US4123410A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Polyphenylene ether resin compositions of reduced melt viscosity
Assignee: General Electric Co
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Filing: 1977-09-30
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Granted: 1978-10-31
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Expires: 1997-09-30
Abstract
Abstract There are provided thermoplastic polyphenylene ether resin compositions which comprise, in admixture, a major proportion of the polyphenylene ether resin, a minor proportion of a plasticizer at least sufficient to provide a plasticized composition after molding and poly(1,4-butylene terephthalate) or branched copolyester in an amount sufficient to reduce the melt viscosity of the composition without substantially reducing the heat distortion temperature and ductility properties thereof. In such compositions, there may also be present an A--B--A 1 copolymeric resin as an impact modifier. In preferred instances, where said poly(1,4-butylene terephthalate) is utilized in an amount in excess of about 5% by weight, the compositions will also contain a hydrogenated A--B--A 1 block copolymer.
Inventors
- 👤 Gim F. Lee, Jr.
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-26 21:15
CPC Classifications
C; C08; C08L; C08L71/00; C08L71/08; C08L71/10; C08L71/12; C08L71/123
Claims Analysis
Total Claims: 15
Claim 1
Independent Claim
69 words
A thermoplastic composition comprising by weight, based on the total weight of the composition, a major proportion of polyphenylene ether resin having intimately admixed therewith a minor proportion of a plasticizer; and poly(1,4-butylene terephthalate) or a copolyester thereof with a minor amount of a branching composition in an amount sufficient to reduce the melt viscosity of said composition without substantially reducing the heat distortion temperature and ductility properties thereof.
Claim 2
Dependent Claim
69 words
A thermoplastic composition comprising by weight, based on the total weight of the composition, a major proportion of polyphenylene ether resin having intimately admixed therewith a minor proportion of a plasticizer; and poly(1,4-butylene terephthalate) or a copolyester thereof with a minor amount of a branching composition in an amount sufficient to reduce the melt viscosity of said composition without substantially reducing the heat distortion temperature and ductility properties thereof.
Claim 3
Dependent Claim
103 words
A composition as defined in claim 1 wherein the polyphenylene ether resin has the formula: ##STR3## wherein the oxygen ether atom of one unit is connected to the benzene nucleus of the next adjoining unit, n is a positive integer and is at least 50, and each Q is a monovalent substituent selected from the group consisting of hydrogen, halogen, hydrocarbon radicals free of a tertiary alpha-carbon atom, halo-hydrocarbon radicals having at least two carbon atoms between the halogen atom and the phenyl nucleus, hydrocarbonoxy radicals and halohydrocarbonoxy radicals having at least two carbon atoms between the halogen atom and the phenyl nucleus.
Claim 4
Dependent Claim
13 words
A composition as defined in claim 2 wherein polyphenylene ether resin is poly(2,6-dimethyl-1,4-phenylene)ether.
Claim 5
Dependent Claim
49 words
A composition as defined in claim 1 wherein the plasticizer is a compound of the formula: ##STR4## wherein R 1 , R 2 and R 3 are the same or different and are alkyl, cycloalkyl, aryl, alkyl substituted aryl, aryl substituted alkyl hydroxyalkyl, hydroxyaryl, hydroxyalkaryl, halogen, haloaryl and hydrogen.
Claim 6
Dependent Claim
15 words
A composition as defined in claim 4 wherein the plasticizer is an aromatic phosphate plasticizer.
Claim 7
Dependent Claim
14 words
A composition as defined in claim 5 wherein the aromatic phosphate is triphenyl phosphate.
Claim 8
Dependent Claim
29 words
A composition as defined in claim 1 wherein said poly(1,4-butylene terephthalate) or branched copolyester thereof is present in a range of from about 2% to about 5% by weight.
Claim 9
Dependent Claim
26 words
A composition as defined in claim 1 wherein the polyphenylene ether resin is present in a range of from about 50% to about 99% by weight.
Claim 10
Dependent Claim
24 words
A composition as defined in claim 1 wherein the plasticizer is present in a range of from about 1% to about 49% by weight.
Claim 11
Dependent Claim
15 words
A composition as defined in claim 1 including an impact modifier in a minor proportion.
Claim 12
Dependent Claim
43 words
A composition as defined in claim 10 wherein the impact modifier is an A--B--A 1 block copolymer in which terminal blocks A and A 1 are polymer of a vinyl aromatic compound and center block B is a copolymer of a conjugated diene.
Claim 13
Dependent Claim
18 words
A composition as defined in claim 11 wherein the A--B--A 1 block copolymer is a styrene-butadiene-styrene block copolymer.
Claim 14
Dependent Claim
42 words
A composition as defined in claim 11 wherein the A--B--A 1 block copolymer is a hydrogenated A--B--A 1 block copolymer and poly(1,4-butylene terephthalate) or branched copolyester thereof is present in said composition in an amount in excess of about 5% by weight.
Claim 15
Dependent Claim
53 words
A composition as defined in claim 13 wherein the hydrogenated block copolymer is a hydrogenated styrene-butadiene-styrene block copolymer which is present in said composition in an amount of about 15% by weight and in which composition the poly(1,4-butylene terephthalate or branched copolyester thereof is present in an amount of about 10% by weight.
References Cited (Backward Citations)
US3703564A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1981-10-30 | 1982-05-01 | 1982-10-31 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1985-10-30 | 1986-05-01 | 1986-10-31 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1989-10-30 | 1990-05-01 | 1990-10-31 | $7700.00 | Window Closed / Lapsed |