Nonlaminating polyphenylene ether blends

Claim 2

A composition comprising (a) a polyphenylene oxide (b) a block copolymer having a number average molecular weight in the range of about 70,000 to about 150,000 and having the formula (A--B-- n Y or A--B--A, wherein A is a block of polymerized monovinylarene having a heterogeneity index of at least 0.1 unit higher than the heterogeneity index of the block copolymer, B is a hydrogenated polymer block of polymerized or copolymerized conjugated diene, said block B rendering the block copolymer rubbery; Y is a radical from a multifunctional coupling agent n is a number of two or more and (c) a monovinylarene resin in which at least 25 weight percent of the polymer units are derived from the compound having the formula ##STR4## wherein R 2 and R 3 are selected from the group consisting of hydrogen and lower alkyl or alkenyl groups of from 1 to 6 carbon atoms; R 4 and R 5 are selected from the group consisting of chloro, bromo, hydrogen, and lower alkyl groups of from 1 to 6 carbon atoms; and R 6 and R 7 are selected from the group consisting of hydrogen and lower alkyl and alkenyl groups of from 1 to 6 carbon atoms or R 6 and R 7 may be concatenated together with hydrocarbyl groups to form a naphthyl group.

Claim 3

The composition of claim 1 wherein the monovinylarene is styrene and the diene is 1,3-butadiene.

Claim 4

The composition of claim 1 wherein said monovinylarene resin is polystyrene.

Claim 5

The composition of claim 1 wherein said block copolymer has the formula (A--B-- n Y.

Claim 6

The composition of claim 4 wherein said monovinylarene resin is polystyrene.

Claim 7

The composition of claim 1 wherein said polyphenylene oxide (a) is poly(2,6-dimethyl-1,4-phenylene oxide), wherein said block copolymer has the formula (A--B-- n Y wherein A is a polystyrene block and B is a polybutadiene block and wherein said monovinylarene resin is polystyrene.

Claim 8

A composition comprising (A) a block copolymer having a number average molecular weight in the range of about 70,000 to about 15,000 formed by a process comprising (1) polymerizing a first quantity of monovinylarene and a first quantity of an essentially monofunctional polymerization initiator to produce a first living polymer mixture, (2) adding to this first living polymer mixture at least one further quantity of monovinylarene and at least one further quantity of monofunctional polymerization initiator to produce a further living polymer mixture having a heterogeneity index at least 0.1 unit higher than the block copolymer, the polymer in this further living polymer mixture being described by the formula A--L wherein A is a block of polymerized monovinylarene and L originates from the monofunctional polymerization initiator, (3) adding to said further living polymer mixture at least one additional quantity of monomer comprising a conjugated diene to form a polymer block B attributing rubbery properties to the final polymer and thereby forming a final living polymer mixture, the polymer in this final living polymer mixture being described by the formula A--B--L (4) coupling the polymer in the final living polymer mixture by contacting it with a multifunctional coupling agent under coupling conditions such as to connect two or more molecules of said polymer A--B--L to form a copolymer described by the formula (A--B-- n Y wherein Y is the residue of said multi-functional coupling agent and n is a number of two or more representative of the coupling degree, (5) hydrogenating and recovering said teleblock copolymer, and (B) a polyphenylene oxide. (C) a monovinylarene resin

Claim 9

A composition comprising (A) a block copolymer having a number average molecular weight in the range of about 70,000 to about 15,000 formed by a process comprising (1) polymerizing a first quantity of monovinylarene and a first quantity of an essentially monofunctional polymerization initiator to produce a first living polymer mixture, (2) adding to this first living polymer mixture at least one further quantity of monovinylarene and at least one further quantity of monofunctional polymerization initiator to produce a further living polymer mixture having a heterogeneity index at least 0.1 unit higher than the block copolymer, the polymer in this further living polymer mixture being described by the formula A--L wherein A is a block of polymerized monovinylarene and L originates from the monofunctional polymerization initiator, (3) adding to said further living polymer mixture at least one additional quantity of monomer comprising a conjugated diene to form a polymer block B attributing rubbery properties to the final polymer and thereby forming a final living polymer mixture, the polymer in this final living polymer mixture being described by the formula A--B--L (4) coupling the polymer in the final living polymer mixture by contacting it with a multifunctional coupling agent under coupling conditions such as to connect two or more molecules of said polymer A--B--L to form a copolymer described by the formula (A--B-- n Y wherein Y is the residue of said multi-functional coupling agent and n is a number of two or more representative of the coupling degree, (5) hydrogenating and recovering said teleblock copolymer, and (B) a polyphenylene oxide. (C) a monovinylarene resin

Claim 10

The composition of claim 7 wherein said block copolymer is one that has been hydrogenated to remove essentially all of the olefinic unsaturation from the polymer while leaving the aromatic unsaturation essentially unchanged to form a hydrogenated teleblock copolymer as a portion of that composition.

Claim 11

The composition of claim 7 wherein said monovinylarene is styrene and said diene is 1,3-butadiene.

Claim 12

The composition of claim 7 further comprising a monovinylarene resin having the formula ##STR5## wherein R 2 and R 3 are selected from the group consisting of hydrogen and lower alkyl or alkenyl groups of from 1 to about 6 carbon atoms; R 4 and R 5 are selected from the groups consisting of chloro, bromo, hydrogen, and lower alkyl groups of from 1 to about 6 carbon atoms; and R 6 and R 7 are selected from the group consisting of hydrogen and lower alkyl and alkenyl groups of from 1 to about 6 carbon atoms or R 6 and R 7 may be concatenated together with hydrocarbyl groups to form a naphthyl group.

Claim 13

The composition of claim 10 wherein said monovinylarene resin is polystyrene.

Claim 14

The composition of claim 7 wherein A is a polystyrene block and B is a polybutadiene block.

Claim 15

The composition of claim 7 wherein the further living polymer mixture is formed by adding one further quantity of monovinylarene and one further quantity of monofunctional initiator to the first living polymer mixture.

Claim 16

The composition of claim 10 comprising at least about 30 weight percent polyphenylene oxide and about 5 to about 25 weight percent teleblock copolymer.

Claim 17

The composition of claim 14 consisting essentially of 30 to 85 weight percent polyphenylene oxide, 10 to 50 weight percent polymonovinylarene, 5 to 25 weight percent teleblock copolymer, and optionally, usually employed polymer additives, the weight percentages given being based on the total composition.