-08-10 1989-02-09 1989-08-11 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1992-08-10 1993-02-09 1993-08-11 $7700.00 Window Closed / Lapsed

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