Photopolymerizable screen printing inks for permanent coatings prepared from aryloxyalkyl compositions

Claim 1

A photopolymerizable screen-printing ink which comprises: A. 35-70% by weight of an aryloxyalkyl acrylate having the general formula: ##STR4##wherein X is a methylene, an alkyl-substituted methylene group, a dialkyl-substituted methylene group, a carbonyl group, a sulfide, a sulfoxide, a sulfone, an amine, an alkyl-substituted amine, an ethylene ether, a propylene ether, a 2-hydroxylpropylene ether, wherein each alkyl group contains from 1 to 8 carbon atoms; Y is lower aklyl or hydroxylower alkyl of up to 8 carbon atoms; A is an unsaturated acyloxy group having from 3 to 18 carbon atoms; and n is 0 through 20, m is 0 or 1, p is 0 or 1; B. 15-45% by weight of a photopolymerizable diluent having terminal ethylenic groups selected from ethylene diacrylate; diethylene glycol diacrylate; tetraethylene glycol diacrylate; glycerol diacrylate; glycerol triacrylate; ethylene dimethacrylate; 1,3-propylene dimethacrylate; 1,2,4-butanetriol trimethacrylate; 1,4-benzenediol dimethacrylate; pentaerythritol tetremethacrylate; 1,3-propanediol diacrylate; 1,6-hexanediol diacrylate; the bis-acrylate of a polyethylene glycol having a molecular weight of 200 to 500; the bis-methacrylate of a polyethylene glycol having a molecular weight of 200 to 500; trimethylol-propane triacrylate; pentaerythritol triacrylate; methylene bis-acrylamide; methylene bis-methacrylamide; 1,6-hexamethylene bis-acrylamide; diethylene triamine tri-methacrylamide; bis-(methacrylamidopropoxy) ethane; bis-methacrylamidoethyl methacrylate N-(beta-hydroxyethyloxy) ethyl acrylamide; divinyl succinate; divinyl adipate; divinyl phthalate; divinyl terephthalate; divinyl benzene-1,3-disulfonate; divinyl butane-1,4-disulfonate; and sorbaldehyde; C. 0.1-10% by weight of a free radical generating addition polymerizing initiating system; said photopolymerizable composition having a viscosity of from 5,000 to 200,000 centipoises and a thixotropic index of from 1.00 to 6.00.