US4267012A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Process for patterning metal connections on a semiconductor structure by using a tungsten-titanium etch resistant layer
Assignee: National Semiconductor Corp
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Filing: 1979-04-30
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Granted: 1981-05-12
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Expires: 1999-04-30
Abstract
Abstract A process for patterning regions on a semiconductor structure comprises the steps of forming a first layer of an alloy of tungsten and titanium on the semiconductor structure, forming a conductive layer of aluminum or chemically similar material on the surface of the tungsten-titanium alloy, removing the undesired portions of the conductive layer by etching with a plasma and removing the thereby exposed portions of the tungsten-titanium alloy layer by chemical etching.
Inventors
- 👤 John M. Pierce
- 👤 William I. Lehrer
- 👤 Kenneth J. Radigan
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-29 03:53
CPC Classifications
H; H10; H10P; H10P50/00; H10P50/20; H10P50/26; H10P50/264; H10P50/266; H10P50/267; H10P50/268; H10P50/60; H10P50/66; H10P50/663; H10P50/667; H10P50/69; H10P50/691; H10P50/692; H10P50/693; H10P50/694
Claims Analysis
Total Claims: 20
Claim 1
Independent Claim
181 words
A process for patterning a layer of conductive material formed on a semiconductor structure comprising; depositing a first layer of an alloy of tungsten and titanium on the semiconductor structure; depositing the layer of conductive material onto the first layer; removing undesired portions of the layer of conductive material by etching said layer with a plasma containing chlorine, wherein the plasma etching is substantially stopped by the first layer after etching through the layer of conductive material; removing the thereby exposed portions of the first layer with an etchant other than the plasma etchant used to etch the layer of conductive material; removing selected portions of the first layer, said selected portions lying beneath the layer of conductive material and contiguous to the edge of the layer of conductive material; and treating at least those portions of the layer of conductive material from beneath which the first layer has been removed to cause those portions to come into contact with the underlying material, the treating including forming a layer of dielectric material over the surface of the layer of selected material.
Claim 2
Dependent Claim
181 words
A process for patterning a layer of conductive material formed on a semiconductor structure comprising; depositing a first layer of an alloy of tungsten and titanium on the semiconductor structure; depositing the layer of conductive material onto the first layer; removing undesired portions of the layer of conductive material by etching said layer with a plasma containing chlorine, wherein the plasma etching is substantially stopped by the first layer after etching through the layer of conductive material; removing the thereby exposed portions of the first layer with an etchant other than the plasma etchant used to etch the layer of conductive material; removing selected portions of the first layer, said selected portions lying beneath the layer of conductive material and contiguous to the edge of the layer of conductive material; and treating at least those portions of the layer of conductive material from beneath which the first layer has been removed to cause those portions to come into contact with the underlying material, the treating including forming a layer of dielectric material over the surface of the layer of selected material.
Claim 3
Dependent Claim
18 words
A process as in claim 1, wherein the alloy comprises between 50% and 100% by weight of tungsten.
Claim 4
Dependent Claim
14 words
A process as in claim 2, wherein the alloy comprises 90% by weight tungsten.
Claim 5
Dependent Claim
28 words
A process as in claim 1, wherein the step of removing the exposed portions of the first layer is performed by a chemical etch which comprises hydrogen peroxide.
Claim 6
Dependent Claim
13 words
A process as in claim 4, wherein the chemical etch includes ammonium hydroxide.
Claim 7
Dependent Claim
17 words
A process as in claim 1, wherein the first layer is between 500 and 2000 Angstroms thick.
Claim 8
Dependent Claim
14 words
A process as in claim 6, wherein the first layer is 1500 Angstroms thick.
Claim 9
Dependent Claim
45 words
A process as in claim 1 wherein the step of removing the exposed portions of the first layer is preceded by a step of forming a coating resistant to plasma etching over those portions of the conductive layer which are not to be plasma etched.
Claim 10
Dependent Claim
11 words
A process as in claim 8 wherein the coating is photoresist.
Claim 11
Dependent Claim
12 words
A process as in claim 1 wherein the conductive material includes aluminum.
Claim 12
Dependent Claim
20 words
A process as in claim 10 wherein the conductive material also includes at least one of chromium, silicon, and copper.
Claim 13
Dependent Claim
20 words
A process as in claim 1 preceded by the step of forming a layer of titanium on the semiconductor structure.
Claim 14
Dependent Claim
23 words
A process as in claim 12 wherein the thickness of the layer of titanium is less than the thickness of the first layer.
Claim 15
Dependent Claim
16 words
A process as in claim 13 wherein the layer of titanium is approximately 200 Angstroms thick.
Claim 16
Dependent Claim
32 words
A process as in claim 1 wherein the step of removing the exposed portions of the first layer and the step of removing selected portions of the first layer are performed simultaneously.
Claim 17
Dependent Claim
16 words
A process as in claim 15 wherein the steps are performed using a chemical etching solution.
Claim 18
Dependent Claim
12 words
A process as in claim 16 wherein the solution includes hydrogen peroxide.
Claim 19
Dependent Claim
18 words
A process as in claim 1 wherein the step of treating includes heating the layer of selected material.
Claim 20
Dependent Claim
15 words
A process as in claim 1 wherein the dielectric material is vapor deposited silicon dioxide.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1984-05-11 | 1984-11-10 | 1985-05-12 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1988-05-11 | 1988-11-10 | 1989-05-12 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1992-05-11 | 1992-11-10 | 1993-05-12 | $7700.00 | Window Closed / Lapsed |