Patent US4252888A successfully refreshed from Google Patents.
US4252888A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Solder mask composition
Assignee: 3M Co
•
Filing: 1980-02-26
•
Granted: 1981-02-24
•
Expires: 2000-02-26
Abstract
Abstract A photopolymerizable composition which is screen-printable and has utility as a solder mask, the composition comprising aryloxyalkyl acrylate monomers or prepolymers, a diacrylate diluent, a monofunctional monomer and a free-radical initiating system.
Inventors
- 👤 Robert R. Rohloff
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-01 17:24
CPC Classifications
G; G03; G03F; G03F7/00; G03F7/004; G03F7/027; H; H05; H05K; H05K3/00; H05K3/22; H05K3/28; H05K3/285; H05K3/287
Claims Analysis
Total Claims: 8
Claim 1
Independent Claim
165 words
A screen-printable photopolymerizable composition comprising from about 15 to about 85 percent by weight of an aryloxyalkyl acrylate having the general formula: ##STR2## wherein X is a methylene, an alkyl-substituted methylene group, a dialkyl-substituted methylene group, a carbonyl group, a sulfide, a sulfoxide, a sulfone, an amine, an alkyl-substituted amine, an ethylene ether, a propylene ether, a 2-hydroxypropylene ether, wherein each alkyl group may have from 1 to 8 carbon atoms, or any combination thereof; Y is ethyl, propyl, 2-hydroxypropyl, or other lower alkyl or hydroxyalkyl groups having up to 8 carbon atoms; A is an unsaturated acryloxy group having from 3 to 18 carbons, preferably acryloxy or methacryloxy; and n is 0 through 20, m is 0 or 1, and p is 0 or 1; from about 15 to about 85 percent by weight of a diacrylate diluent; an effective amount of a monofunctional monomer selected from the group consisting of styrene and its monofunctional analogs; and a free-radical generating addition polymerizing initiating system.
Claim 2
Dependent Claim
165 words
A screen-printable photopolymerizable composition comprising from about 15 to about 85 percent by weight of an aryloxyalkyl acrylate having the general formula: ##STR2## wherein X is a methylene, an alkyl-substituted methylene group, a dialkyl-substituted methylene group, a carbonyl group, a sulfide, a sulfoxide, a sulfone, an amine, an alkyl-substituted amine, an ethylene ether, a propylene ether, a 2-hydroxypropylene ether, wherein each alkyl group may have from 1 to 8 carbon atoms, or any combination thereof; Y is ethyl, propyl, 2-hydroxypropyl, or other lower alkyl or hydroxyalkyl groups having up to 8 carbon atoms; A is an unsaturated acryloxy group having from 3 to 18 carbons, preferably acryloxy or methacryloxy; and n is 0 through 20, m is 0 or 1, and p is 0 or 1; from about 15 to about 85 percent by weight of a diacrylate diluent; an effective amount of a monofunctional monomer selected from the group consisting of styrene and its monofunctional analogs; and a free-radical generating addition polymerizing initiating system.
Claim 3
Dependent Claim
23 words
The photopolymerizable composition of claim 1 wherein said aryloxyalkyl acrylate constitutes from about 15 to about 40 percent by weight of said composition.
Claim 4
Dependent Claim
23 words
The photopolymerizable composition of claim 1 wherein said diacrylate diluent constitutes from about 40 to about 70 percent by weight of said composition.
Claim 5
Dependent Claim
41 words
The photopolymerizable composition of claim 1 wherein the weight ratio of said diacrylate diluent to said aryloxyalkyl acrylate is about 1 to 3, and wherein said monofunctional monomer constitutes from about 1 to about 50 percent by weight of said composition.
Claim 6
Dependent Claim
44 words
The photopolymerizable composition of claim 1 wherein the ratio of said diacrylate diluent to said aryloxyalkyl acrylate is from about 1 to 1 to 3 to 1, and said monofunctional monomer constitutes from about 1 to about 30 percent by weight of said composition.
Claim 7
Dependent Claim
27 words
The photopolymerizable composition of claim 1 wherein said diacrylate diluent is selected from the group consisting of 1,3-butylene glycol diacrylate, triethylene glycol diacrylate and tetraethylene glycol diacrylate.
Claim 8
Dependent Claim
13 words
The photopolymerizable composition of claim 1 wherein said monofunctional monomer is vinyl toluene.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1984-02-24 | 1984-08-25 | 1985-02-24 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1988-02-24 | 1988-08-25 | 1989-02-24 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1992-02-24 | 1992-08-25 | 1993-02-24 | $7700.00 | Window Closed / Lapsed |